光谱学与光谱分析 |
|
|
|
|
|
Application of X-Ray Photoelectron Spectroscopy to the Study of Complexes and Its Progress |
YUAN Huan-xin, OUYANG Jian-ming* |
Department of Chemistry, Jinan University, Guangzhou 510632, China |
|
|
Abstract X-ray photoelectron spectroscopy (XPS) provides information about the core-level binding energies and oxidation states of complexes. It can be used to identify the species and valence states of elements, measure the relative content of elements, investigate the interaction between ligands and central ions, and verify the results obtained by quantum chemistry theory. XPS has been found to be a powerful tool for identifying coordination site, evaluating charge redistribution, and characterizing geometry of complexes.
|
Received: 2005-07-08
Accepted: 2005-10-28
|
|
Corresponding Authors:
OUYANG Jian-ming
E-mail: toyjm@jnu.edu.cn
|
|
Cite this article: |
YUAN Huan-xin,OUYANG Jian-ming. Application of X-Ray Photoelectron Spectroscopy to the Study of Complexes and Its Progress[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(02): 395-399.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2007/V27/I02/395 |
[1] Zhang H, Yang B. Thin Solid Films, 2002, 418: 169. [2] Yehya M, Kelly P J. Surf. Coat. Technol., 2003, 174-175: 286. [3] Artyushkova K, Fulghum J E. J. Electron. Spectrosc. Relat. Phenom., 2001, 121: 33. [4] OUYANG Jian-ming, BAI Yu, YU Gui, et al(欧阳健明, 白 钰, 于 贵, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(4): 499. [5] Kim Y J, Park C R. Inorg. Chem., 2002, 41(24): 6211. [6] DU Xi-guang, DU Guo-tong, MA Chun-yu, et al(杜锡光, 杜国同, 马春雨, 等). J. Mol. Sci.(分子科学学报), 2003, 19(4): 241. [7] CHENG Xian-su, SU Ying-cao, GUAN Huai-min(程贤甦, 苏英草, 关怀民). J. Mol. Sci.(分子科学学报), 2000, 16(2): 118. [8] Bernardt P V, Flanagan B M, Riley M J, et al. J. Electron. Spectrosc. Relat. Phenom., 2002, 124: 73. [9] ZHANG Yi-heng, FENG Shao-hong, GONG Zhu-fang, et al(张宜恒, 冯少红, 宫竹芳, 等). Photographic Science and Photochemistry(感光科学与光化学), 2001, 19(1): 19. [10] JIN Dou-man, YANG Rui-na, WANG Dong-mei, et al(金斗满, 杨瑞娜, 王冬梅, 等). Chin. J. Inorg. Chem.(无机化学学报), 2000, 16(2): 335. [11] Bhargava S K, Mohr F, Gorman J D. J. Organomet. Chem., 2000, 607: 93. [12] Wu J B, Lin Y F, Wang J L, et al. Inorg. Chem., 2003, 42: 4516. [13] Ding M, De Jong B H W S, Roosendaal S J, et al. Geochim. Cosmochim. Acta, 2000, 64(7): 1209. [14] Miao Q, Yie X G, Xin X Q, et al. Appl. Surf. Sci., 2001, 171: 49. |
[1] |
CI Cheng-gang*, ZANG Jie-chao, LI Ming-fei*. DFT Study on Spectra of Mn-Carbonyl Molecular Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1434-1441. |
[2] |
FAN Chun-hui1, 2, ZHENG Jin-huan3, LIU Hong-xin1. FTIR, 2D-IR and XPS Analyses on the Mechanism of Protoplast Derived From Calendula Officinalis in Response to Lead and Cadmium in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1420-1425. |
[3] |
SHAO Ke-man, FU Gui-yu, CHEN Su-yan, HONG Cheng-yi, LIN Zheng-zhong*, HUANG Zhi-yong*. Preparation of Molecularly Imprinted Fluorescent Probe for Rare Earth Complex and Determination of Malachite Green Residue[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 808-813. |
[4] |
HE Xiong-fei1, 2, HUANG Wei3, TANG Gang3, ZHANG Hao3*. Mechanism Investigation of Cement-Based Permeable Crystalline Waterproof Material Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3909-3914. |
[5] |
LI Ping1,2, WU Yi-qiang1, LÜ Jian-xiong3, YUAN Guang-ming1, ZUO Ying-feng1*. Effect of Biomimetic Respiration Method on the Impregnation Effect of Silicate Modified Chinese Fir by XPS and FTIR Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1430-1435. |
[6] |
GE Tao1, 2, LI Yang1, Wang Meng2, CHEN Ping3, MIN Fan-fei1, ZHANG Ming-xu1. Spectroscopic Characterization of Carbon Structure in High Sulfur Fat Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 45-51. |
[7] |
GE Tao1,2, LI Yang1, WANG Meng2, LI Fen1, ZHANG Ming-xu1. Structural Characterization and Molecular Model Construction of Gas-Fat Coal With High Sulfur in Shanxi[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3373-3378. |
[8] |
LIU Xiu-yu, ZHANG Bing, ZHANG Hao, DU Xiao-yan, TANG Gang*. Research of Flame Retardant Mechanism for RPUF/EG Composites Based on TG-FTIR and XPS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1626-1633. |
[9] |
GE Tao1,3, CAI Chuan-chuan1, CHEN Ping3, MIN Fan-fei1, ZHANG Ming-xu1. The Characterization on Organic Sulfur Occurrence in Coking Coal and Mechanism of Microwave Actionon Thiophene[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1321-1327. |
[10] |
LI Zhi-yuan1, LIU Xue-lian1,2, ZHENG An-dong1, WANG Guo-dong1, XIA Guo1,3, LU Hong-bo1,2*. Research on the Spectral Analysis and Stability of Ultraviolet-Enhanced Thin Films with Stable and Tunable Graphene Oxide-Rare Earth Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 379-384. |
[11] |
LIN Qing-feng, ZHOU Liang-liang, SUN Yan-qiong*, CHEN Yi-ping. The Hydrothermal Synthesis, Crystal Structure and Spectral Properties of a 2D Pr-Cd Heterometal Complex[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(10): 3034-3039. |
[12] |
LI Zhao, CAO Jing, WANG Yong-feng. Synthesis and Spectral Properties of Phosphors Based on Schiff Base Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2879-2882. |
[13] |
PENG Chen-jia1, WANG Ke-hua1*, LU Wei-xue1, GUAN Chun-qian1, HU Ya-jing1, MA Shuang1, ZHU Ming-chang2, GAO En-jun2. Synthesis, Crystal Structure and DNA/BSA Interaction of a Ni(Ⅱ) Coordination Compound[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 559-564. |
[14] |
HAN Li-nan, LIU Zi-zhong*, LIU Hong-xia, SHEN Chen-fei. Correlation Between the Ring Stretching Vibration Raman Spectroscopic Frequency and Aromaticity for Half Sandwich Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 114-122. |
[15] |
SU Ya-jing, FAN Ting-ting, ZHANG Mei-na, LI Xia*. 4,4’-Bipyridine Bridged Chain Zn(Ⅱ) Complex: Synthesis, Crystal Structure and Fluorescence Sensitization for Tb (Ⅲ) Ion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2170-2174. |
|
|
|
|