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| Eco-Friendly Fabrication of Selenium Nanoparticles by Solidstate Thermal Decomposition of SeCl4-L-Glutamine Precursor: Spectroscopic Characterizations |
| Sattam Al-Otaibi* |
| College of Engineering, Taif University, Al-Haweiah, Taif 21974, Saudi Arabia |
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Abstract In this article, spherical black spots-like selenium metal nanoparticles were synthesized. Accordingly, this experimental work proposed an innovative facile, green, one-step and solvent-free strategy to a large scale synthesis of Se-NPs via thermal decomposition of green precursor. The Se(Ⅳ) L-glutamine precursor was prepared by solid state grinding using selenium(Ⅳ) tetrachloride, SeCl4, and L-glutamine for 2 hr without using any organic solvent. It was characterized by infrared spectroscopy, and micro analytical. The solid precursor compound was subsequently annealed in the muffle furnace at 300 ℃ for 3 hr in static air. Selenium NPs was resulted and well characterized using X-ray powder diffraction (XRD), FT-IR spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The FTIR and XRD data showed that the Se NPs is pure and has a good crystalline structure because no characteristic peaks of impurity were detected, while the SEM and TEM results showed that the obtained product is tiny, aggregated with spherical-like shape, narrow size distribution with an average size between 5～10 nm. Results show that the solid state thermal decomposition method is simple, eco-friendly, safe and suitable for preparation of SeNPs. This method can also be applied to synthesize nanoparticles pure metal and metal oxides.
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Received: 2020-04-24
Accepted: 2020-08-08
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Corresponding Authors:
Sattam Al-Otaibi
E-mail: dr.sattam.alotaibi@gmail.com; srotaibi@tu.edu.sa
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[1] Ma L, Liu J. iScience, 2020, 23(124): 100815.
[2] Shih P H, Do T N, Gumbs G, et al. Physica E: Low-dimensional Systems and Nanostructures, 2020, 118: 113894.
[3] López-Díaz D, Solana A, García-Fierro J L, et al. J. Luminescence, 2020，219：116954.
[4] Odeniyi M A, Okumah V C, Adebayo-Tayo B C, et al. Sustainable Chemistry and Pharmacy, 2020，15：100197.
[5] Do M, Stinson K, George R. Biochemistry and Biophysics Reports, 2020, 22: 100745.
[6] Harsij M, Kanani H G, Adineh H. Aquaculture, 2020, 52115: 734942.
[7] Alotaibi S, Manjunathan K N, Paul S. Applied Surface Science, 2017, 424(3): 330.
[8] Mo R, Li J, Tang Y, et al. Appl. Surface Sci., 2019，47615：552.
[9] Kumar A, Sevonkaev I, Goia D V. Journal of Colloid and Interface Science, 2014，41615：119.
[10] Yu B, You P, Song M, et al. New J. Chem., 2016，40：1118.
[11] Zhang S Y, Zhang J, Wang H Y, et al. Materials Letters, 2004, 58: 2590.
[12] Wang H, Zhang J, Yu H. Free Radic. Biol. Med., 2007, 42: 1524.
[13] Husen A, Siddiqi K S. J. Nanobiotechnology, 2014, 12: 28.
[14] Fesharaki P J, Nazari P, Shakibaie M, et al. Braz. J.Microbiol., 2010, 41: 461.
[15] Lortie L, Gould W D, Rajan S, et al. Appl. Environ. Microbiol., 1992, 58: 4042.
[16] Husen A, Siddiqi K S. Nano Res. Lett., 2014, 9: 229.
[17] Prakash N T, Sharma N, Prakash R, et al. Biotechnol. Lett., 2009，31：1857.
[18] Chen W, Yue L, Jiang Q, et al. Int. J. Biol. Macromolecules, 2018, 11415: 751.
[19] Zhu H, Sun M, Yang X. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008，320(1-31)：74.
[20] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Fourth ed., Wiley, New York, 1986.
[21] Overschelde O V, Guisbiers G. Opt. Laser Technol., 2015，73：156.
[22] Shakibaie M, Forootanfar H, Golkari Y, et al. Journal of Trace Elements in Medicine and Biology, 2015，29：235.
[23] Hemalatha T, Krithiga G, Kumar B S, et al. Acta Metallurgica Sinica (English Letters), 2014, 27: 1152.
[24] Nair B, Pradeep T. Crystal Growth & Design, 2002, 2: 293.
[25] Cullity B D, Stock S R. Elements of X-Ray Diffraction, 3rd ed., New York: Prentice Hall，2001.389. |
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