| 光谱学与光谱分析 |
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| Study on Solid Phase Extraction and Spectrophotometric Determination of Uranium in Water with 2-(2-Quinolylazo)-5-Dimthylaminophenol |
| WANG Liang1, 2，YUAN Zhuo-bin1，2, HU Qiu-fen3, YANG Guang-yu3 , YIN Jia-yuan3 |
1. Department of Chemical Engineering, Dalian Nationalities University, Dalian 116600, China
2. Institute of Applied Chemistry, Graduate School of Chinese Academy of Sciences, Beijing 100039, China
3. Department of Chemistry, Yunnan University, Kunming 650091, China |
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Abstract A new chromogenic reagent 2-(2-quinolylazo)-5-Dimthylaminophenol (QADMAP) was synthesized, and its structure was verified by elemental analysis, infrared spectrum, 1H nuclear magnetic resonance spectrum，mass spectrum and UV-spectrum. The color reaction of QADMAP with uranium was studied. In the presence of pH 7.8 buffer solution, when fluorin ion and Triton X-100 medium exist, QADMAP can react with uranium and fluorin to form a stable 1∶1∶1 stable complex [F-∶QADMAP∶U(Ⅵ)]. The molar absorptivity is 1.05×105 L·mol-1·cm-1 at 590 nm. Beer’s law is obeyed in range of 0-20 μg/10 mL. The uranium in samples can be enriched and separated by solid phase extraction with TBP resin cartridge. This method is applied to the determination of uranium in water sample. The relative standard deviations are 2.2%-3.6%, and the recoveries are 94%-105%.
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Received: 2003-12-03
Accepted: 2004-04-18
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Corresponding Authors:
WANG Liang
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| Cite this article: |
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WANG Liang,YUAN Zhuo-bin,HU Qiu-fen, et al. Study on Solid Phase Extraction and Spectrophotometric Determination of Uranium in Water with 2-(2-Quinolylazo)-5-Dimthylaminophenol [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(05): 768-771.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2005/V25/I05/768 |
[1] Chinese Environment Protection Agency(国家环保局). Analysis Method for Monitoring Water and Waste Water(水和废水监测分析方法). Third Edition(第3版). Beijing: Environmental Science Press in China(北京: 中国环境监测出版社). 1998. 163.
[2] YANG Xiang-zhen(杨乡珍). Hydrometallurgy of China(湿法冶金), 2002, 21(3)：154.
[3] WANG Li-hong(王莉红). Physical Testing and Chemical Analysis(Part B: Chemical Analysis)(理化检验-化学分册), 1996，32(3)：158.
[4] ZHANG Xiao-min et al(张晓敏等). J. of Instrumental Analysis(分析测试学报), 1997，16(2)：69.
[5] DENG Fan-zheng, SHI Ying, LIU Yan-mei(邓凡政, 石 影, 刘延美). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(3): 440.
[6] Hu Q F, Yang G Y, Huang Z J, Yin J Y. Talanta, 2002, 58(3): 467.
[7] Yang G Y, Huang Z J, Hu Q F, Yin J Y. Talanta, 2002, 58(3): 511.
[8] Hu Q F, Yang G Y, Yang J H, Huang Z J, Yin J Y. Analytical and Bioanalytical Chemistry, 2002, 374(7/8): 1325.
[9] Hu Q F, Yang G Y, Yang J H, Yin J Y. Journal of Environment Monitoring, 2002, 4(6), 956.
[10] ZENG Yun-e et al(曾云鹗等). Handbook of Modern Chemical Reagent(现代化学试剂手册). Fourth Volume. Chromogenic Reagent of Inorganic Ion(无机离子显色剂). Beijing: Chemical Industry Press(北京：化学工业出版社), 1989. 240.
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