| 光谱学与光谱分析 |
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| Studies on the Anion Recognition of N-Aryl-N′-(4-Ethyloxybenzoyl) Thioureas Derivatives by Spectroscopy |
| HU Jing-han1,XU Wei-xia2,WEI Tai-bao2 |
1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
2. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China |
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Abstract The interactions of N-aryl-N′-(4-ethyloxybenzoyl) thioureas derivatives and anions such as F-,Cl-,Br-,I-,CH3COO-,H2PO-4,HSO-4 and NO-3 in DMSO were investigated by UV-Vis and 1H NMR spectroscopy. The results showed that hydrogen-bonding complexes were formed between receptors and the three anions such as F-,CH3COO- and H2PO-4,and the solutions turned light yellow from colorlessness, but there had no evident binding with Cl-,Br-,I-,HSO-4 and NO-3. It was regular that the two receptors had different binding ability with F-,CH3COO- and H2PO-4. For the same anion, the association constants followed the trend: receptor 1a> receptor 1b. The UV-Vis data indicated that a 1∶1 stoichiometry complex was formed.
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Received: 2005-12-16
Accepted: 2006-03-28
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Corresponding Authors:
HU Jing-han
E-mail: hujinghan62@163.com
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| Cite this article: |
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HU Jing-han,XU Wei-xia,WEI Tai-bao. Studies on the Anion Recognition of N-Aryl-N′-(4-Ethyloxybenzoyl) Thioureas Derivatives by Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(06): 1172-1175.
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https://www.gpxygpfx.com/EN/Y2007/V27/I06/1172 |
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