Abstract：The emission spectra of OH(A2Σ→X2Π, O—O), O(3p5P→3s5S02) and Hα(3P→2S) produced by the positive pulsed corona discharge of N2 and H2O mixture in a needle-plate reactor have been successfully recorded against a severe electromagnetic interference coming from the pulsed corona discharge at one atmosphere. The relative populations and the vibrational temperature of N2(C, v′) were determined. The emission intensity of OH(A2Σ→X2Π, 0—0) is obtained through the simulation of the emission spectra of the Δv=+1 vibration transition band of N2(C3Πu→B3Πg). Relative populations of OH(A2Σ), O(3p5P) and Hα(3P) have been obtained by the emission intensity of OH(A2Σ→X2Π, 0—0), O(3p5P→3s5S02) and Hα(3P→2S) and Einstein’s transition probability. The effects of discharge voltage and pulse repetition rate and oxygen flow on the relative populations of OH(A2Σ), O(3p5P) and Hα(3P) are investigated.
王文春，刘 峰，张家良，任春生 . 利用发射光谱研究脉冲电晕放电中的自由基[J]. 光谱学与光谱分析, 2004, 24(11): 1288-1292.
WANG Wen-chun, LIU Feng, ZHANG Jia-liang, REN Chun-sheng. Study of Radicals in Pulsed Corona Discharge by Emission Spectroscopy . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(11): 1288-1292.
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