Abstract:The thermal decomposition processes of 2-H-heptafluoropropane were investigated during a 30 second reaction time and at temperatures of 400, 500, 600, 700 and 800 ℃ using fast pyrolysis method and Fourier transform infrared spectra (FTIR) and gas chromatography/mass spectrometry (GC/MS) analytical techniques. The results indicate that the reaction temperatures have the obvious effects on the thermal decomposition of 2-H-heptafluoropropane. The 2-H-heptafluoropropane is steady at first three temperatures, whereas starts to obviously decompose at 700 ℃ and undergoes intense decomposition at 800 ℃. At the same time, coke formation was observed on the surface of the reactor at 800 ℃. Moreover, three cyclocompounds, 1,2-bis(trifluoromethyl)perfluoroindane, perfluoro(1-ethylideneindane) and octafluoronaphthalene, were for the first time discovered in the products of thermal decomposition at 800 ℃. This demonstrates that 2-H-heptafluoropropane experiences not only simple decomposition, but also cyclization and the polymerization reactions under high temperature thermal decomposition conditions.
胡永华,李疏芬*. 2-氢七氟丙烷在不同温度下的热分解[J]. 光谱学与光谱分析, 2007, 27(12): 2413-2416.
HU Yong-hua,LI Shu-fen*. Thermal Decomposition of 2-H-Heptafluoropropane at Different Temperatures. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(12): 2413-2416.
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