光谱学与光谱分析 |
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Synthesis of Two Different Structural Aromatic Carboxylic Acid Complexes with Terbium by Solid State Reaction at Low Temperature and Studies on Luminescence Property |
LI Wen-xian,ZHANG Rui-ping,GUO Lei,XIA Hai-ting,CHEN Li-juan |
College of Chemistry and Chemical Industry,Inner Mongolia University,Hohhot 010021,China |
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Abstract Two solid complexes of terbium with phenylacetic acid (L1) and phenyl-hydroxylacetic acid (L2) were synthesized by solid state reaction at low temperature,and the complexes were characterized by chemical analysis. Elemental analysis and rare earth coordination titration studies suggested that the composition of the complexes is Tb(L1)3·H2O and Tb(L2)3·4H2O respectively. IR spectra and 1H NMR studies indicated that the coordination fashion of the two ligands with Tb(Ⅲ) is different. The ligand (L1) is bonded with Tb(Ⅲ) ions by two oxygen atoms in carboxyl group which coordinate as a symmetrical chelate bidentate group. The ligand (L2) is bonded with Tb(Ⅲ) ions by one oxygen atom in carboxyl group. The molar conductivity in DMSO solvent indicates that all complexes are non-electrolyte. The fluorescence spectra of complexes and phosphorescence spectra of the ligands showed that all of the two ligands were sensitized differently by Tb3+ ions for fluorescence intensity,which indicates that the triplet state energy of ligands and the different structure of complexes play an important role in the luminescence of complexes. Fluorescence intensity of Tb(L1)3·H2O is smaller than that of Tb(L2)3·4H2O. So the structure of ligand carboxylic acid has an effect on Tb3+ luminescence in these complexes.
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Received: 2006-03-16
Accepted: 2006-06-28
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Corresponding Authors:
LI Wen-xian
E-mail: nmglwx@163.com
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Cite this article: |
LI Wen-xian,ZHANG Rui-ping,GUO Lei, et al. Synthesis of Two Different Structural Aromatic Carboxylic Acid Complexes with Terbium by Solid State Reaction at Low Temperature and Studies on Luminescence Property[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(07): 1279-1282.
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URL: |
https://www.gpxygpfx.com/EN/Y2007/V27/I07/1279 |
[1] Bassi P S,Chopra G S,Kanwaljit Kaur. Indian Journal of Chemistry,1990,29A(5): 454. [2] SHI Xu-hua,LI Dan,FENG Qiao,et al(石旭华,李 丹,冯 巧,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2003,23(3): 529. [3] Lü Jing-ci,CHEN Jun-sheng,SU De-qing,et al(吕敬慈,陈军生,苏德庆,等). Chemical Journal of Chinese Universities(高等学校化学学报),1997,18(8): 1262. [4] YANG Yu,JIA Dian-zeng,GE Wei-wei(杨 彧,贾殿赠,葛炜炜). Chinese Journal of Inorganic Chemistry(无机化学学报),2004,20(8): 881. [5] DING Yun-feng,YU Xi-bin,XIONG Juan,et al(丁云峰,余锡宾,熊 娟,等). Chinese Rare Earth(稀土),2003,24(4): 18. [6] LI Wen-xian,TIAN Gui-xiang,GAO Jin-feng(李文先,田桂香,高金凤). Chemical Reagent(化学试剂),2003,25(1): 8. [7] Deacon G B,Phillips R J. Coord. Chem. Rev.,1980,33(3): 227. [8] Manhass B S,Trikha A K. J. Indian Chem. Soc.,1982,59(2): 315. [9] LI Bin,ZHANG Hong-jie,MA Jian-fang(李 斌,张洪杰,马建方). Chinese Journal of Chemical Physics(化学物理学报),1998,11(2): 152. [10] YAN Lai,ZHAO Yong-liang,ZHAO Feng-ying,et al(燕 来,赵永亮,赵凤英,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(5): 928. |
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