Abstract：Cyclopentadienylvanadium derivatives of polyoxotungstates [Bu4N]4[(CpV)PW11O39] (1), [Bu4N]4H[(CpV)SiW11O39] (2) and [Bu4N]4[A-β-(η5-CpV)SiW9V3O40] (3) were synthesized, and characterized by elemental analysis, IR, 51V and 183W NMR spectroscopy. Experiment results indicate that (1) and (2) are polyoxometalate-incorporated organometallic complexes, and (3) is a polyoxometalate supported organometallic complex. Antitumoral activities were examined by MTT method. Experiment results indicate that the title complexes did exhibit to a certainty antitumor activity for HL-60 and B16.
刘巨涛，卢艳飞，范圣第. 杂多酸环戊二烯钒衍生物的合成、谱学性质及抗肿瘤活性[J]. 光谱学与光谱分析, 2012, 32(09): 2512-2514.
LIU Ju-tao, LU Yan-fei, FAN Sheng-di. Synthesis, Spectroscopic Characterization and Antitumoral Activities of Cyclopentadienylvanadium Derivatives of Polyoxotungstates . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(09): 2512-2514.
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