Abstract：The binuclear complex of Schiff base C14H12NO3K(KHL) derived from 2-hydroxy-1-naphthaldehyde and β-alanine with lanthanide nitrate was synthesized and characterized by elemental analysis, IR, UV, TG-DTA, and molar conductance analysis. The composition of the complex was [La2(L)2(NO3)2]·2C2H5OH. The interaction of the complex and DNA was studied by fluorescence spectrum. The result indicates that the La(Ⅲ) complex could cause a sharp decrease in the fluorescence intensity of EB-DNA system, and the complex could partly sustain the place of EB.
李莹莹, 范玉华*, 毕彩丰, 张栋梅, 邹彦娜, 肖艳. La(Ⅲ)与β-丙氨酸缩β-萘酚醛双核配合物的合成、表征及其与DNA的作用[J]. 光谱学与光谱分析, 2006, 26(12): 2268-2271.
LI Ying-ying, FAN Yu-hua*, BI Cai-feng, ZHANG Dong-mei, ZOU Yan-na,XIAO Yan. Synthesis and Characterization of La(Ⅲ) Binuclear Complex with 2-Hydroxy-1-Naphthaldehyde-β-Alanine and Its Interaction with DNA. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(12): 2268-2271.
[1] Singh N K, Misseema Agrawal R C. Synth. React. Inor. Met-Org. Chem., 1985, 15(1): 75. [2] CHEN De-yu，JIANG Yin-zhi(陈德余, 江银枝). Chinese Journal of Applied Chemistry(应用化学), 1997, 14(3): 5. [3] BI Si-wei, GAO En-qing, TIAN Jun-lian, et al(毕思玮，高恩庆，田君廉, 等). Chinese Journal of Applied Chemistry(应用化学)，1995，12(6)：13. [4] ＷANG Ｍing-zhao, NING Ya-lan, MENG Zhao-xing, et.al (王明召，宁亚兰，孟昭兴, 等). Spectrocopy and Spectral Analysis(光谱学与光谱分析)，2005, 25(2): 174. [5] Baseer M A, Jadhav V D, Phule R M. Oriental Journal of Chemistry, 2000, 16(3): 553. [6] Yuhua F，Caifeng B, Jinying L. Synth React Inorg Met-Org Chem., 2003, 33 (1): 137. [7] KONG De-yuan, ZHANG Xiong-wen, ZHU Qin, et al(孔德源，章雄文，朱 勤, 等). Chinese Journal of Medicinal Chemistry(中国药物化学杂志)，1998，8(4)：245. [8] KONG De-yuan, XIE Yu-yuan(孔德源，谢毓元). Chinese Journal of Medicinal Chemistry(中国药物化学杂志)，1999，9(3)：162. [9] TANG Hong-wu, CHEN Bei, et al(唐宏武，陈 蓓, 等). J. Wuhan Univ.(Natural Science Edition) (武汉大学学报·自然科学版), 1997，43(6)：711. [10] LIN Qiu-yue, HU Rui-ding, ZHENG Xiao-hua(林秋月，胡瑞定，郑孝华). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004，24(8)：988. [11] Geary W J. Coordination Chemistry Reviews, 1997, 7: 81. [12] Kazuo Nakmoto, Auth.(中本一雄著).Infrared and Raman Spectra of Inorganic and Coordination Compounds(无机和配位化合物的红外和拉曼光谱). Translated by HUANG De-ru, WANG Qing-ren(黄德如, 汪庆仁，译). Beijing: Chemical Industry Press(北京: 化学工业出版社), 1988. 10. [13] GUO Dong-fang, HE Jiang, ZENG Zheng-zhi(郭东方，何 疆，曾正志). Journal of Rare Earths(中国稀土学报), 2004，22(1)：55. [14] YE Yong, HU Ji-ming, ZENG Yun-e(叶 勇，胡继明，曾云鹗). Chinese Journal of Inorganic Chemistry(无机化学学报), 2000，16(6)：951.
