| 光谱学与光谱分析 |
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| Nonlinear Kalman Filter Simultaneous Determination of Mixture of Phenol and 2-Chlorophenol |
| WANG Qiang1, 2, MA Pei-sheng1,TANG Hong-mei1, 2,JIA Qing-zhu1 |
1. College of Chemical Engineering, Tianjin University, Tianjin 300072, China
2. College of Chemical Engineering, Tianjin University of Science and Technology, Tianjin 300222，China |
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Abstract An analysis method of nonlinear absorbance for binary composition mixture was proposed. The nonlinear absorbance was composed of the contributions from both themselves and the change in their contributions due to mixing, as well as the contribution from their interaction. The mixture of phenol and 2-chlorophenol was simultaneously determined using nonlinear Kalman filter UV spectrophotometry. UV absorption spectra were obtained with 32 standard solutions (range 1-15 mg·L-1) and 71 wavelengths(250-290 nm). Standard work matrix of extended Kalman filter was performed from partial least-squares method. The vectors function Jacobi matrix was obtained by linearization of Taylor series for nonlinear absorbance formula. The recovery experiment showed that the extended Kalman filter simultaneous determination of mixture of phenol and 2-chlorophenol that is not only exact, but also stable.
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Received: 2005-11-10
Accepted: 2006-02-16
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Corresponding Authors:
WANG Qiang
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| Cite this article: |
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WANG Qiang,MA Pei-sheng,TANG Hong-mei, et al. Nonlinear Kalman Filter Simultaneous Determination of Mixture of Phenol and 2-Chlorophenol[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 899-903.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I05/899 |
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