| 光谱学与光谱分析 |
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| Preparation, Spectral Analysis and Photocatalytic Activities of TiO2 Films Codoped with Iron and Nitrogen |
| LIU Wan-bing1, DENG Jian1*, ZHAO Yu-bao1, XU Jin-sheng2, ZHOU Liang1 |
1. School of Chemistry and Chemical Engineering，University of South China，Hengyang 421001, China
2. Hengyang Normal College, Hengyang 421008, China |
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Abstract Using tetrabutyl titanate as the titanium source, and ammonia and ferric nitrate as the sources of nitrogen and ferrum respectively, iron and nitrogen-codoped nano-TiO2 gelatins were prepared by sol-gel method. The iron and nitrogen-codoped nano-TiO2 complex films were prepared with the obtained gelatins used to coat the surface of cleaned glass slides by several times of dipping-lifting procedure, followed by natural seasoning at room temperature and calcined at 450 ℃ for 3 hours, then the films were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectrum (XPS) and ultraviolet-visible diffuse reflectance spectrum (UV-Vis). The XRD spectra of samples showed that the Fe-TiO2-xNx films were of anatase structure with a few of oxygen atoms in the lattice of anatase TiO2 substituted by nitrogen atoms, resulting in the distorsion of crystal lattice. The SEM image showed that the nanoparticles of the films have a good dispersion characteristic and uniform orbicular shape with an average diameter of about 19 nm. The absorption edges of UV-Vis spectra exhibited a red shift up to 740 nm when the TiO2 films were codoped with iron and nitrogen. The XPS of the Fe-TiO2-xNx film presented a lowering of Ti 2p3/2 electron binding energy because of the codoping of iron and nitrogen, which then resulted in the widening of the absorption of visible light range. The photocatalytic properties were studied by photocatalytical degradation of sudan Ⅰ as a model reaction in a self-assembled light-reactor. When the atomic ratio of Fe3+/Ti4+ reached 0.4%, the Fe-TiO2-xNx film showed the highest catalytic performance in degradation of sudan Ⅰ which was decomposed by up to 97% after 4 hours of photocatalytic reaction. Codoping of nitrogen and appropriate amount of iron in TiO2 enhances photoresponse and utilizing efficiency in visible light region, and then improves the performances of Fe-TiO2-xNx photocatalyst. The complex film catalyst prepared by this method will have potential application in areas of wastewater disposal.
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Received: 2008-01-08
Accepted: 2008-04-16
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Corresponding Authors:
DENG Jian
E-mail: lights7622@yahoo.com.cn
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