| 光谱学与光谱分析 |
|
|
|
|
|
| SEM, XRD and FTIR Investigation on Crystal Growth of Calcium Oxalate Modulated by Sodium Tartrate |
| ZHENG Hui1, CHEN Cun-yuan1, OUYANG Jian-ming1, 2* |
1. Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632, China
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China |
|
|
|
|
Abstract Crystallization of calcium oxalate (CaOxa) was investigated in the presence of sodium tartrate (Na2tart) of different concentration in a gel system by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. It was found that in the presence of a low concentration of Na2tart (0.01 mol·L-1), calcium oxalate monohydrate (COM) is the dominant crystal phase. The percentage of calcium oxalate dihydrate (COD) is less than 5%. In the XRD pattern the main diffraction peaks are (101), (020), and (202) planes of COM crystals. In the FTIR spectrum, the main asymmetric carbonyl stretching band νas(COO-) and the metal-carboxylate stretch νs(COO-) of COM occur at 1 618 and 1 317 cm-1, respectively. With the concentration of Na2tart increasing to 0.10 and 0.50 mol·L-1, the percentage of COD crystals increases to 10% and 50%, respectively, and the surface area of COM crystals decreases. The diffraction peaks that assigned to the (200), (211), (411), and (213) planes of COD crystals become stronger and stronger. The temperature can influence the modulation of Na2tart in terms of the phase composition and morphology of CaOxa crystals. As the temperature decreases, the percentage of COD increases. At a higher temperature beyond 47 ℃, COM is the dominant phase; but COM is dominant when the temperature is lower than 27 ℃. The νas(COO-) and νs(COO-) of COD crystals occur at 1 647.6 and 1 327.7 cm-1, respectively.
|
|
Received: 2005-01-17
Accepted: 2005-06-02
|
|
|
|
Corresponding Authors:
OUYANG Jian-ming
|
|
| Cite this article: |
|
ZHENG Hui,CHEN Cun-yuan,OUYANG Jian-ming. SEM, XRD and FTIR Investigation on Crystal Growth of Calcium Oxalate Modulated by Sodium Tartrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 874-878.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2006/V26/I05/874 |
[1] Huang H S, Ma M C, Chen C F, et al. Urology, 2003, 62(6): 1123.
[2] Zhang D, Qi L, Ma J, et al. Chem. Mater., 2002, 14(6): 2450.
[3] OUYANG Jian-ming(欧阳健明). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(2): 391.
[4] Selvam G S, Varalakshmi P. Med. Sci. Res., 1989, 17(16): 685.
[5] OUYANG Jian-ming, TAN Yan-hua, SHEN Yu-hua(欧阳健明, 谭燕华, 沈玉华). Acta Phy. Chim. Sinica(物理化学学报), 2003, 19(4): 368.
[6] OUYANG Jian-ming(欧阳健明). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(2): 365.
[7] Donnet M, Jongen N, Lemaitre J, et al. J. Mater. Sci. Lett., 2000, 19: 749.
[8] Cody A M, Cody R D. J. Cryst. Growth, 1995, 151: 369.
[9] OUYANG Jian-ming(欧阳健明). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(1): 170.
[10] Ouyang J M, Duan L, Tieke B. Langmuir, 2003, 19(21): 8980.
[11] Bouropoulos N, Weiner S, Addadi L. Chem. Eur. J., 2001, 7: 1881.
