SUN Xue-bai, ZHANG Xi-qing, DU Peng,CHANG Xiao-wei, WANG Jun-ling, HUANG Shi-hua
Institute of Optoelectronics Technology, Laboratory of Materials for Information Storage and Display, Beijing Jiaotong University, Beijing 100044, China
Abstract:CdS thin films were prepared by chemical bath deposition (CBD) at 90 ℃. The influence of annealing and CdCl2 treatment on CBD-CdS thin film was studied. XRD and SEM were used to study the crystal structure and surface morphology of the films. The untreated CBD-CdS films had poor crystallinity; the CdS thin film made with annealing treatment had cubic crystallinity but small grain size. After the CdCl2 treatment, these films recrystallized to the hexagonal phase, resulting in a better crystallinity, and smooth surface morphology. Optical properties were studied by absorption spectrum. The energy gap of the films was found to decrease by annealing, and the CBD-CdS made with CdCl2 treatment had a lower density of planar defects. In conclusion, the CdCl2 treatment can improve the properties of the CdS thin films.
孙学柏,张希清,杜鹏,常笑薇,王俊玲,黄世华. CdS薄膜的化学沉积法制备及其特性的研究[J]. 光谱学与光谱分析, 2007, 27(01): 32-34.
SUN Xue-bai, ZHANG Xi-qing, DU Peng,CHANG Xiao-wei, WANG Jun-ling, HUANG Shi-hua . Study on the Property of CBD-CdS Thin Films. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(01): 32-34.
[1] Moutinho H R, Albin D, Yan Y, et al. Thin Solid Films, 2003, 436: 175. [2] Dieter Bonnet. Thin Solid Films, 2000, 361: 547. [3] CHU Xiang-qiang, XIE Da-tao, MENG Tie-jun, et al(储祥蔷, 谢大弢, 孟铁军, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 625. [4] Metin H, Esen R. Journal of Crystal Growth, 2003, 258: 141. [5] Ximello-Quiebras J N, Contreras-Puente G, et al. Solar Energy Materials & Solar Cells, 2004, 82: 263. [6] HUANG Xiao-rong, ZHENG Jia-gui, CAI Wei, et al(黄小融, 郑家贵, 蔡 伟). Semiconductor Optoelectronics(半导体光电),1998, 19: 404. [7] Morris G C, Das S K. Conference Record of the Twenty-Sixth IEEE. 1997. 469. [8] Yeh C. Phys. Rev. B: Condens. Matter, 1992, 46: 10086. [9] Kodigala Subba Ramaiah, Pilkington R D, Hill A E, et al. Materials Chemistry and Physics, 2001, 68: 22. [10] Sung Chan Park, Byung Wook Han, Jin Hyung Ahn, et al. Conference Record of the Twenty-Third IEEE. 1993. 531.