| 光谱学与光谱分析 |
|
|
|
|
|
| Research of FTIR and XRD Study on the Organic Modification of Bentonites |
| ZHENG Yu-ying,WANG Can-yao,FU Ming-lian |
| College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China |
|
|
|
|
Abstract Organobentonites were prepared to improve the compatibility between bentonites and organic phase. The change of lamellar structure after organic modification was observed. Na+-bentonites and octadecylamine were used to exchange the Na+ which is in the layers of bentonites, and the organobentonites were obtained. Both FTIR and DTA-TG proved that octadecylamine entered the layers of bentonites, and XRD showed that the lamellar distance increased from 1.4 nm to 4.3 nm. Based on the experiment, most of the properties of Na+-bentonites such as the ethylene blue adsorbed by bentonites, cation exchange capacity and the like are better than Ca2+-bentonites’. The bentonites modified by octadecylamine improved the hydrophobic ability and widened the lamellar distance of bentonites, which contributes to enhancing the whole properties of composites.
|
|
Received: 2004-04-16
Accepted: 2004-07-28
|
|
|
|
Corresponding Authors:
ZHENG Yu-ying
|
|
| Cite this article: |
|
ZHENG Yu-ying,WANG Can-yao,FU Ming-lian. Research of FTIR and XRD Study on the Organic Modification of Bentonites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(11): 1813-1816.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2005/V25/I11/1813 |
[1] WANG Ke, ZHU Zhan, GUO Bing-nan, et al(王 珂，朱 湛, 郭炳南, 等). J. of Beijing Institute of Technology(北京理工大学学报)，2002，22(2): 240.
[2] XIAO Ming-yan, CHEN Jian-min(肖明艳，陈建敏). Polymer Material Science and Engineering(高分子材料科学与工程)，2001，17(5)：6.
[3] Ellsworth M W, Gin D L. Polymer News, 1999, 24: 331.
[4] Carotenuto G. Polymer News, 2000, 25: 191.
[5] Fu X, Qutubuddin S. Polymer, 2001, 42: 807.
[6] Kor nmann X, Linderg H, Berglund L A. Polymer, 2001, 42(10) : 4493.
[7] Huang J C, Zhu Z K, Kin J, et al. Polymer, 2001, 42(3): 873.
[8] ZHANG Yong-nian, WANG Shu-ping, QIAO Shi-de, et al(张永年, 王淑萍, 乔世德, 等). Non-Metallic Mines(非金属矿)，1996，(4)：15.
[9] ZHANG Xue-qin, LI Yang, HUANG Ling, PAN Yuan-jiang(张雪芹, 李 杨, 黄 铃, 潘远江). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2002，22(2)：229.
[10] ZENG Xin-an, ZHANG Ben-shan, GENG Yu-huan( 曾新安, 张本山, 耿予欢). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2002，22 (1)：29.
[11] ZHENG Yu-ying, FU Ming-lian, CAI Wei-long, et al (郑玉婴, 傅明连, 蔡伟龙, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，待发表.
|
| [1] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
| [2] |
ZONG Zhi-fang1, 2, 3, LONG Hong-ming1*, Yilin Gui3*, ZHANG Hao1, 2, DONG Wei2, ZHOU Xiao-hui2, JI Yi-long1. Microstructure Characteristics of Nano Solid Waste High Sulfur Cement Based on XRD and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1974-1980. |
| [3] |
XU Qi-lei, GUO Lu-yu, DU Kang, SHAN Bao-ming, ZHANG Fang-kun*. A Hybrid Shrinkage Strategy Based on Variable Stable Weighted for Solution Concentration Measurement in Crystallization Via ATR-FTIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1413-1418. |
| [4] |
KAN Yu-na1, LÜ Si-qi1, SHEN Zhe1, ZHANG Yi-meng1, WU Qin-xian1, PAN Ming-zhu1, 2*, ZHAI Sheng-cheng1, 2*. Study on Polyols Liquefaction Process of Chinese Sweet Gum (Liquidambar formosana) Fruit by FTIR Spectra With Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1212-1217. |
| [5] |
YUE Kong, LU Dong, SONG Xue-song. Influence of Thermal Modification on Poplar Strength Class by Fourier Infrared Spectroscopy Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 848-853. |
| [6] |
YAN Li-dong1, ZHU Ya-ming1*, CHENG Jun-xia1, GAO Li-juan1, BAI Yong-hui2, ZHAO Xue-fei1*. Study on the Correlation Between Pyrolysis Characteristics and Molecular Structure of Lignite Thermal Extract[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 962-968. |
| [7] |
LI Zong-xiang1, 2, ZHANG Ming-qian1*, YANG Zhi-bin1, DING Cong1, LIU Yu1, HUANG Ge1. Application of FTIR and XRD in Coal Structural Analysis of Fault
Tectonic[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 657-664. |
| [8] |
CHENG Xiao-xiao1, 2, LIU Jian-guo1, XU Liang1*, XU Han-yang1, JIN Ling1, SHEN Xian-chun1, SUN Yong-feng1. Quantitative Analysis and Source of Trans-Boundary Gas Pollution in Industrial Park[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3762-3769. |
| [9] |
ZHANG Hao1, 2, HAN Wei-sheng1, CHENG Zheng-ming3, FAN Wei-wei1, LONG Hong-ming2, LIU Zi-min4, ZHANG Gui-wen5. Thermal Oxidative Aging Mechanism of Modified Steel Slag/Rubber Composites Based on SEM and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3906-3912. |
| [10] |
WANG Xu-yang1, SUN Tao1, ZHU Xin-ping1, TANG Guang-mu2, JIA Hong-tao1*, XU Wan-li2. Phosphorus Species of Biochar Modified by Phosphoric Acid and
Pyrophosphoric Acid Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3084-3090. |
| [11] |
ZHANG Yuan, BI Xiao-qian, LI Ping, LI Xian-jun, YUAN Guang-ming, ZUO Ying-feng*. Study on Strengthening and Fixation Mechanism of Chinese Fir Modified by Silica-Magnesium Gel[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2437-2443. |
| [12] |
CHEN Jing-yi1, ZHU Nan2, ZAN Jia-nan3, XIAO Zi-kang1, ZHENG Jing1, LIU Chang1, SHEN Rui1, WANG Fang1, 3*, LIU Yun-fei3, JIANG Ling3. IR Characterizations of Ribavirin, Chloroquine Diphosphate and
Abidol Hydrochloride[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2047-2055. |
| [13] |
WANG Xue-pei1, 2, ZHANG Lu-wei1, 2, BAI Xue-bing3, MO Xian-bin1, ZHANG Xiao-shuan1, 2*. Infrared Spectral Characterization of Ultraviolet Ozone Treatment on Substrate Surface for Flexible Electronics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1867-1873. |
| [14] |
MA Fang1, HUANG An-min2, ZHANG Qiu-hui1*. Discrimination of Four Black Heartwoods Using FTIR Spectroscopy and
Clustering Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1915-1921. |
| [15] |
ZHANG Dian-kai1, LI Yan-hong1*, ZI Chang-yu1, ZHANG Yuan-qin1, YANG Rong1, TIAN Guo-cai2, ZHAO Wen-bo1. Molecular Structure and Molecular Simulation of Eshan Lignite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1293-1298. |
|
|
|
|