[12] TAN Yan-hua, OUYANG Jian-ming, MA Jie, et al(谭燕华, 欧阳健明, 马 洁, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 700.
|
| [1] |
LI Zong-xiang1, 2, ZHANG Ming-qian1*, YANG Zhi-bin1, DING Cong1, LIU Yu1, HUANG Ge1. Application of FTIR and XRD in Coal Structural Analysis of Fault
Tectonic[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 657-664. |
| [2] |
ZHANG Hao1, 2, HAN Wei-sheng1, CHENG Zheng-ming3, FAN Wei-wei1, LONG Hong-ming2, LIU Zi-min4, ZHANG Gui-wen5. Thermal Oxidative Aging Mechanism of Modified Steel Slag/Rubber Composites Based on SEM and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3906-3912. |
| [3] |
HE Xiong-fei1, 2, HUANG Wei3, TANG Gang3, ZHANG Hao3*. Mechanism Investigation of Cement-Based Permeable Crystalline Waterproof Material Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3909-3914. |
| [4] |
Samy M. El-Megharbel*，Moamen S. Refat. In First Time: Synthesis and Spectroscopic Interpretations of Manganese(Ⅱ), Nickel(Ⅱ) and Mercury(Ⅱ) Clidinium Bromide Drug Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3316-3320. |
| [5] |
Samy M. El-Megharbel*, Moamen S. Refat. Preparations and Spectroscopic Studies on the Three New Strontium(Ⅱ), Barium(Ⅱ), and Lead(Ⅱ) Carbocysteine Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2975-2979. |
| [6] |
WANG Yi1, 2, LI Chang-rong1, 2*, ZHUANG Chang-ling1, 2. Study on Alumina/Lanthanum Oxide X-Ray Diffraction and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2480-2483. |
| [7] |
LI Huan-tong1, 2, CAO Dai-yong3*, ZHANG Wei-guo1, 2, WANG Lu4. XRD and Raman Spectroscopy Characterization of Graphitization Trajectories of High-Rank Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2491-2498. |
| [8] |
YE Xu1, QIU Zhi-li1, 2*, CHEN Chao-yang3, ZHANG Yue-feng1. Nondestructive Identification of Mineral Inclusions by Raman Mapping: Micro-Magnetite Inclusions in Iridescent Scapolite as Example[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2105-2109. |
| [9] |
SUN Feng1, 2, YAN Qing-qing1, WANG Lu1, SUN Zhen-fei1. Study on the Conditions of Hydrothermal Synthesis of Chinese Purple BaCuSi2O6 and the Analysis of Its Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2284-2287. |
| [10] |
Khaled Althubeiti. Synthesis and Structural Characterizations of Ternary Iron(Ⅱ) Mixed Ligand Complex: Low Cost Materialsas a Precursor for Preparation of Nanometric Fe2O3 Oxide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1988-1992. |
| [11] |
TANG Gu-hua, ZHANG Hui, SUN Xin-yuan, XU Meng, OUYANG Jian-ming*. Differences in Adsorption of Anionic Surfactant AOT by Calcium Oxalate Dihydrate With Different Morphologies[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1079-1085. |
| [12] |
HUANG Wei-bo, CHEN Jia-yun, HUANG Fang, HUANG Li-shan, OUYANG Jian-ming*. Effects of Different Molecular Weight of Gracilaria Lemaneiformis Polysaccharide on Calcium Oxalate Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1163-1170. |
| [13] |
ZHANG Zhi-dan1, ZHAO Min-shuang1, ZHANG Li-na1, LIU Hang1, LI Rui1, SHENG Qian-nan1, GUO Dan1, ZHAO Xiao-yi2, ZHANG Jin-jing1*, ZHONG Shuang-ling1*. Application of Synchrotron Radiation X-Ray Diffraction Spectroscopy in the Study of Clay Minerals in Zonal Forest Soils[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 529-534. |
| [14] |
Moamen S. Refat1*, Amnah M. Alsuhaibani2, Mohamed Nagaty1. Infrared Spectroscopy and Morphological Assessments on the Nutritional Value of Prickly Pear Fruit[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 648-653. |
| [15] |
GE Tao1, 2, LI Yang1, Wang Meng2, CHEN Ping3, MIN Fan-fei1, ZHANG Ming-xu1. Spectroscopic Characterization of Carbon Structure in High Sulfur Fat Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 45-51. |
|
|
|
|
