| 光谱学与光谱分析 |
|
|
|
|
|
| EDXRF Analysis of Soil Heavy Metals on Lead-Zinc Orefield |
| CHU Bin-bin1,2, LUO Li-qiang1* |
1. National Research Center for Geoanalysis, Beijing 100037, China
2. School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China |
|
|
|
|
Abstract Due to the impact of lead-zinc mining and smelting, the soil of lead-zinc orefield and nearby areas has been widely polluted. Moreover, the concentration of lead and zinc was high, and their concentration range was wide. Furthermore, the impact of overlapping interference between low concentration As and high Pb was serious, and the lack of soil standards of lead and zinc was also a problem. According to these problems, the present work studied an effective solution to setting up the EDXRF analysis of Pb, As, Cd, Cu and Zn of soil on lead-zinc orefield. The measurable concentration of Pb was 4.4-23 600 μg·g-1, and that of Zn was 7.0-39 400 μg·g-1. The detection limit was 1.1 μg·g-1 for Pb and 0.9 μg·g-1 for Zn. The average relative error was 7.6% for Pb and 6.2% for Zn.
|
|
Received: 2009-03-29
Accepted: 2009-06-30
|
|
|
|
Corresponding Authors:
LUO Li-qiang
E-mail: luoliqiang@cags.net.cn
|
|
[1] Cappuyns V, Swennen R, Vandamme A. Journal of Geochemical Exploration, 2006, 88(1-3): 6.
[2] Verner J F, Ramsey M H, Helios-Rybicka E, et al. Applied Geochemistry, 1996, 11(1-2): 11.
[3] Jung M C, Thornton I. Applied Geochemistry, 1996, 11(1-2): 53.
[4] Moles N R, Smyth D, Mather C E, et al. Northern Ireland. Applied Earth Science, 2004, 113: 21.
[5] Wilson B, Lang B, Pyatt F B. Ecotoxicology and Environmental Safety, 2005, 60(3): 269.
[6] Kachur A N, Arzhanova V S, Yelpatyevsky P V, et al. The Science of the Total Environment, 2003, 303(1-2): 171.
[7] Sobanska S, Ledésert B, Deneele D, et al. Earth and Planetary Sciences, 2000, 331(4): 271.
[8] Shikazono N, Zakir H M, Sudo Y. Journal of Geochemical Exploration, 2008, 98(3): 80.
[9] Aslan A, Budak G, Karabulut A. Journal of Quantitative Spectroscopy and Radiative Transfer, 2004, 88(4): 423.
[10] Ostachowicz J, Ostachowicz B, Hoyńska B, et al. X-Ray Spectrometry, 1995, 24(2): 81.
[11] Kutle A, Nad K, Obhoda J, et al. X-Ray Spectrometry, 2004, 33(1): 39.
[12] Bennet C, Jonsson P, Lindgren S. X-Ray Spectrometry, 2005, 34(1): 1.
[13] Boman J, Gatari M J, Wagner A, et al. X-Ray Spectrometry, 2005, 34(5): 460.
[14] Marguí E, Padilla R, Hidalgo M, et al. X-Ray Spectrometry, 2006, 35(3): 169.
[15] Nguyen Thi Hong, Huynh Vinh Ha. X-Ray Spectrometry, 1996, 25(1): 3.
[16] ZHAN Xiu-chun, LUO Li-qiang(詹秀春，罗立强). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 804.
