Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy
Ahmed. I. El-Shenawy*，Ishaq. F. E. Ahmed，Moamen. S. Refat
Department of Chemistry, Colloge of Education, Imam Abdulrahman Bin Faisal University, Dammam 1982, Saudi Arabia
Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy
Ahmed. I. El-Shenawy*, Ishaq. F. E. Ahmed, Moamen. S. Refat
Department of Chemistry, Colloge of Education, Imam Abdulrahman Bin Faisal University, Dammam 1982, Saudi Arabia
摘要： The main task of this article was to prepared of new pigment model in situ solar cells accordance to charge-transfer complexes of rhodamine C (RhC) donor as dye laser gain media with iodine (σ-acceptor) and chloranilic acid, CLA (π-acceptor). The synthesis stoichiometry of these complexes were of 1∶2 (donor∶acceptor) with general formulas [(RhC)]I·I3 and [(RhC)(CLA)2]. The discussed data of elemental analysis, conductivity measurements, FT-IR, UV-Vis spectroscopy and photometric titration data visualized the stoichiometry, formula and complexity of the complexes. The physicochemical and spectroscopic analyses obtained suggested that the electron transfer occurred through nitrogen atom in a tertiary amine —N(C2H5)2 of RhC donor with acceptor. The synthesized solid complexes were under go to thermogravimetric analyses to investigate their thermal stability and decomposition steps. The molar conductance measurements revealed that RhC complexes have an electrolytic statement. The thermal stability of rhodamine C complexes was enhanced in comparable with RhC itself. The polymer membranes of poly-methyl methacrylate) (PMMA) combined with the RhC charge(transfer complexes in chloroform solvent have been prepared and characterized by (infrared & electronic) spectroscopy and scanning electron microscopy (SEM) morphological examination. The photo-stability properties of the RhC complexes have been investigated.
Abstract：The main task of this article was to prepared of new pigment model in situ solar cells accordance to charge-transfer complexes of rhodamine C (RhC) donor as dye laser gain media with iodine (σ-acceptor) and chloranilic acid, CLA (π-acceptor). The synthesis stoichiometry of these complexes were of 1∶2 (donor∶acceptor) with general formulas [(RhC)]I·I3 and [(RhC)(CLA)2]. The discussed data of elemental analysis, conductivity measurements, FT-IR, UV-Vis spectroscopy and photometric titration data visualized the stoichiometry, formula and complexity of the complexes. The physicochemical and spectroscopic analyses obtained suggested that the electron transfer occurred through nitrogen atom in a tertiary amine —N(C2H5)2 of RhC donor with acceptor. The synthesized solid complexes were under go to thermogravimetric analyses to investigate their thermal stability and decomposition steps. The molar conductance measurements revealed that RhC complexes have an electrolytic statement. The thermal stability of rhodamine C complexes was enhanced in comparable with RhC itself. The polymer membranes of poly-methyl methacrylate) (PMMA) combined with the RhC charge(transfer complexes in chloroform solvent have been prepared and characterized by (infrared & electronic) spectroscopy and scanning electron microscopy (SEM) morphological examination. The photo-stability properties of the RhC complexes have been investigated.
基金资助: the Deanship of Scientific Research at Imam Abdulrahman Bin Faisal University(2017-143-CED)
通讯作者:
Ahmed. I. El-Shenawy
E-mail: aelshenawy@uod.edu.sa
引用本文:
Ahmed. I. El-Shenawy，Ishaq. F. E. Ahmed，Moamen. S. Refat. Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy[J]. 光谱学与光谱分析, 2019, 39(07): 2307-2315.
Ahmed. I. El-Shenawy, Ishaq. F. E. Ahmed, Moamen. S. Refat. Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2307-2315.
[1] Hashem H A, Refat M S. Surf. Rev. Lett., 2006, 13(4): 439.
[2] Seridi S, Dinar K, Seridi A, et al. New J. Chem., 2016, 40: 4781.
