(NH4)2SO4，NH4NO3和(NH4)2SO4/NH4NO3混合气溶胶吸湿质量增长因子的快速测量方法

doi:10.3964/j.issn.1000-0593(2021)11-3444-07

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摘要：气溶胶颗粒的吸湿性决定了其尺寸、浓度、化学组成以及相态，从而显著影响着全球气候、大气异相化学以及人类健康。运用在线、原位、连续扫描衰减全反射傅里叶变换红外光谱（ATR-FTIR）技术, 结合线性湿度（RH）控制系统，实现了RH连续变化条件下气溶胶FTIR-ATR光谱的快速测量。根据水弯曲振动谱带（~1 640 cm^-1）峰面积随RH的变化，得到了(NH₄)₂SO₄，NH₄NO₃和(NH₄)₂SO₄/NH₄NO₃混合气溶胶的质量增长因子（MGFs）、潮解点（DRH）和风化点（ERH）。与气溶胶的E-AIM模型预测值相比较，实验结果表现出良好的一致性，证实该方法是一种测量大气气溶胶MGFs，ERH和DRH的快速测量方法。

关键词：衰减全反射傅里叶变换红外光谱；吸湿性；质量增长因子；线性湿度变化

Abstract：The hygroscopicity of aerosol particles determines their size, concentration, chemical compositions and phase states, and thus affects the global climate, heterogeneous atmospheric chemistry and human health. In this study, an on-line and in-situ rapid scan attenuated total reflection Fourier transform infrared (ATR-FTIR) technique coupled with a linear relative humidity (RH) controlling system was utilized to obtain the IR spectra of aerosols under different RH. The mass growth factors (MGFs), deliquescence relative humidity (DRH) and efflorescence relative humidity (ERH) of (NH₄)₂SO₄, NH₄NO₃, and mixed (NH₄)₂SO₄/NH₄NO₃ aerosols were determined rapidly by measuring the peak areas of the bending vibration band of liquid water (~1 640 cm^-1). Comparisons between the measurements and the predictions from the E-AIM model showed good consistency, which verifies the rapid scan ATR-FTIR as a powerful tool for investigating hygroscopic behaviors and phase transitions of atmospheric aerosols. Furthermore, pure (NH₄)₂SO₄ and NH₄NO₃ particles were found to effloresce at 49% and 25% RH, respectively, while mixed (NH₄)₂SO₄/NH₄NO₃ aerosols with a mole ratio of 1∶1 and 1∶2 exhibited one-stage efflorescence transition beginning at 44% and 38% RH, respectively, upon dehydration. These results indicate that the presence of NH₄NO₃ can inhibit the crystallization of (NH₄)₂SO₄, and formed (NH₄)₂SO₄ seeds will act as heterogeneous nuclei to promote the efflorescence of NH₄NO₃ at higher RH. In addition, the double salt (NH₄)₂SO₄·2NH₄NO₃ was formed upon efflorescence of mixed particles. These findings are critical for understanding complex phase transitions of mixed inorganic aerosols and interpretation for RH dependency of heterogeneous reaction rates of atmospheric reactive species.

Key words：ATR-FTIR; Hygroscopicity; Mass growth factors; Linear RH changes

收稿日期: 2020-10-15 修订日期: 2021-02-26

中图分类号:

O433.4

基金资助: 国家自然科学基金项目（41875144，91644101）资助

通讯作者: 张韫宏 E-mail: yhz@bit.edu.cn

作者简介: 李琼，1996年生，北京理工大学化学与化工学院硕士生 e-mail: lq270224181@126.com

引用本文:

李琼，马帅帅，庞树峰，张韫宏. (NH₄)₂SO₄，NH₄NO₃和(NH₄)₂SO₄/NH₄NO₃混合气溶胶吸湿质量增长因子的快速测量方法[J]. 光谱学与光谱分析, 2021, 41(11): 3444-3450.
LI Qiong, MA Shuai-shuai, PANG Shu-feng, ZHANG Yun-hong. Measurement on Mass Growth Factors of (NH₄)₂SO₄, NH₄NO₃, and Mixed (NH₄)₂SO₄/NH₄NO₃ Aerosols Under Linear RH Changing Mode. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3444-3450.

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