光谱学与光谱分析 |
|
|
|
|
|
Raman Scattering Spectra of Ca3NbGa3Si2O14(CNGS) Crystals |
LAN Jian-hui1, LU Gui-wu1*, WANG Zeng-mei2, YUAN Duo-rong3, XIA Hai-rui3 |
1. College of Physics Science and Technology, China University of Petroleum, Dongying 257061, China 2. Institute of Material Science and Engineering, Ocean University of China, Qingdao 266003, China 3. National Laboratory of Crystal Material, Shandong University, Jinan 250100, China |
|
|
Abstract The CNGS crystal belongs to the trigonal system, the 32 point group and the P321 space group, which is the same as the LGS crystal. Its lattice constants are a=0.808 73 nm and c=0.497 98 nm. The primitive cell of the CNGS crystal contains only one formula unit (23 atoms). The vibration modes were measured with Raman spectroscopy technique, assigned with ab initio molecular orbit calculation method. In order to model the crystal, two clusters Ca3NbGa2SiO12 and Ca3NbGaSi2O12 were designed, and calculations were carried out on them. Their configurations were optimized, and the vibration frequencies were calculated with UHF method. By investigating the force constants and activities of the assigned Raman spectra, the structure of CNGS crystal was analyzed, and its layer structure and piezoelectric properties were confirmed. It is concluded that CNGS crystals have more excellent anisotropy and piezoelectric properties than LGS crystals.
|
Received: 2004-12-23
Accepted: 2005-08-27
|
|
Corresponding Authors:
LU Gui-wu
|
|
Cite this article: |
LAN Jian-hui,LU Gui-wu,WANG Zeng-mei, et al. Raman Scattering Spectra of Ca3NbGa3Si2O14(CNGS) Crystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 861-864.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2006/V26/I05/861 |
[1] Wang Zengmei, Cheng Xiufeng, Yuan Duorong, et al. J. Cryst. Growth, 2003, 249(1-2): 240. [2] Kang Yong Ho, Jung I I Hyoung, Joo Kyung, et al. Journal of Ceramic Processing Research, 2001, 2(4): 170. [3] Lu G W, Li C X, Wang W C, et al. Phys. Stat. Sol.(b), 2004, 241(2): 439. [4] Kaminskii A A, Mill B V, Khodzhabagyan G G, et al. Phys. Stat. Sol.(a), 1983, 80: 387. [5] Bohm J, Heimann R B, Hengst M, et al. J. Cryst. Growth, 1999, 204(1-2): 128. [6] da Cunha M P, Fagundes S de A. IEEE Trans. Ultrason. Ferroelectr. Control, 1999, 46: 1583. [7] Shimamura K, Takeda H, Kohno T, et al. J. Cryst. Growth, 1996, 163(4): 388. [8] ZHAO Peng, XIA Hai-rui, LU Gui-wu, et al(赵 朋, 夏海瑞, 卢贵武, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(1): 71. [9] Frisch M J, Tucks G W, Scuseria H B, et al. Gaussian 98(Revision A. 9, Gaussian Inc., Pittsburgh PA, 1998). [10] Hahn T. The International Tables for Crystallography Vol. A: Space Group Symmetry. Reidel, Dordreeht, 1983. [11] ZHANG Guang-yin, LAN Guo-xiang, WANG Yu-fang(张光寅, 蓝国祥, 王玉芳). Lattice Vibration Spectroscopy, Edition Ⅱ(晶格振动光谱学, 第2版). Beijing: Higher Education Press(北京: 高等教育出版社), 2001.
|
[1] |
DONG Jia-lin1, HONG Ming-jian1, 3*, ZHENG Xiang-quan2, 3, XU Yi2, 3. Discrimination of Human, Dog and Rabbit Blood Using Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 459-466. |
[2] |
ZHANG Bao-yong1,2,ZHOU Hong-ji1,2,WU Qiang1,2,GAO Xia3. Raman Spectra Characteristics of Gas Hydrate Growth with Different Driving Forces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2768-2773. |
[3] |
WU Cheng-ling1, GUO Jun-hong1, 2, YAO Heng-bin1, PAN Ling-nan1, WANG Fei1, WU Wen-qi1, JI Tong1, HU Fang-ren1, 2*. Study on the Photoluminescence Properties of ZnO Single Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1700-1702. |
[4] |
XU Dong-mei1, PAN Kun1, LIU Xu-wei1, WANG Xue-jin1*, WANG Wen-zhong2, LIANG Chun-jun3, WANG Zhi2 . Raman and Visible-Near Infrared Spectra of Cu(InGa)Se2 Films [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3197-3201. |
[5] |
WANG Guo-xiang1, WANG Hai-yan2, WANG Hu1, ZHANG Zheng-yong2, LIU Jun1 . Study on the Recognition of Liquor Age of Gujing Based on Raman Spectra and Support Vector Regression[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 729-735. |
[6] |
ZHANG Bao-yong1, 2, YU Yue1, 2*, WU Qiang1, 2, GAO Xia3 . Quantitative Analysis of the Hydration Process of Mine Gas Mixture Based on Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1912-1916. |
[7] |
LI Tao, TANG Yan-lin*, LING Zhi-gang, LONG Zheng-wen . Study on the Frontier Orbital and Raman Spectra of Aflatoxin B1 and Isomer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2122-2125. |
[8] |
LI Jing1, MAO Shi-de1*, ZHENG Hai-fei2,3 . Raman Spectroscopic Quantitative Study of NaCl-CaCl2-H2O System at High Temperatures and Pressures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1747-1753. |
[9] |
WU Dun, SUN Ruo-yu, LIU Gui-jian*, YUAN Zi-jiao. The Spectrum Studies of Structure Characteristics in Magma Contact Metamorphic Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(10): 2861-2864. |
[10] |
TAO Dong-yan, LIU Chao*, YIN Chun-hai, ZENG Yi-ping . Raman Spectra Analysis of GaN∶Er Films Prepared by Ion Implantation [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(03): 699-703. |
[11] |
HAN Jing-hua1, DUAN Tao2, FAN Wei-xing1, 3, FENG Guo-ying1*, YANG Li-ming4, NIU Rui-hua1, YANG Jie1, ZHAI Ling-ling1, GUO Chao1. Study on Characteristics of Laser Ablation in KTP Crystal and Its Influence on the Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(07): 1820-1824. |
[12] |
SHI Bin, ZHANG Hai-jun, WU Lan, ZHANG Dong-xian*. Study of the Raman-AFM System for Simultaneous Measurements of Raman Spectrum and Micro/Nano-Structures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(04): 993-996. |
[13] |
ZHANG Fei-fei, ZHENG Hai-fei*. Research on Raman Spectra of Isooctane at Ambient Temperature and Ambient Pressure to 1.2 GPa[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(03): 676-680. |
[14] |
LIANG Xiao-feng1,2,3, YIN Guang-fu2, YANG Shi-yuan1, WANG Jun-xia1 . Raman Spectrum Study of the Calcium Phosphate Glass Structure Affected by the Addition of TiO2 [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(07): 1790-1793. |
[15] |
SHEN Long-hai1, LI Qian1, WU Li-jun1, MA Yan-mei2, CUI Qi-liang2 . Raman Characterization of High-Pressure Phase Transition in AlN Nanowires[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(03): 696-699. |
|
|
|
|