光谱学与光谱分析 |
|
|
|
|
|
Tunable Fiber Laser Based Photoacoustic Spectroscopy for Acetylene Detection |
PENG Yong1, 2, YU Qing-xu1 |
1. School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116023, China 2. Department of Physics, Dalian Maritime University, Dalian 116026, China |
|
|
Abstract An acetylene detection system has been constructed with a tunable erbium-doped fiber laser (TEDFL) based photoacoustic spectrometer. Combining wavelength modulation and second harmonic signal detection technique, the system is able to effectively eliminate the background noise generated by absorption of the cell windows and the wall of the acoustic resonator. The system was applied to low concentration acetylene flowing measurement, through optimizing the systemic optics, acoustics and electron detection technique condition. The experimental results show that the second harmonic amplitude is directly proportional to gas concentration. Their linear pertinence coefficient is 0.999 53. The system sensitivity limit for acetylene detection is 0.3 ppm under atmosphere pressure with 100 ms time constant and 3.5 mW average optical power. The TEDFL was used as light source in stead of the DFB diode laser which is relatively costly. The system appears promising as a basis for developing cheap, practical, portable spectroscopy instruments for trace gas detection. The detection sensitivity could be greatly improved by using multi-path cell or increasing the laser power with EDFA.
|
Received: 2008-05-28
Accepted: 2008-08-29
|
|
Corresponding Authors:
PENG Yong
E-mail: pengting25@163.com
|
|
[1] Jacek Z K, Zbigniew L T. Proceedings of SPIE, 1998, 3731: 22. [2] KAN Rui-feng, LIU Wen-qing, ZHANG Yu-jun, et al(阚瑞峰, 刘文清, 张玉钧, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(3): 392. [3] Schilt S, Thévenaz L, Niklès M, et al. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2004, 60(14): 3259. [4] Webber M E, Pushkarsky M, Patel C K N. Applied Optics, 2003, 42: 2119. [5] Repond P, Sigrist M W. Applied Optics, 1996, 35: 4065. [6] Miklos A, Hess P, Bozoki Z. Review of Scientific Instruments, 2001, 72(4): 1937. [7] Sigrist M W. Review of Scientific Instruments, 2003,74(1): 486. [8] ZHANG Wang, YU Qing-xu(张 望,于清旭). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(3): 614. [9] Susanne Sgaard, Jes Henningsen, Jens Engholm Pedersen. SPIE, 2000, 4185: 436. [10] Silver J A. Applied Optics, 1992, 31: 707. [11] Gustafsson J, Chekalin N, Axner O. Spectrochimica Acta Part B, 2003, 58: 123. [12] Webber M E, Pushkarsky M B, Patel C K N. SPIE, 2003, 4817: 111. [13] Webber M E, Baer D S, Hanson R K. Applied Optics, 2001, 40(12): 2031. [14] Bijnen F G C, Reuss J, Harren F J M. Review of Scientific Instruments, 1996, 67(8): 2914. [15] Reid J, Labrie D. Applied Physics B, 1981, 26(3): 203.
|
[1] |
WAN Liu-jie1, 2, ZHEN Chao3, QIU Zong-jia1, LI Kang1, MA Feng-xiang3, HAN Dong1, 2, ZHANG Guo-qiang1, 2*. Research of High Precision Photoacoustic Second Harmonic Detection Technology Based on FFT Filter[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 2996-3001. |
[2] |
XIE Ying-chao1,2, WANG Rui-feng1,2, CAO Yuan1,2, LIU Kun1*, GAO Xiao-ming1,2. Research on Detecting CO2 With Off-Beam Quartz-Enhanced Photoacoustic Spectroscopy at 2.004 μm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2664-2669. |
[3] |
SONG Xiu-li1,2, YANG Hui-min1, LIU Xian1, JIAN Xuan1, LIANG Zhen-hai1*. Mechanism of the Green Cosolvent Triethylene Glycol on the Process of Electrochemical Oxidation of Acetylene[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(08): 2645-2651. |
[4] |
HE Qi-xin1, LIU Hui-fang1, LI Bin1, PAN Jiao-qing2, WANG Li-jun2, ZHENG Chuan-tao1*, WANG Yi-ding1* . Online Detection System on Acetylene with Tunable Diode Laser Absorption Spectroscopy Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(11): 3501-3505. |
[5] |
SHAO Jie1, HAN Ye-xing1, GUO Jie1, WANG Li-ming1, HAN Ying1, YING Chao-fu1, WANG Yao2 . Research on Spectrum Technology Based on SG-DBR Laser [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1774-1779. |
[6] |
SONG Ke-feng, GAO Bo, LIU An-wen, WANG Na, HU Shui-ming* . A Very Sensitive CW Cavity Ring-Down Spectrometer and Its Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(03): 835-838. |
[7] |
SUN Jian-ping1,2, MA Lin-pu1, LIN Ting1 . Photo-Induced Electron Transfer Effects of Poly(2-Methoxy-5-Octyloxy)-p-Phenylene Vinylene/Y2O3∶Eu3+ Nano-Composites [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(01): 13-17. |
[8] |
SUN Jian-ping1,2, WENG Jia-bao1,2, CHENG Yun-tao1, LIN Ting1, HUANG Xiao-zhu1. Photophysical Properties of Poly (2-Methoxy-5-Octyloxy)-p-Phenylene Vinylene/TiO2 Nano-Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(12): 2758-2762. |
[9] |
HE Ying,ZHANG Yu-jun,KAN Rui-feng,XIA Hui,WANG Min,CUI Xiao-juan,CHEN Jiu-ying,CHEN Dong,LIU Wen-qing, LIU Jian-guo. The Development of Acetylene On-Line Monitoring Technology Based on Laser Absorption Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(10): 2228-2231. |
[10] |
LU Ju-sheng, TIAN Jiu-ying, DU Bai-xiang,MIAO Xiao-qing. Study of the Sensitizing Effects of Surfactants on the Determination of Aluminum by Air-Acetylene Flame Atomic Absorption Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(09): 1858-1861. |
[11] |
TU Xing-hua, LIU Wen-qing, ZHANG Yu-jun, DONG Feng-zhong, WANG Min, WANG Tie-dong, WANG Xiao-mei, LIU Jian-guo. Second-Harmonic Detection with Tunable Diode Laser Absorption Spectroscopy of CO and CO2 at 1.58 μm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(07): 1190-1194. |
[12] |
HAO Yu-lan,ZHANG Gang-sheng*. In situ Resonance Raman Spectra of Organic Pigments in Freshwater Cultured Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(01): 78-80. |
[13] |
WU Shao-wei1, 2, YANG Xiao-qiu1,CHEN Wen-wu1, YANG Ming1, TANG Zhi-yong1, JIN Ze-xiang1* . Determination of Trace Beryllium in Geological Samples by Oxygen Doped Air-Acetylene Flame Atomic Absorption Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(05): 785-787. |
|
|
|
|