| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of Trace Elements in Tobaccos by Microwave Digestion/ICP-MS Method |
| SUN Yu-an1, SONG Shi-qiu1, WANG Guo-qing1, WEI Li-fang2, LI Zhen-xing1 |
1. Department of Applied Chemistry, Zhengzhou University of Light Industry, Zhengzhou 450002, China
2. Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, China |
|
|
|
|
Abstract 2 mL 50% HNO3 and 1 mL 47% H2O2 were chosen for tobaccos digestion, and the acidity of final digestion solution was confined to about 2%. Standard solutions were diluted with 2% HNO3. The digestion solutions were determined by ICP-MS directly after adding internal standard elements Ge and Rh. In stead of using concentrated acid, this method not only can leave out the process of drying or dilution and extended the life of relevant components of the instrument, but also eliminate the errors of the inconsistency between digestion solutions and standard solutions could be eliminated. The contents of 30 trace elements, the results of eight representatives of which were provided, in tobaccos from seven areas were determined. The detection limits of measured elements were from 0.006 to 1.133 ng·mL-1. The relative standard deviations were from 0.90% to 5.66%. The recovery rates of two elements (Cu, Y) were from 93% to 102%. The results showed that this method proposed could be applied to multielement simultaneous determination of tobaccos, and there is a deep relationship between the contents of the trace elements and the production place and classification of tobaccos.
|
|
Received: 2009-08-10
Accepted: 2009-11-16
|
|
|
|
Corresponding Authors:
SUN Yu-an
E-mail: sya@zzuli.edu.cn; sya371@163.com
|
|
[1] Tso T C, Sorokin T P, Engelhaupt M E. Plant Physiology, 1973, 51(4): 805.
[2] ZHANG Yan-ling, ZHOU Han-ping(张艳玲，周汉平). Tobacco Science ＆ Technology(烟草科技), 2004, 12: 20.
[3] Adrian A A. Journal of Mass Spectrometry, 2007, 42(4): 419.
[4] Linge K L. Geostandards and Geoanalytical Research, 2008, 32(4): 453.
[5] XU Ping, MOU Ren-xiang, CAO Zhao-yun, et al(许 萍，牟仁祥，曹赵云，等). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2009, 26(1): 57.
[6] MEI Lin, SONG Shi-yuan, SU Jian-hua, et al(梅 林，宋世远，苏建华，等). Laser Journal(激光杂志), 2008, 29(2): 72.
[7] Ródenas de la Rocha S, Sánchez-Muniz F J, Gómez-Juaristi M, et al. Journal of Food Composition and Analysis, 2009, 22(4): 330.
[8] HUANG Xu, XU Zi-gang(黄 旭，徐子刚). Journal of Zhejiang University (Science Edition)(浙江大学学报·理学版), 2007, 34(6): 658.
[9] SUO Wei-guo，HU Qing-yuan，CHEN Zai-gen, et al(索卫国，胡清源，陈再根，等). Chinese Journal of Analysis Laboratory(分析试验室), 2008, 27(6): 81.
[10] SUN Wei-min, XUE Da-fang, LI Hong, et al(孙卫民，薛大方，李 红，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2009, 29(1): 256.
[11] Niemela M, Peramaki P, Piispanen J, et al. Analytica Chimica Acta, 2004, 52(2): 137.
[12] Nardi E P, Evangelista F S, Tormen L, et al. Food Chemistry, 2009, 112(3): 727.
[13] Araujo G C L, Gonzalez M H, Ferreira A G, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2002, 57(12): 2121.
[14] Creed J T, Brockhoff C A, Martin T D. USA EPA Method 2008, Revision 5.4, 1994.
