Abstract:Optical limiting (OL) cycling behavior of chloroindium (Ⅲ) phthalocyanine (InPcCl) solution was investigated by repeating Z-scan measurement up to 150 times, while photostability was characterized by changes in the UV-Vis absorption spectra during the process of laser irradiation and daylight illumination. The results show that InPcCl is stable against laser irradiation, leading to its good OL cycling behavior, although it features poor stability against daylight illumination. The possible mechanism behind this difference in photostability is proposed.
[1] Moloney J V. Nonlinear Optical Materials. New York: Springer, 1998. [2] SHI De-heng, XU Qi-fu(施德恒, 许启富). Optical Technique(光学技术), 2000, 26(1): 52. [3] HUA Chao, WANG Ting-wei, WANG Bing-sheng(花 超, 王庭慰, 王炳升). Optical Technique(光学技术), 2003, 29(6): 716. [4] SHEN Yong-jia(沈永嘉). The Syntheses and Applications of Phthalocyanines(酞菁的合成与应用). Beijing: Chemical Industry Press(北京: 化学工业出版社), 2000. [5] Leznoff. C C, Lever A B P. Phthalocyanines: Properties and Applications. New York: VCH Publishers, Inc., 1989. [6] Arthur L Thomas. Phthalocyanine Research and Applications. Florida: CRC Press, Inc., 1990. [7] ZHAN Hong-bing, DU Yu-hong, LIN Chun-ying, et al(詹红兵,杜育红,林春莺,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(11): 1850. [8] QIN Jing, ZHAO Xu-cheng, LIN Ai-mei, et al(秦 静, 赵旭成, 林爱梅, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(2): 255. [9] Perry J W, Mansour K, Lee I Y S, et al. Science, 1996, 273(13): 1533. [10] Danilo Dini, Markus Barthel, Thorsten Schneider, et al. Solid State Ionics, 2003, 165: 289. [11] O’Flaherty Sean, Hold Stephanie V, Cook Michale J, et al. Advanced Materials, 2003, 15(1): 19. [12] Pudolf Slota, Gabriela Dyrda. Inorganic Chemistry, 2003, 42: 5743. [13] Michael Hanack, Thorsten Schneider, Markus Barthel, et al. Coordination Chemistry Reviews, 2001, 219: 235. [14] WANG Shuang-qing, GAN Quan, ZHANG Yong-fang. Chem. Phys. Chem(Chemphyschem), 2006, 7: 935.