光谱学与光谱分析 |
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Quantitative Determination of Melamine by Fluorescence Spectroscopy and Radial Basis Function Neural Networks |
CHEN Guo-qing, WEI Bai-lin, WANG Jun, WU Ya-min, GAO Shu-mei, KONG Yan, ZHU Tuo* |
School of Science, Jiangnan University, Wuxi 214122, China |
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Abstract Based on the experimental study, it was found that melamine solution excited by UV light can generate a strong fluorescence.The fluorescence spectrum is within a range from 310 to 600 nm, the peak wavelength of the fluorescence is about 420 nm, and the relationship between fluorescence intensity and melamine solution concentration is nonlinear.A method for the determination of melamine solution concentration was presented, which was based on fluorescence spectroscopy and radial basis function neural networks.For each sample, 30 emission wavelength values were selected, the fluorescence intensity corresponding to the selected wavelength was used as the network data, and a radial basis function neural network was trained and constructed.The trained radial basis function neural network was employed to predict the melamine solution concentration in five kinds of samples, and the relative errors of the results were 0.93%, 0.09%, 0.31%, 1.55% and 4.61%, respectively.The results show that this method can determine the content of melamine quickly and accurately.The whole research outcomes will provide a new method for determining the content of melamine and food safety supervision.
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Received: 2009-01-10
Accepted: 2009-04-20
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Corresponding Authors:
ZHU Tuo
E-mail: tzhu@jiangnan.edu.cn
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[1] Ogasawara H, Imaida K, Ishiwata H, et al.Carcinogenesis, 1995, 16(11): 2773. [2] GONG Xiao-ming, DONG Jing, SUN Jun, et al(宫小明, 董 静, 孙 军, 等).Food Science(食品科学), 2008, 29(4): 321. [3] WU Hui-qin, HUANG Fang, LIN Xiao-shan, et al(吴惠勤, 黄 芳, 林晓珊, 等).Journal of Instrumental Analysis(分析测试学报), 2008, 27(10): 1044. [4] HUANG Fang, HUANG Xiao-lan, WU Hui-qin, et al(黄 芳, 黄晓兰, 吴惠勤, 等).Journal of Instrumental Analysis(分析测试学报), 2008, 27(3): 313. [5] LI Ai-jun, ZHANG Dai-hui, MA Shu-min, et al(李爱军, 张代辉, 马书民, 等).Chinese Journal of Analytical Chemistry(分析化学), 2008, 36(5): 699. [6] CAI Qin-ren, OUYANG Ying-yu, QIAN Zhen-jie, et al(蔡勤仁, 欧阳颖瑜, 钱振杰, 等).Chinese Journal of Chromatography(色谱), 2008, 26(3): 339. [7] WU Dan, XU Gui-ying(吴 丹, 徐桂英).Acta Phys.Chim.Sin.(物理化学学报), 2006, 22(2): 254. [8] LI Xiao-yan(李晓燕).Acta Phys.Chim.Sin.(物理化学学报), 2007, 23 (2): 262. [9] LIU Gen-lan, NI Yong-nian(刘根兰, 倪永年).Chemical Journal of Chinese Universities(高等学校化学学报), 2008, 29(7): 1339. [10] BAI Hai-xin, YANG Cheng, YANG Xiu-rong(白海鑫, 杨 成, 杨秀荣).Chemical Journal of Chinese Universities(高等学校化学学报), 2007, 28(2): 227. [11] HU Ya-min, WANG Xing-ming, FEI Dan, et al(胡亚敏, 王兴明, 费 丹, 等).Acta Chimica Sinica(化学学报), 2008, 66(10): 1245. [12] YANG Ran, QU Ling-bo, CHEN Xiao-lan, et al(杨 冉, 屈凌波, 陈晓岚, 等).Acta Chimica Sinica(化学学报), 2006, 64(13): 1349. [13] HE Jun-hua, CHENG Yong-jin, HAN Yan-ling, et al(贺俊华, 程永进, 韩艳玲, 等).Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(8): 1870. [14] XU Jin-gou, WANG Zun-ben(许金钩, 王尊本).Fluorimetry(荧光分析法).Beijing: Science Press(北京: 科学出版社), 2006. [15] Yiqun Huang, Lars J Kangas, Barbara A Rasco.Critical Reviews in Food Science and Nutrition, 2007, 47(2): 113. [16] HAO Rong-hua, CAI Yu-jie, ZHENG Fei-yun, et al(郝荣华, 蔡宇杰, 郑飞云, 等).China Brewing(中国酿造), 2007, 9: 15. [17] FENG Shang-kun, XU Hai-ju(冯尚坤, 徐海菊).Infrared Technology(红外技术), 2008, 30(1): 58. [18] Hilmi Berk Celikoglu, Hikmet Kerem Cigizoglu.Mathematical and Computer Modelling, 2007, 45(3-4): 480. [19] Zhao Zhongqiu, Huang Deshuang.Applied Mathematical Modelling, 2007, 31(7): 1271. [20] GE Zhe-xue, SUN Zhi-qiang(葛哲学, 孙志强).Neural Network Theory and Achievement by MATLABR2007(神经网络理论与MATLABR2007实现).Beijing: Publishing House of Electronics Industry(北京: 电子工业出版社), 2007.
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