光谱学与光谱分析 |
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Myanmar Jadeitite Low-Temperature Metamorphic Water-Rock Reaction: Eveidence from Microscopic Fourier Transform Infrared Spectroscopy |
YAN Ruo-gu1,4, QIU Zhi-li1,3*, FENG Ming2, JIN Chun-mei1,3, LI Liu-fen1,3, SHI Gui-yong4, WANG Ping1 |
1. Department of Earth Science, Sun Yat-sen University, Guangzhou 510275, China 2. Key Laboratory of Crust-Mantle Materials and Environments, University of Science and Technology of China, Chinese Academy of Sciences, Hefei 230026, China 3. Guangdong Provincial Key Lab of Geological Processes and Mineral Resource Survey, Guangzhou 510275, China 4. Enterprise Management Institute of Social Science Academy of Guangdong Province, Guangzhou 510610, China |
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Abstract Weathering & transporting and depositing processes may improve the quality of some natural low-quality jadeite through reaction with surrounding water fluids. But the mechanism of such water-rock reaction has not been known clearly to date. Applying microscopic Fourier transform infrared spectroscopy (Micro-FTIR), this paper carried out comparatively in-situ research of jadeites’ mineral composition before and after water-rock reaction. The results show that water-rock reaction cannot impact jadeites in their major and minor element composition, but greatly change their water content. Jadeites became richer, with even several times increase, in water content, after experiencing water-rock reaction, and hence show a shift of absorption peak at 3 550 cm-1 to higher frequency. The mineral crystals of these jadeites showed reglar variation in water content from core to edge, and these jadeites have more water in marginal area than in center area, being opposite to the change in water content in jadeite during high temperature and pressure metamorphic process, hence implying that there are different mechanism and shift direction for H+/OH- of jadeite between high pressure metamorphic process and low temperature water-rock reaction. We think that this finding may contribute to understanding the behavior of water in jadeite during metamorphic process and the mechanism of jadeite quality improvement.
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Received: 2013-10-17
Accepted: 2014-02-21
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Corresponding Authors:
QIU Zhi-li
E-mail: qiuzhili@mail.sysu.edu.cn;qiu84112488@163.com
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[1] QIU Zhi-li, WU Fu-yuan, YANG Shu-feng, et al(丘志力, 吴福元, 杨树峰, 等). Chinese Science Bulletin (科学通报), 2008, 53(24): 3104. [2] HU Chu-yan,CHEN Zhong-hui(胡楚雁, 陈钟惠). Journal of Gems and Gemology(宝石和宝石学杂志), 2002,4(2):1. [3] XIA Qun-ke(夏群科). Bulletin of Mineralogy,Petrology and Geochemistry(矿物岩石地球化学通报), 2005, 24(1): 1. [4] HU Chu-yan, DI Jing-ru, ZHANG Cong-sen(胡楚雁, 狄敬茹, 张丛森). Journal of Shenzhen Polytechnic(深圳职业技术学院学报), 2003, (3): 30. [5] YANG Xiao-zhi, XIA Qun-ke ,SHENG Ying-ming(杨晓志,夏群科,盛英明). Acta Petrologica Sinica(岩石学报), 2005, 21(6): 1. [6] XIA Qun-ke, CHEN Dao-gong, GUO Li-he(夏群科, 陈道公, 郭立鹤). Acta Mineralogica Sinica(矿物学报), 1999, 19(2): 161. [7] SHENG Ying-ming, XIA Qun-ke, DING Qiang, et al(盛英明, 夏群科, 丁 强,等). Acta Mineralogica Sinica(矿物学报), 2005, 25(4): 334. [8] FAN Xiao-yu, HUANG Li-wu, CAO Shu-min,et al.(樊孝玉, 黄利武, 曹姝旻, 等). J. Chin. Electr. Microsc. Soc.(电子显微学报), 2006, 25(s): 165. [9] FAN Xiao-yu, WU Xiu-ling, MENG Da-wei(樊孝玉, 吴秀玲, 孟大维). Earth Science-Journal of China University of Geosciences (地球科学:中国地质大学学报), 2007, 32(2): 167. [10] SHEN Zhao-li,WANG Yan-xin(沈照理, 王焰新), Earth Science-Journal of China University of Geosciences(地球科学:中国地质大学学报), 2002, 27(2):127. [11] LIU Liang-ming, PENG Sheng-lin(刘亮明, 彭省临). Advances in Earth Sciences(地球科学进展), 2000, 14(4): 395. [12] JIN Chun-mei, QIU Zhi-li, YAN Ruo-gu,et al(金春梅, 丘志力, 严若谷, 等). Journal of Gems and Gemmology(宝石和宝石学杂志), 2009, 11(4): 4. [13] Wen Su, Kai Ye, Liu Jingbo. Mineralogical Magazine, 2006, 70(5): 509. [14] Andrut M, Wildner M, Ingrin J, et al. Phys Chem Minerals, 2007, 34: 543. |
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