| 光谱学与光谱分析 |
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| Henry’s Law Constant Measurement for Hydrogen Peroxide Using Oxidative Decoloration of BPR |
| CHEN Zhong-ming,QU Xiao-cao |
| The State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences, Peking University, Beijing 100871, China |
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Abstract The temperature-dependent Henry’s Law Constant for hydrogen peroxide was measured.The gas phase of hydrogen peroxide from the vapor saturator collected in a cryogenic trap was analyzed by a spectrophotometric determination, based on the oxidative decoloration of BPR (bromopryogallol red) reaction with hydrogen peroxide under the catalysis of hemin.At 10 ℃-35 ℃, the relationship between Henry’s Law constant KH (mol·L-1·atm-1) of hydrogen peroxide and temperature T (K) can be expressed as ln KH=a/T-b, where a=7 269±22, and b=13.26±0.08.The standard heat of hydrogen peroxide aqueous solution is 60.43±0.18 kJ·K-1·mol-1.
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Received: 2003-12-28
Accepted: 2004-04-28
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Corresponding Authors:
CHEN Zhong-ming
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| Cite this article: |
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CHEN Zhong-ming,QU Xiao-cao. Henry’s Law Constant Measurement for Hydrogen Peroxide Using Oxidative Decoloration of BPR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(07): 1114-1117.
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https://www.gpxygpfx.com/EN/Y2005/V25/I07/1114 |
[1] Jackson A V，Hewitt C N.Crit.Rev.Environ.Sci.Tech., 1999, 29: 175.
[2] Lee M, Heikes B G, O'Sullivan D W.Atmos.Environ., 2000, 34: 3475.
[3] Staaudinger J，Roberts P V.Chemosphere, 2001, 44: 561.
[4] Hwang H，Dasgupta P K.Environ.Sci.Technol, 1985, 19: 255.
[5] Lind J A，Kok G L.J.Geophys.Res., 1986, 91: 7889.
[6] Lind J A，Kok G L.J.Geophys.Res., 1994, 99: 21119.
[7] Staffelbach T A，Kok G L.J.Geophys.Res.，1993, 98: 12713.
[8] O'Sullivan D W, Lee M, Noone B C, et al.J.Phys.Chem., 1996, 100: 3241.
[9] Guo Z X, Shen H X，Li L.Microchimica Acta, 1999, 131: 171. |
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