Preparation and Characterization of 2(8-Hydroxyquinoline)-2(Phenol)Zirconium Thin Film
HAO Yu-ying1, HAO Hai-tao2, WANG Hua2, ZHOU He-feng2, LIU Xu-guang2, XU Bing-she2
1. The College of Science of Taiyuan University of Technology,Taiyuan 030024, China 2. The College of Material Science and Engineering of Taiyuan University of Technology,Taiyuan 030024, China
Abstract:In this paper, the new emitting material zirconium complex with 8-hydroxyquinoline and phenol (Zr(OPh)2q2), which can form high quality nano-scale amorphous thin films at glass substrates cleaned by vacuum evaporation, was synthesized. Its crystallization,thermal stability,the structure of energy band and PL mechanism were investigated respectively by FTIR spectra, DTA-TG analysis , SEM, XRD spectra, UV-Vis absorption spectra and fluorescence spectra. Results show that the Zr(OPh)2q2 is a thermally stable material, whose melting point is 381.2 ℃, decomposition temperature is 467.1 ℃, whose film can emits intense yellow-green fluorescence with peak wavelength at 525 nm and a full width at half-maximum of 107.6 nm under UV excitation(390 nm), powder has intense yellow fluorescence, therefore it may be a excellent electroluminescent material.
[1] Tang C W, Van Slyke S A. J. Appl. Phys. Lett., 1987, 51: 913. [2] Burrows P E,Sapochak L S et al. J. Appl. Phys. Lett.,1994, 64(20): 2718. [3] Hopkins T A, Meerholz K, Shaheen S et al. J. Chem. Mater.,1996, 8: 344. [4] Chen C H, Shi J M. J. Coord. Chem. Rev., 1998, 171: 161. [5] WANG Wei, DING Xiao-ping, MENG Guang-zheng(王 薇, 丁小平, 孟广政). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(2): 219. [6] HAO Yu-ying, WANG Hua et al(郝玉英,王 华等). Chin. J. Lumin.(发光学报),to be published. [7] WANG Hua, HAO Yu-ying et al(王 华,郝玉英等). Chin. Chem. Prog.,to be published. [8] XU Bing-she, WANG Hua, ZHOU He-feng(许并社,王 华,周禾丰). 2nd Cross-Strait Workshop on Nano Science and Technolege(第二届海峡两岸纳米科技研讨会),2002. 12. [9] XU Bing-she et al(许并社等). Chinese Patent(中国专利), Application number(申请号):031456766. [10] XU Bing-she et al(许并社等). Chinese Patent(中国专利), Application number(申请号):031456774. [11] Louis M. Leung, Lo W Y et al. J. Am. Chem. Soc.,2000, 122: 5640. [12] HUANG Chun-hui, LI Fu-you, HUANG Yan-yi(黄春辉,李富友,黄岩谊). Ultrathin Films for Optics and Electronics(光电功能超薄膜),Beijing:Peking University Press(北京:北京大学出版社),2001. 76. [13] FANG Rong-chuan(方容川). Solid State Spectroscopy(固体光谱学). Hefei: Press of China University of Science and Technology (合肥:中国科技大学出版社),2001. 61,128,195. [14] Burrows P E,Shen Z et al. J. Appl. Phys.,1996,79(10):7991. [15] Campbell A J, Bradley D D C, Lidzey D G. J. Appl. Phys.,1997, 82(12): 6326. [16] GUO Yi-cheng,WANG Zheng-xi(郭贻诚,王震西). The Physics of Amorphous State(非晶态物理学). Beijing:Science Press(北京:科学出版社),1984. 204.