Abstract：Six cobalt complexes, Co(H2O)6·H2btec(1); {[Co2(HCOO)6]·CH3OH}n(2); {[Co(4,4’-bipy)2(H2O)4]·suc·4H2O}n(3); Co(NA)2(H2O)4(4); [Co(mal)(4,4’-bipy)H2O]n(5) and [Co(HCOO)4Co(H2O)4]n(6), were synthesized through hydrothermal method. UV-Vis absorption spectra and surface photovoltage spectra of the complexes were detected and the structures of the complexes were determined by single-crystal X-ray diffraction. There are positive responses in the range of 300-800 nm in the SPS. There are good corresponding relationships between response bands of SPS and absorption peaks of UV-Vis absorption spectra by the comparison. Comparing the SPS of six complexes, the valence, coordination mode and coordination micro-environment affect the position and the shape of the response bands.
李 雷，金 晶，史忠丰，邢永恒，牛淑云* . 光诱导下系列钴配合物的表面电子行为对比研究 [J]. 光谱学与光谱分析, 2010, 30(09): 2443-2446.
LI Lei, JIN Jing, SHI Zhong-feng, XING Yong-heng, NIU Shu-yun* . Comparative Research on Light-Induced Surface Electron Behavior of Cobalt Complexes . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(09): 2443-2446.
