| 光谱学与光谱分析 |
|
|
|
|
|
| Study on UV-Vis Absorption Spectra and Fluorescence Emission Spectra of Sixteen Tetra-Substituted Metallophthalocyanine Complexes |
| HUANG Zi-yang1, 2, HUANG Jian-dong1, CHEN Nai-sheng1, HUANG Jin-ling1* |
1. Institute of Research on Functional Materials, Fuzhou University, Fuzhou 350002, China
2. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China |
|
|
|
|
Abstract The UV-Visible absorption spectra and the fluorescence emission spectra of sixteen tetra-substituted metallo-phthalocyanine complexes {R4PcM, where R=2-[4-(2-sulfonic ethyl)piperazin-1-] ethoxyl (SPEO—), 2-(piperidin-1-yl)ethoxyl (PEO—); substitution position at α-position and β-position of phthalocyanine ring; M=Zn(Ⅱ), Ni(Ⅱ), Co(Ⅱ)and Cu(Ⅱ)} were measured. The influence of different central ion, substituted group and its position, as well as different solvent on the Q-band of phthalocyanine complex in its UV-Vis absorption spectra was investigated. The influence of different central ion, substituted group and its position on the fluorescence emission spectra was discussed. Some properties of the UV-Vis absorption spectra such as the maximum absorption wavelength (λmax)of Q-band and its molar extinction coefficient (ε), and those of the fluorescence emission spectra such as fluorescence quantum yield (ΦF), fluorescence lifetime (τ) and excited state energy (Es)were studied. The results showed that the λmax of Q-band of all complexes were located at 681-718 nm, which had a distinct red shift in contrast with unsubstituted metallophthalocyanines (669-671 nm). All complexes of R4PcM possessed a very high molar extinction coefficient up to 105 L·mol-1·cm-1. And the UV-Vis absorption spectra and the fluorescence emission spectra of all complexes exhibited mirror shape concurrently. Two β-substituted zinc phthalocyanine complexes with formula β-(SPEO)4PcZn and β-(PEO)4PcZn possessed very high molar extinction coefficient, fluorescence quantum yield and fluorescence lifetime specially. Therefore, it is hoped that these two would be developing to be new photosensitizers for photodynamic therapy (PDT)and photodynamic diagnosis (PDD).
|
|
Received: 2007-06-06
Accepted: 2007-09-08
|
|
|
|
Corresponding Authors:
HUANG Jin-ling
E-mail: zyhuang@finu.edu.cn
|
|
[1] McKeown N B. Phthalocyanine Materials Synthesis, Structure and Function. London: Cambridge University Press, 1998. 1.
[2] Lever A B P, Pickens S R, Minor P C, et al. Journal of American Chemical Society, 1981, 103: 6800.
[3] HUANG Jin-ling, CHEN Nai-sheng, HUANG Jian-dong, et al(黄金陵, 陈耐生, 黄剑东, 等). Science in China(Series B), 2001, 44(2): 113.
[4] Dirk D V, Huwyler J, Eberle A, et al. Canada Int. J. Cancer, 2002, 101: 78.
[5] Abimbola O, David M, Tebello N. J. Molecular Structure, 2003, 650: 131.
[6] Zhang X F, Xu H J. Journal of Chemical Society, Faraday Transition Ⅰ, 1993, 89(18): 3347.
[7] XUE Jin-ping, HONG Hu-ming, YE Ting-xiu, et al(薛金萍, 洪湖铭, 叶廷秀, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(11): 2050.
[8] CONG Fang-di, DU Xi-guang, ZHAO Bao-zhong, et al(丛方地, 杜锡光, 赵宝中, 等). Journal of Molecular Science(分子科学学报), 2003, 19(1): 26.
[9] ZHU Xiao-li, XU Xiu-zhi, YANG Liang, et al(朱晓利, 许秀枝, 杨 亮, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(5): 953.
[10] Hiromi S, Olga T, Gunter S, et al. Journal of Photochemistry and Photobiology A: Chemistry, 2006, 184: 50.
