|
|
|
|
|
|
| Luminescence of Erbium Doped Telluride Glass Enhanced by Surface Plasmon of Metallic Silver Nanoparticles |
| CHEN Xiao-bo1, LI Song1, ZHAO Guo-ying2, LONG Jiang-mi1, WANG Shui-feng1, ZHENG Dong1, WU Zheng-long1, MENG Shao-hua2, GUO Jing-hua1, XU Ling-zhi2, YU Chun-lei3, HU Li-li3 |
1. Applied Optics Beijing Area Major Laboratory and Physics Department, Beijing Normal University, Beijing 100875, China
2. School of Materials Science and Technology, Shanghai Institute of Technology, Shanghai 200235, China
3. Shanghai Institute of the Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China |
|
|
|
|
Abstract Interesting optical properties of metal surface plasmon, especially the behavior on luminescence enhancement field, have become a hot research topic globally. The surface plasmon is just a kind of collective oscillation made of free electron and light electromagnetic fields because their resonant frequencies are similar when they are interacting with each other. In present paper, the erbium luminescence resonant enhanced by surface plasmon of Ag nanoparticles (NPs) in telluride glass is studied. The absorption, excitation, luminescence spectra, and lifetime are measured. First, we select the 365.5 and 379.0 nm excitation peaks as excitation wavelength to measure the visible luminescence spectra in the wave range of 385～780 nm. We find 4 luminescence peaks positioned at 408.0, 525.0, 546.0, and 658.5 nm. They are, respectively, the fluorescence transitions of 2H9/2→4I15/2, 2H11/2→4I15/2, 4S3/2→4I15/2, and 4F9/2→4I15/2 of Er3+ ions. It is easy to calculate the peak intensities of the above 4 visible luminescence of (A) Er3+(0.5%)Ag(0.2%): Telluride glass with the average diameter of 80 nm for Ag NPs are about 1.44～2.52 times larger than that of the (C) Er3+(0.5%): Telluride glass. Moreover, the peak intensities of the above 4 visible luminescence spectra of (B) Er3+(0.5%)Ag(0.2%): Telluride glass with the average diameter of 50 nm for Ag NPs are about 1.08～1.55 times larger than that of the sample (C). Then, we select the 365.5 and 379.0 nm excitation peaks as excitation wavelength to measure the near infrared luminescence spectra in the wave range of 928～1 680 nm. It is found that near infrared luminescence peaks are positioned at 979.0 and 1 530.0 nm. They are, respectively, the fluorescence transitions of 4I11/2→4I15/2 and 4I13/2→4I15/2 of Er3+ ions. The peak intensities of the above 2 near infrared luminescence spectra of sample (A) are about 1.43～2.14 times larger than that of the sample (C). Similarly, the peak intensities of the above 2 near infrared luminescence spectra of sample (B) are about 1.28～1.82 times larger than that of the sample (C). Therefore, the largest enhancement is about 2.52 times larger. From the experiments of fluorescence lifetime dynamics, we find that the 550 nm fluorescence lifetime of sample (A) is about τA(550)=43.5 μs, that of sample (B) is about τB(550)=43.2 μs, and that of sample (C) is about τC(550)=48.6 μs. The experimental results illustrate that τA≈τB＜τC. This means that the luminescence enhancement of sample (B) relative to sample (C) results from the spontaneous radiation enhancement effect. However, this also means that the luminescence enhancement of sample (A) relative to sample (B) results from the Size r effect, in which the increased of the scattering cross section Cs is much larger than that of the absorption cross section Ca when r is enlarged, because the scattering cross-section Cs are proportional positive ratio to r6 and the absorption cross-section Ca are proportional positive ratio to r3. As we know that the scattering cross-section Cs is the reason for the increase of fluorescence, meanwhile the absorption cross-section Ca is the reason for the decease of fluorescence. When r is increase, scattering cross-section Cs is the main part. When luminescent material couples with the metallic surface Plasmon, the energy is transferred quickly to metallic surface Plasmon, and then scattered to the far field. It’s beneficial for the enhancement of fluorescence. As a comprehensive result, the fluorescence is enhanced when r is enlarged. It has excellent application prospects in the optogalvanic electricity generation of solar cell and biophysical application other as well as fields.
|
|
Received: 2018-05-19
Accepted: 2018-10-14
|
|
|
|
[1] Song Z F. Principle and Application of Atomic Spectroscopy and Crystal Spectroscopy. Beijing: Science Press, 1987.
[2] Yang Z, Ni W H, Yan C H, et al. J. Phys. Chem. C，2008, 112(48): 18895.
[3] Luo Q, Chen Y R, Li Z Q, et al. Nanotechnology，2014, 25(18): 185401.
[4] Zhan Q Q, Zhang X, He S L, et al. Laser & Photonics Rev.，2015, 9(5): 479.
[5] Cheng F R, Jing X P, Wang Z Y. Phys. Chem. Chem. Phys.，2015, 17(5): 3689.
[6] Yin Z, Xu W, Song H W, et al. Advanced Materials，2016, 28(13): 2518.
[7] Trupke T, Shalav A, Green M A, et al. Solar Energy Materials & Solar Cells，2006, 90(18-19): 3327.
