| 光谱学与光谱分析 |
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| Interaction Models of Cucurbit(n=6,7,8) Urils and Imidazo[4,5，f]1,10-Phenanthroline Derivates |
| WANG Qiu-li1,XUE Sai-feng1*,MU Lan1,ZHU Qian-jiang1,TAO Zhu1,ZHANG Jian-xin2 |
1. Institute of Applied Chemistry, Guizhou University, Guiyang 550025, China
2. Key Laboratory of Chemistry for Natural Products of Guizhou Province, Guiyang 550002, China |
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Abstract The interaction structures and optical properties of host-guest of cucurbit[n=6-8]urils with synthesized three imidazo-[4,5,f]1,10-phenathroline derivates were investigated by using 1H NMR technique, fluorescence spectrophotometry, and ultraviolet spectrophotometry. The experimental results reveal that cucurbit [6] uril (Q[6]) can only interact with guest salt of 2-(4-methyl)-phenyl-imidazo-[4,5,f]1,10-phenathroline (W1) with a ratio of 1∶1; however, cucurbit [7] uril (Q[7])can interact with all three guest salts of 2-(4-methylphenyl)-imidazo-[4,5,f]1,10-phenathroline(W1), 2-(2-methylphenyl)-imidazo-[4,5,f]1,10-phenathroline(W2)，and 2-(3-methyloxyl phenyl)-imidazo-[4,5,f]1,10-phenathroline(W3) with the same ratio of 1∶1; cucurbit [8] uril (Q[8]), except interaction with W1 with a ratio of 1∶2, can also interact with W2 and W3 with a ratio of 1∶1.
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Received: 2004-12-02
Accepted: 2005-04-28
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Corresponding Authors:
XUE Sai-feng
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| Cite this article: |
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WANG Qiu-li,XUE Sai-feng,MU Lan, et al. Interaction Models of Cucurbit(n=6,7,8) Urils and Imidazo[4,5，f]1,10-Phenanthroline Derivates [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(03): 499-504.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I03/499 |
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