[3] Mohamed M E, Frag E Y Z, Hathoot A A, et al. Spectrochim Acta A, 2018, 189: 357.
[4] Wu Y, Luo S, Cao L, et al. Anal. Chim. Acta，2017，976: 74.
[5] Refat M S, Adam A M A, El-Sayed M Y. Arabian J. Chem., 2017, 10: S3482.
[6] Mutneja R, Singh R, Kaur V, et al. Dyes. Pigm., 2107, 139: 635.
[7] Duarte F J. High Power Dye Lasers. Springer-Verlag: Berlin，1991.
[8] Beija M, Afonso C A M, Martinho J M G. Chem. Soc. Rev., 2009, 38: 2410.
[9] Park H, Choi J, Choi J, et al. J. Photochem. Photobiol. A, 2018, 351: 139.
[10] El-Maghrabi H H, Barhoum A, Nada A A, et al. J. Photochem. Photobiol. A, 2018, 351: 261.
[11] Eiamprasert U, Sudchanham J, Surawatanawong P, et al. J. Photochem. Photobiol. A，2018，352: 86.
[12] Grabchev I, Bojinov V. J. Photochem. Photobiol. A: Chem., 2001, 139: 157.
[13] Trotter P J, White P A. Appl. Spectrosc., 1978, 32: 323.
[14] Skoog D A. Principle of Instrumental Analysis. 3rd ed. Ch. 7. Saunders College Publishing, New York, 1985.
[15] Kiefer W, Bernstein H J. Chem. Phys. Lett., 1972, 16: 5.
[16] Andrews L, Prochaska E S, Loewenschuss A. Inorg. Chem., 1980, 19: 463.
[17] Kaya K, Mikami N, Udagawa Y, et al. Chem. Phys. Lett., 1972, 16: 151.
[18] Abu-Eittah R, El-Kourashy A. J. Phys. Chem., 1972, 76(17): 2405.
[19] Briegleb G, Angew Z. Chem., 1964, 76: 326.
[20] Martin A N, Swarbrick J, Cammarata A. Physical Pharmacy, 3<sup>rd</sup> ed. Lee and Febiger, Philadelphia, PA, 1969. 344.
[21] Rathore R, Lindeman S V, Kochi J K. J. Am. Chem. Soc., 1997, 119: 9393.
[22] Tsubomura H, Lang R P. J. Am. Chem. Soc., 1961, 83: 2085.
[23] Aloisi G G, Pignataro S. J. Chem. Soc. Faraday Trans., 1973, 69: 534.
[24] Briegleb G, Czekalla J, Physikchem Z, et al. Chem. (Frankfurt), 1960, 24: 237.
[25] Pandeeswaran M, Elango K P. Spectrochim. Acta A, 65: 1148.
[26] El-Habeeb A A, Refat M S. Russ. J. Gen. Chem., 2015, 85(4): 939.
[27] Nour E M, Shahada L A. Spectrochim. Acta A, 1989，45: 1033.
[28] Kiefer W, Bernstein H J. Chem. Phys. Let., 1972, 16: 5.
[29] Coats A W, Redfern J P. Nature，1964，201: 68.
[30] Karipcin F, Dede B, Caglar Y, et al. Opt. Commun., 2007, 272: 131.
[31] Yakuphanoglu F, Cukurovali A, Yilmaz I. Opt. Mater, 2005, 27: 1363.
[32] Hoffman M, Martin S, Choi W, et al.Chemical Review, 1995, 95: 69.
[33] Fu M L, Guo G G, Liu X, et al. Inorg. Chem. Comm., 2005, 8: 18.
[34] Grabchev I, Bojinov V. Polym. Degrad. Stab., 2000, 70: 147.
[35] Esumi K, Hayakawa K, Yoshimura T. J. Colloid and Interface Science, 2003, 268(2): 501.