[11] Bayliss N S. Journal of Chemical Physics, 1950, 18(3): 292. |
| [1] |
HUANG Li, MA Rui-jun*, CHEN Yu*, CAI Xiang, YAN Zhen-feng, TANG Hao, LI Yan-fen. Experimental Study on Rapid Detection of Various Organophosphorus Pesticides in Water by UV-Vis Spectroscopy and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3452-3460. |
| [2] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
| [3] |
LIU Xian-yu1, YANG Jiu-chang1, 2, TU Cai1, XU Ya-fen1, XU Chang3, CHEN Quan-li2*. Study on Spectral Characteristics of Scheelite From Xuebaoding, Pingwu County, Sichuan Province, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2550-2556. |
| [4] |
LÜ Yang1, PEI Jing-cheng1*, ZHANG Yu-yang2. Chemical Composition and Spectra Characteristics of Hydrothermal Synthetic Sapphire[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3546-3551. |
| [5] |
ZHAO Xiong-wei1, WU Dong-ming2, LI Qin-fen2, WANG Xu1*, CHEN Miao2. Response of Dissolved Organic Matter Chemical Properties to Long-Term Different Fertilization in Latosol: Insight From Ultraviolet-Visible Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3210-3216. |
| [6] |
MA Ping1, 2, Andy Hsitien Shen1*, ZHONG Yuan1, LUO Heng1. Study on UV-Vis Absorption Spectra of Jadeite From Different Origins[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1827-1831. |
| [7] |
ZHONG Yuan, QU Meng-wen, Andy Hsitien Shen*. Comparison of Chemical Composition and Spectroscopy of Purple- Brownish Red Garnet From Zambia, Tanzania and Australia[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 184-190. |
| [8] |
YANG Yun-fan1, HU Jian-bo1, LIU Yong-gang1，2*, LIU Qiang-qiang3, ZHANG Hang4, XU Jian-jie5, GUO Teng-xiao5. DFT／TDDFT Study on Spectra of Peptides[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3172-3177. |
| [9] |
ZHANG Jiao1, 2, WANG Yuan-zhong1, YANG Wei-ze1, ZHANG Jin-yu1*. Data Fusion of ATR-FTIR and UV-Vis Spectra to Identify the Origin of Polygonatum Kingianum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1410-1416. |
| [10] |
CHEN Yu1, LIU Yu-zhu1, 2*, WANG Xing-chen3, ABULIMITI Bumaliya3*. Effect of External Electric Field on the Spectral Characteristics of Bromobenzene[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3732-3735. |
| [11] |
ZHAO Qiu-ling1,3，SHI Ya-jing1，ZHANG Zhen-yu2. Rapid Determination of Canthaxanthin in Egg Yolk by First Order Derivative Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3537-3541. |
| [12] |
YAN Jun1,2, SUN Qing2, YAN Xue-jun1, FANG Shi-bin1, SHENG Jia-wei2, ZHANG Jian2*. The Categories of the UV-Vis Reflectance Spectra of Seawater Cultured Black Pearl and Its Unique PL Spectral Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2781-2785. |
| [13] |
LIAN Jie1, REN Yi-fei2, YANG Rui-qin1*, HAO Hong-xia3. Rapid Detection System of 2,4,6-Trinitrophenol (TNP) Based on Fluorescent Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 804-808. |
| [14] |
XIN Chang-chun1, 2, JIA Hui1, 2, 3*, LI Juan1, 2, WEN Hai-tao2, 3, LI Jing-yu2, WANG Jie1, 2, 3. Integrity Detection of Hollow Fiber Membrane Bioreactor Based on Fluorescence Spectrum Response[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 125-130. |
| [15] |
ZHANG Chong-hui, HE Ting-shu*, LI Hui, BU Xian-zhong. Adsorption Thermodynamics and Kinetics of Xanthate at Chalcopyrite Surface Based on Ultraviolet Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(10): 3172-3178. |
|
|
|
|
