| 光谱学与光谱分析 |
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| Identification of Cistanche Deserticola from Boschniakla Rossica and Cynomorium Songaricum Using FTIR and Two-Dimensional Correlation IR Spectroscopy |
| CHEN Jun1，2, SUN Su-qin3, XU Rong1*, LIU You-gang4, YU Jing1, LIU Tong-ning5, LI Jian-qiang2 |
1. The Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100193, China
2. College of Agronomy and Biotechnology, China Agricultural University, Beijing 100194, China
3. Department of Chemistry, Tsinghua University, Beijing 100084, China
4. Tianjin University of Traditional Chinese Medicine，Tianjin 300193, China
5. Ningxia Yongning Plantation of Herba Cistanche, Yinchuan 750100, China |
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Abstract In the present paper, Fourier transform infrared spectroscopy (FTIR) combined with two-dimensional correlation spectroscopy (2D-IR) was used for the identification of Cistanche deserticola from its adulterants, Boschniakla rossica and Cynomorium songaricum. The results showed that these IR spectra showed their different macro-fingerprint feathers: the charactersistic peaks for Cistanche deserticola were located at ～1 730 and 931 cm-1. While absorption peaks at ～1 510, 1 375 and 1 266 cm-1 were only found in Boschniakla rossica. And the strongest peak of Cynomorium songaricum was at 1 614 cm-1. Differences were more obvious in the second derivative IR spectra: the intensities of the four peaks of Cistanche deserticola at ～1 453, 1 336, 931, and 892 cm-1 were strong, among which the peak at ～931 cm-1 was sharp and the strongest in intensity. There was the strongest peak at ～1 509 cm-1 for Boschniakla rossica. In addition, the shape of peaks at ～1 633 and 1 161 cm-1 was wider and the intensities were stronger. While the shape of peak at ～1 682 cm-1 was sharp, and also the intensity of peak at 1 605 cm-1 was stronger. According to the features of the IR spectra of each kind, a quick and accurate method based on FTIR for the identification of Cistanche deserticola was established.
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Received: 2008-05-06
Accepted: 2008-08-08
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Corresponding Authors:
XU Rong
E-mail: rxu@implad.ac.cn;sherryxr@yahoo.com.cn
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[1] The Pharmacopoeia Commission of the People’s Republic of China(国家药典委员会编). Pharmacopoeia of the People’s Republic of China Part Ⅰ(中华人民共和国药典·一部). Beijing: Chemical Industry Press(北京：化学工业出版社)，2005. 90.
[2] SONG Zhi-hong, LEI Li, TU Peng-fei(宋志宏，雷 丽，屠鹏飞). Chinese Traditional and Herbal Drugs(中草药), 2003, 34(9): 16.
[3] LIU Jing-he, LIANG Zhong-yan(刘景河，粱忠岩). Special Wild Economic Animal and Plant Research(特产研究), 2001, 24(4): 55.
[4] LIN Jia, XU Li-zhen, ZOU Zhong-mei(林 佳，徐丽珍，邹忠梅). Foreign Medical Sciences(国外医学：中医中药分册), 2003, 25(6): 332.
[5] WAN Peng, JING Xue-mei, WANG Ling(万 鹏，荆雪梅，王 苓). Lishizhen Medicine and Materia Medica Research(时珍国医国药), 1997, 8(4): 332.
[6] ZHANG Yong(张 勇). Lishizhen Medicine and Materia Medica Research(时珍国医国药), 2001, 12(3): 227.
[7] ZHANG Hao-jie, DING Xiu-fang(张浩杰, 丁秀芳). Lishizhen Medicine and Materia Medica Research(时珍国医国药), 2002, 13(3)：1831.
[8] Hua R，Sun S Q，Zhou Q，et al. J. Pharm. Biomed. Anal.，2003，33: 199.
[9] LI Ying-ming, WANG Li-qun, DENG Fen, et al(李英明，王立群，邓 芬，等). Acta Academiae Medicinae Sinicae(中国医学科学院学报)，2004，26(6): 614.
[10] LI Shu, LE Jian, CHEN Gui-liang, et al(李 树，乐 健，陈桂良，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(11): 2212.
[11] PEI Li-kuan, GUO Bao-lin, SUN Su-qin, et al(裴利宽，郭宝林，孙素琴，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(1): 55.
[12] ZHANG Lei-hong, DU Nian-sheng(张雷红, 堵年生). Chinese Traditional Patent Medicine(中成药), 2003, 25(4): 323.
[13] ZHANG Wei-jie(张惟杰). Biochemical Technology of Glycoconjugate(糖复合物生化研究技术). Hangzhou: Zhejiang University Press(杭州：浙江大学出版社), 1999. 128.
[14] SUN Su-qin, ZHOU Qun, QIN Zhu(孙素琴，周 群，秦 竹). Atlas of Two-Dimensional Correlation Infrared Spectroscopy for Traditional Chinese Medicine Identification(中药二维相关红外光谱鉴定图集). Beijing: Chemical Industry Press(北京：化学工业出版社), 2003.
[15] XIE Jing-xi, CHANG Jun-biao, WANG Xu-ming(谢晶曦，常俊标，王绪明). Applications of IR Spectra in Organic Chemistry and Pharmaceutical Chemistry(红外光谱在有机化学和药物化学中的应用). Beijing: Science Press(北京：科学出版社), 2001.
[16] Noda I. Appl. Spectrosc., 1993, 47: 1329.
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