Study on Applications of Heteropoly Acids (Blue) Spectrophotometry to Determination of Trace Elements
XIONG Yu-di1,LIU Xia2,FENG Chang-gen1*
1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China 2. College of Science, China Agricultural University, Beijing 100094, China
Abstract:Heteropoly acids can be reduced to the pigmented heteropoly blue. Therefore a reliable method for determination of trace elements can be founded by association with spectrophotometry. At present, heteropoly acids spectrophotometry has made great progress in trace analytical field for its high accuracy, simple instruments and rapidity in detection. In the present paper, the application and research progress of heteropoly acids in the determination of trace elements (P, As, Si and V) are reviewed. The methods include the molybdenum blue method, the heteropoly-basic dye approach, fluorophotometry, the flow injection analysis, atomic absorption spectrophotometry, laser thermal spectrophotometry, etc. Finally, analysis and comparison of these methods are studied.
熊宇迪1,刘霞2,冯长根1*. 杂多酸(蓝)分光光度法在测定痕量元素中的研究进展[J]. 光谱学与光谱分析, 2008, 28(01): 231-234.
XIONG Yu-di1,LIU Xia2,FENG Chang-gen1*. Study on Applications of Heteropoly Acids (Blue) Spectrophotometry to Determination of Trace Elements. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(01): 231-234.
[1] Schindler D W. Science, 1977, 195: 260. [2] GAO Xiao-qiang, WANG Yi-ming, ZHENG Zhong(高小强,王逸铭,郑 忠). Journal of Iron and Steel Research(钢铁研究学报),2007,19(5):5. [3] Soares S S, Martins H, Duarte R O, et al. J. Inorg. Biochem,2007, 101(1): 80.. [4] WANG En-bo, HU Chang-wen, XU Lin(王恩波,胡长文,许 林). An Introduction to Polyacid Chemistry(多酸化学导论). Beijing: Chemical Industry Press(北京: 化学工业出版社), 1998. [5] Sandell E B. Colorimetric Determination of Trace Metals, 3rd ed. New York: Interscience, 1959. [6] Norosanva S A, Grishko G A, Shkatova L A. Zh. Anal. Khim., 1974,29: 529. [7] Marczenko Z. Spectrophotometric Determination of Elements, New York: John Wiley & Sons, England, 1976. [8] Boltz D F, Howell J. Colorimetric Determination of Nonmetals,2nd ed. New York: John Wiley & Sons, 1978. [9] FANG Wei-min(方卫民). Journal of Zhejiang University(Science Edition)(浙江大学学报·理学版),2003, 30(6): 663. [10] LI Shan, LIU Dan(李 山,刘 丹). Metallurgical Analysis(冶金分析),2006,26(3): 82. [11] WANG Yu-biao, ZHAO Hua-zhang(王玉标,赵化章). Journal of China University of Science and Technology(中国科学技术大学学报), 1997,27(3): 372. [12] HOU Man-ling, DENG Fei-yue, LU Tong-juan, et al(侯曼玲,邓飞跃,鲁统娟,等). Metallurgical Analysis(冶金分析),2004,24(1): 39. [13] Abdolraouf S, Ebrahim A. Talanta,2006, 70(4): 756. [14] SHA Li-qing, ZHOU Fei-de, SHAO Ze-yao(沙丽清,周斐德,邵则瑶). Chinese Journal of Soil Science(土壤通报), 1999, 30(6): 281. [15] Stobart J A. Analyst, 1969, 94: 1142. [16] HE Xiao-wei, CHEN Yong-jie, QU Shou-bo, et al(贺晓唯,陈永杰,曲寿波,等). Journal of Shenyang Institute of Chemical Technology(沈阳化工学院学报),2000,14(3): 182. [17] KAI Xiao-ming(开小明). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(3): 451. [18] ZHANG Ying-qi, LI Bing(张莹琪,李 冰). Metallurgical Analysis(冶金分析),2004,24(6): 6. [19] SONG Gong-wu(宋功武). Journal of Instrumental Analysis(分析测试学报), 1995, 14(1): 85. [20] SONG Gui-lan,LU Yan, WANG Xing-en, et al(宋桂兰,卢 燕,王兴恩,等). Journal of Shangdong Institute of Building Materials(山东建材学院学报), 1995, 9(1): 37. [21] LIU Bao-sheng, WANG Gui-hua, SUN Han-wen, et al(刘保生,王桂华,孙汉文,等). China Journal of Analytical Chemistry(分析化学),2001,29(1): 42. [22] LIU Bao-sheng, GAO Jing, LIU Zhi-chao, et al(刘保生,高 静,刘智超,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(2): 306. [23] Ruzicka J, Hansen E H. Analytica Chimica Acta, 1975, 78(1): 145. [24] Motomizu S, Li Z H. Talanta,2005, 66(2): 332. [25] MI Jian-ping, LI Yuan-qian, ZOU Xiao-li, et al(米建萍,黎源倩,邹晓莉,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27(6):1188. [26] Vlessidis A G, Kotti M E, Evmiridis N P. J. Anal. Chem,2004, 59(1): 77. [27] Motomizu S, Mikasa H, Oshima M, et al. Bunseki Kagaku, 1984, 33: 116. [28] Li Z H, Oshima M, Sabarudin A, et al. Analytical Sciences,2005,21(3): 263. [29] SONG Gong-wu(宋功武). Analysis and Testing Technology and Instrument(分析测试技术与仪器), 1997, 3(4): 241. [30] SONG Gong-wu(宋功武). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1999, 19(3): 466. [31] DENG Bo(邓 勃). Principle, Technique and Application of Atomic Absorption Spectroscopy(原子吸收光谱分析的原理、技术和应用). Beijing: Tsinghua University Press(北京:清华大学出版社),2004. [32] Zaugg W S, Knox R J. Analytical Biochemistry, 1967,20(2): 282. [33] HUO Guang-jin, ZHANG Zheng-jun(霍广进,张正钧). Chemical World(化学世界), 1994, 35(4): 195. [34] HUANG Jin-ping, HANG Guo-pei(黄金萍,杭国培). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1999, 19(3): 421. [35] Vishnikin A B. Journal of Molecular Liquids,2005, 118(1-3): 51. [36] HAN Quan, YAN Hong-tao(韩 权,阎宏涛). Progress in Chemistry(化学进展),2002, 14(1): 24. [37] Proskurnin M A, Osipova N V, Kuznetsova V V, et al. Analyst, 1996, 121(4): 419. [38] HAN Quan, YAN Hong-tao, YANG Xiao-hui(韩 权,阎宏涛,杨晓慧). Journal of Shaanxi Normal University(Natural Science Edition)(陕西师范大学学报·自然科学版),2001,29(3): 79. [39] ZHANG Ying, HAN Quan, YAN Hong-tao(张 英,韩 权,阎宏涛). Journal of Instrumental Analysis(分析测试学报),2001,20(5): 24.