[8] Mie G. Annalen der Physik，1908, 25(3): 377.
[9] Mahrazl Z A S, Sahar M R, Ghoshal S K, et al. Mater. Lett., 2013, 112: 136.
[10] Reisfeld R. Lasers and Excited States of Rare-Earth, Springer-Verlag, 1977.
[11] Wu Jianghong, Cheng Peihong, Bao Jilong, et al. Spectroscopy and Spectral Analysis, 2018, 38(1): 128.
[12] Rivera V A G, Osorio S P A, Ledemi Y, et al. Opt. Express，2010, 18(24): 25321.
[13] Fares H, Elhouichet H, Gelloz B, et al. J. Appl. Phys.，2014, 116(12): 123504. |
| [1] |
GUAN Jian-fei, CHEN Tao. High Sensitivity Nanosensor Based on Fano Resonance in a
Metal-Dielectric-Metal Waveguide Coupled With a
Split-Ring Cavity[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1746-1751. |
| [2] |
LU Yan-hua, XU Min-min, YAO Jian-lin*. Preparation and Photoelectrocatalytic Properties Study of TiO2-Ag
Nanocomposites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1112-1116. |
| [3] |
SUN Nan, TAN Hong-lin*, ZHANG Zheng-dong, REN Xiang, ZHOU Yan, LIU Jian-qi, CAI Xiao-ming, CAI Jin-ming. Raman Spectroscopy Analysis and Formation Mechanism of Carbon
Nanotubes Doped Polyacrylonitrile/Copper Cyclized to Graphite
at Room Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2983-2988. |
| [4] |
LI Meng-jun1, FANG Hui2. Research of Electromagnetic Field Enhancement of Surface Plasmon
Resonant Mode in Metal Nanosphere-Nanodisc Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1098-1103. |
| [5] |
WANG Zhao-hui1, ZHAO Yan1, 3, 4*, FENG Chao2. Multi-Wavelength Random Lasing Form Doped Polymer Film With Embedded Multi-Shaped Silver Nanoparticle[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 38-42. |
| [6] |
JIN Xiang-peng, LI Xing-jia, ZHANG Chen-jie, YUAN Ya-xian, YAO Jian-lin*. Surface Enhanced Raman Spectroscopic Investigation on SPR Catalyzed Decarboxylation of Ortho-Mercaptobenzoic Acid at Au Nanoparticles Monolayer Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3153-3158. |
| [7] |
SHI Dong-dong1, ZHANG Yue1, SUN Cheng1, 2*. Spectral Characteristics of Asymmetric Silver Double Nanorings Surface Plasmons[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1566-1573. |
| [8] |
CHEN Xiao-bo1, LI Song1, ZHAO Guo-ying2, LONG Jiang-mi1, WANG Shui-feng1, MENG Shao-hua2, WANG Jie-liang1, GUO Jing-hua1, YOU Jia-jia1, MA Yu2, YU Chun-lei3, HU Li-li3. The Silver Surface Plasmon Enhancement for Er3+ Ion Upconversion of 978 and 1 539 nm Laser in Bismuth Glass[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2721-2726. |
| [9] |
CHEN Xiao-bo1, LI Song1, ZHAO Guo-ying2, LONG Jiang-mi1, GUO Jing-hua1, MENG Shao-hua2, ZHENG Dong1, WANG Shui-feng1, YOU Jia-jia1, XU Ling-zhi2, YU Chun-lei3, HU Li-li3. Luminescence Enhancement of Erbium Doped Bismuth Glass by Silver Surface Plasmon[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 362-367. |
| [10] |
WU Ying, ZHU Pan-pan, XIE Wen-jing, LIU Ying*, LU Hao, TANG Qi, HAN Cai-qin. Study on E. coli Activity and Sterilization Effect Based on Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(11): 3619-3623. |
| [11] |
GUO Xiao-ying1, QIU Li1, ZHANG Jin-jie1*, YANG Dan-ting2*, TANG Chun-lan2, XU Da-lun1, LOU Qiao-ming1, YANG Wen-ge1, HU Qi-jie3. Rapid and Quantitative Analysis of Histamine in Fish Using Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2561-2567. |
| [12] |
YIN Zeng-he, ZHU Yong*, ZHANG Jing, ZHANG Xiao-lei, ZHANG Jie. Enhanced Raman Experiments of Graphene-Ag Nanoparticles Prepared with Annealing Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 477-484. |
| [13] |
LI Meng-jun1, FANG Hui2*, LI Xiao-ming2, YUAN Xiao-cong2. Characteristic of Surface Plasmon Resonance Spectrum of Metal Nanosphere-Nanodisc Gap Mode Excited the Radially Polarized Optical Vector Beam[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 8-13. |
| [14] |
SI Ji-zong1, LIU Yan-hong2, SUN Cheng1,3*. Spectral Characteristics at Mid-Infrared Wavelength Regime of Gold Micro-Nano Arrays Surface Plasmons[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 87-95. |
| [15] |
ZHANG Xiao-lei, ZHU Yong*, DING Yi-min, ZHANG Jie. TiO2/Graphene/Ag Composite Structure for Surface-Enhanced Raman Scattering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3441-3445. |
|
|
|
|