[15] de Souza S S, Santos D, Krug F J, et al. Talanta, 2007, 73(3): 451.
|
| [1] |
ZHU Zhao-zhou1*, YANG Xin-xin1, LI Jun1, HE Hui-jun2, ZHANG Zi-jing1, YAN Wen-rui1. Determination of Rare Earth Elements in High-Salt Water by ICP-MS
After Pre-Concentration Using a Chelating Resin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1862-1866. |
| [2] |
WANG Bin1, 2, ZHENG Shao-feng2, LI Wei-cai2, ZHONG Kang-hua2, GAN Jiu-lin1, YANG Zhong-min1, SONG Wu-yuan3*. Determination of Rare Earth Elements in Imported Copper Concentrate by Inductively Coupled Plasma Mass Spectrometry With High Matrix
Injection System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1822-1826. |
| [3] |
ZHANG Fei1，HUA Xia2，YOU Fan1，WANG Bin3，MAO Li3*. Determination of Thallium and Its Compounds in Workplace Air by Ultrasonic Extraction-Inductively Coupled Plasma Mass Spectrometry Using No Gas Mode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2279-2283. |
| [4] |
CHEN Chao-yang1，HUANG Wei-zhi1，SHAO Tian1，LI Zhi-bin2，Andy Hsitien Shen1*. Characteristics of Visible Spectrum of Apatite With Alexandrite Effect[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1483-1486. |
| [5] |
ZHAO Ting1,2,3, CHI Hai-tao1,2,3*, LIU Yi-ren1,2,3, GAO Xia1,2,3, HUANG Zhao1,2,3, ZHANG Mei1,2,3, LI Qin-mei1,2,3. Determination of Elements in Health Food by X-Ray Fluorescence Microanalysis Combined With Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 750-754. |
| [6] |
WANG Chao1, LI Peng-cheng2, YANG Kai1, ZHANG Tian-tian2, LIU Yi-lin2, LI Jun-hui2*. Rapid Detection of Tobacco Quality Grade and Analysis of Grade Characteristics by Using Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 943-947. |
| [7] |
ZHOU An-li1, JIANG Jin-hua1, SUN Chun-xiao2, XU Xin-zhong2, LÜ Xin-ming1,2*. Identification of Different Origins of Hetian Jade Based on Statistical Methods of Multi-Element Content[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3174-3178. |
| [8] |
LIU Yan-de, GAO Xue, JIANG Xiao-gang, GAO Hai-gen, LIN Xiao-dong, ZHANG Yu, ZHENG Yi-lei. Detection of Anthracnose in Camellia Oleifera Based on Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2815-2820. |
| [9] |
ZHANG Liang-liang, WANG Chang-hua, HU Fang-fei, MO Shu-min, LI Ji-dong*. Determination of Trace Impurity Elements in Zircaloy by Ion Exchange-Inductively Coupled Plasma Mass Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2622-2628. |
| [10] |
ZHAO Qian-qian1, YAN Lai-lai1,2, XIE Qing1,2, LIU Ya-qiong1,2, YANG Si-yu1, GUO Chen1, WANG Jing-yu1,2*. Effect of Zinc on the Growth and Element Content of Lactobacillus Acidophilus[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1489-1494. |
| [11] |
LU Xiao-ke1, LI Wei-dong1, LI Xin-wei2. Spectroscopic Analysis of Relics Unearthed from Xipo Site[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1186-1194. |
| [12] |
LIAO Qin-jing, HUANG Wei-zhi, ZHANG Qian, PEI Jing-cheng*. Gemological and Spectral Characterization of Brownish Yellow Tourmaline from Mozambique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(12): 3844-3848. |
| [13] |
GE Jiong1, SUN Lin2, SHEN Xiao-jie1, SHA Yun-fei1, HUANG Tian-xiong2, DU Yi-ping2, ZHANG Wei-bing2, XIE Wen-yan1*, YAO He-ming1*. Simultaneous Detection of Lutein and β-Carotene in Tobacco by Using Raman Spectroscopy Combined with Partial Least Squares[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(11): 3519-3524. |
| [14] |
LIANG Piao-piao1, ZHOU Shan-shan1, XING Yun-xin1, LIU Ying1, 2*. Quantification of Trace Elements in Hair Samples from 156 Women Living in the Low-Selenium Region of Inner Mongolia by ICP-AES and AFS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2217-2222. |
| [15] |
SUN Qi-xuan, WEI Xing, LIU Xun, YANG Ting, CHEN Ming-li*, WANG Jian-hua*. Atomic Spectrometry/Elemental Mass Spectrometry in Bioanalytical Chemistry: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1340-1345. |
|
|
|
|
