Determination of Metal Elements in Paper Sludges by ICP-AES
LIU Xian-miao1,JIANG Ze-hui2*,FEI Ben-hua1,REN Hai-qing3,FU Feng3
1.Beijing Forestry Machinery Research Institute of State Forestry Administration, Beijing 100029, China 2.Research Institute of International Center for Bamboo and Rattan, Beijing 100102, China 3.Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China
Abstract:Metal elements, especially the heavy metal element, need to be considered for resource utilization of paper sludge.Seventeen kinds of metal elements were determined by ICP-AES method, which were form two kinds of paper sludge from Anhui Shanying paper mill, one kind of paper sludge from Fujian Qingshan paper mill, and one kind of paper sludge from Fujian Zhongzhu paper mill.The results show that there are different amounts of metal elements in the 4 kinds of paper sludge including poisonous metal elements, such as Cr, etc, metal element which is poisonous when excessive, such as Fe, etc, and P and K which are beneficial for plant growth.Al and Ca contents are maximal.The recovery ratio for Fujian Zhongzhu paper mill obtained by standard addition method is 94.4%-107.3%.Heavy metal elements content lower than the national standard GB/4284—84 “Control standards for pollutions in sludge form agricultural use”.The order of heavy metal elements content is paper sludge from Fujian Zhongzhu paper mill<paper sludge from Fujian Qingshan paper mill<paper sludge from Anhui Shanying paper mill.The results provide theoretical directions for resource utilization of paper sludge, especially for agricultural utilization and land utilization.
Key words:Paper sludge;ICP-AES method;Metal element;Heavy metal element;Resource utilization
刘贤淼1,江泽慧2*,费本华1,任海青3,傅 峰3 . ICP-AES法测定造纸污泥中金属元素[J]. 光谱学与光谱分析, 2010, 30(01): 255-258.
LIU Xian-miao1,JIANG Ze-hui2*,FEI Ben-hua1,REN Hai-qing3,FU Feng3 . Determination of Metal Elements in Paper Sludges by ICP-AES. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(01): 255-258.
[1] WANG De-han, PENG Jun-jie, DAI Miao(王德汉,彭俊杰,戴 苗).Paper and Paper Making(纸和造纸),2003,(3): 47. [2] Yen Hong-Wei, Brune David E.Bioresource Technology, 2007, 98: 130. [3] Fierro A, Angers D A, Beauchamp C J.Soil Biology & Biochemistry, 2000, 32: 143. [4] WANG De-han, PENG Jun-jie, DAI Miao(王德汉,彭俊杰,戴 苗).Transactions of China Pulp and Paper(中国造纸学报),2003,18(1): 141. [5] Marche T, Schnitzer M, Dinel H, et al.Geoderma, 2003, 116: 345. [6] Yan Xiangkui, Change K W, Xu H L.Pedosphere, 2005, 15(1): 84. [7] Tong Wangyu, Fu Xiangyang, Lee Sang-Mok.Biochemical Engineering Journal, 2004, 18: 89. [8] Lee Sang-Mok, Koo Yoon-Mo, Lin Jianqiang.Adv.Biochem.Engin/Biotechnol., 2004, 87: 173. [9] Khalili N R, Vyas J D, Eeangkaew W.Separation and Purification Technology, 2002, 26: 259. [10] Moreira Josino Costa.The Science of the Total Environment,1996,188: 61. [11] GUO Lan, XIE Ming-yong, YAN Ai-ping, et al(郭 岚,谢明勇,鄢爱平,等).Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27(11): 2345. [12] WU Shu-bin, KONG Xiao-ying, XIE Guo-hui, et al(武书彬, 孔晓英, 谢国挥,等).China Pulp & Paper(中国造纸),2002,21(1): 12. [13] WANG Bao-gen(王宝根).Chinese Journal of Frontier Health and Quarantjne(中国国境卫生检疫杂志),2007,30(1): 49.