|
| [1] |
CHEN Ying1, YANG Hui1, XIAO Chun-yan2, ZHAO Xue-liang1, 3, LI Kang3, PANG Li-li3, SHI Yan-xin3, LIU Zheng-ying1, LI Shao-hua4. Research on Prediction Model of Soil Heavy Metal Zn Content Based on XRF-CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 880-885. |
| [2] |
WU Xi-jun1, ZHANG Jie1, XIAO Chun-yan2, ZHAO Xue-liang1, 3, LI Kang3, PANG Li-li3, SHI Yan-xin3, LI Shao-hua4. Study on Inversion Model of Soil Heavy Metal Content Based on NMF-PLS Water Content[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 271-277. |
| [3] |
ZHOU Mo1, 2, ZOU Bin1, 2*, TU Yu-long1, 2, XIA Ji-pin1, 2. Hyperspectral Modeling of Pb Content in Mining Area Based on Spectral Feature Band Extracted from Near Standard Soil Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2182-2187. |
| [4] |
YUAN Zi-ran, WEI Li-fei*, ZHANG Yang-xi, YU Ming, YAN Xin-ru. Hyperspectral Inversion and Analysis of Heavy Metal Arsenic Content in Farmland Soil Based on Optimizing CARS Combined with PSO-SVM Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 567-573. |
| [5] |
WANG Hui-min1, 2, TAN Kun1, 2, 3*, WU Fu-yu1, 2, CHEN Yu1, 2, CHEN Li-han1, 2. Study of the Retrieval and Adsorption Mechanism of Soil Heavy Metals Based on Spectral Absorption Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 316-323. |
| [6] |
WANG Jin-feng1, 2, 5, WANG Shi-jie2, 3, BAI Xiao-yong2, 3*, LIU Fang1, LU Qian1, 2, TIAN Shi-qi2, 4, WANG Ming-ming2. Prediction Soil Heavy Metal Zinc Based on Spectral Reflectance in Karst Area[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(12): 3873-3879. |
| [7] |
WANG Teng-jun1, 2, ZHAO Ming-hai3, YANG Yun1*, ZHANG Yang2, 4, CUI Qin-fang1, LI Long-tong1. Inversion of Heavy Metals Content in Soil Using Multispectral Remote Sensing Imagery in Daxigou Mining Area of Shaanxi[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(12): 3880-3887. |
| [8] |
Yasenjiang Kahaer1, 2, Rukeya Sawut1, 2, Nijat Kasim1, 2, Nigara Tashpolat1, 2*, ZHANG Fei1, 2*, Abdugheni Abliz2, 3, SHI Qing-dong1, 2, 3. Estimation of Heavy Metal Contents in Soil Around Open Pit Coal Mine Area Based on Optimized Spectral Index[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2486-2494. |
| [9] |
TAO Chao1, CUI Wen-bo1, WANG Ya-jin1, ZOU Bin1, 2*, ZOU Zheng-rong1. Soil Heavy Metal Qualitative Classification Model Based on Hyperspectral Measurements and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2602-2607. |
| [10] |
REN Dong1,2, SHEN Jun1,2, REN Shun1,2*, WANG Ji-hua1,2,3, LU An-xiang3. An X-Ray Fluorescence Spectroscopy Pretreatment Method for Detection of Heavy Metal Content in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(12): 3934-3940. |
| [11] |
FU Chen-fei1, 2, LUO Li-qiang1, 2*. Quantitative Analysis, Distribution and Speciation of Elements as Pb, As, Cd in Human Hair from Inhabitants in a Lead-Zinc Mining Area[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2606-2611. |
| [12] |
WANG Shi-fang, LUO Na, HAN Ping*. Application of Energy-Dispersive X-Ray Fluorescence Spectrometry to the Determination of As, Zn,Pb and Cr in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1648-1654. |
| [13] |
CHENG Hang1，2, WAN Yuan3, CHEN Yi-yun2，4，5*, WAN Qi-jin1，6，7*, SHI Tie-zhu8, SHEN Rui-li9, GUO Kai2, HU Jia-meng2. Study on the Characteristics and Mechanism of Visible and Near Infrared Reflectance Spectra of Soil Heavy Metals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 771-778. |
| [14] |
XU Liang-ji1,2, LI Qing-qing1, ZHU Xiao-mei1, LIU Shu-guang1. Hyperspectral Inversion of Heavy Metal Content in Coal Gangue Filling Reclamation Land[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3839-3844. |
| [15] |
YUAN Di, GAO Xun*, YAO Shuang, ZHENG Bao-luo . The Detection of Heavy Metals in Soil with Laser Induced Breakdown Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2617-2620. |
|
|
|
|
