光谱学与光谱分析
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铅锑合金的预处理及锑、硒的ICP-AES法测定
方奕文,宋一兵,孙长勇,薛 亮,余 林
汕头大学化学系,广东 汕头 515063
Pretreatment of Lead-Antimony Alloy and Determination of Antimony and Selenium Using ICP-AES
FANG Yi-wen, SONG Yi-bing, SUN Chang-yong, XUE Liang, YU Lin
Department of Chemistry, Shantou University, Shantou 515063, China
摘要 : 用“锯末法”从铅锑合金锭中取样,并用硝酸和酒石酸的混合溶液溶解样品,再经过适当的处理后,用ICP-AES法测定样品溶液中锑和硒的含量。结果表明,锑的加标回收率为96.2%;硒的加标回收率为92.1%,11次测定的RSD(n =11)小于3.56%。方法操作方便,分析速度快,结果准确。方法已用于铅锑合金产品中锑、硒的测定,取得满意的结果。
关键词 :电感耦合等离子原子发射光谱;铅-锑合金;锑;硒
Abstract :The sample was obtained from original sample using “sawing method” and was dissolved with a mixed solvent of nitric acid and tartaric acid. After the sample solution was pretreated with a series of methods, Sb and Se were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES). The results show that the recovery of standard addition of Sb was 96.2% and that of Se was 92.1%, and that the relative standard deviations(n =11)were smaller than 3.56%. The method is efficient, accurate and easy to operate, and has been applied to the determination of Sb and Se in Pb-Sb alloy products with satisfactory results.
Key words :Inductively coupled plasma atomic emission spectrometry;Pb-Sb alloy;Antimony;Selenium
收稿日期: 2005-01-06
修订日期: 2005-04-25
通讯作者:
方奕文
引用本文:
方奕文,宋一兵,孙长勇,薛 亮,余 林. 铅锑合金的预处理及锑、硒的ICP-AES法测定[J]. 光谱学与光谱分析, 2006, 26(03): 561-563.
FANG Yi-wen, SONG Yi-bing, SUN Chang-yong, XUE Liang, YU Lin. Pretreatment of Lead-Antimony Alloy and Determination of Antimony and Selenium Using ICP-AES . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(03): 561-563.
链接本文:
https://www.gpxygpfx.com/CN/Y2006/V26/I03/561
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