Abstract：In the paper the complexes of metal cobalt(Ⅲ), manganese(Ⅲ), iron(Ⅲ) and copper(Ⅱ) with Schiff-base N,N-ethylenebis(salicylideneaminnato) have been synthesized and characterized. The nanosized porous material MCM-41 has been functionalized by the modification of the internal pore surface with γ-aminopropyl and was assembled by the modification groups with metal complex of Schiff-base. These metal complexes and functionalized nanosized porous materials were charcterized by XRD, IR and UV-Vis. It is indicated by spectral analysis that the synthesized nanosized porous materials have been confirmed to be MCM-41 with hexagon bores, and the γ-aminopropyls have been bonded on their internal pore surface. And the complexes of metal cobalt(Ⅲ), manganese(Ⅲ), iron(Ⅲ) and copper(Ⅱ) with Schiff-base N,N-ethylenebis(salicylideneaminnato) were assembled into MCM-41. The IR spectra of these samples show that there were characteristic absorptions of the amino and the Schiff base groups, and the absorption of amino shifted to longer wavelength.
霍涌前，李 珺，王 伟，弓亚琼，张逢星* . MCM-41介孔分子筛组装过渡金属配合物的电子光谱 [J]. 光谱学与光谱分析, 2004, 24(03): 281-284.
HUO Yong-qian, LI Jun, WANG Wei, GONG Ya-qiong, ZHANG Feng-xing* . Electron Spectra of Chemical Assembly Mesoporous MCM-41 with Transition Metal Complexes . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 281-284.
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