Detection of Organophosphorus Pesticide Residue on the Surface of Apples Using SERS
LI Xiao-zhou1, YU Zhuang1, YANG Tian-yue1, DING Jian-hua2
1. School of Science, Shenyang Ligong University, Shenyang 110159, China 2. School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024, China
Abstract:Traditional pesticide residue detection methods are usually complicated, time-consuming, and destructive. Rapid, nondestructive, online real-time is the development direction of the pesticide testing. In the present paper, we use surface enhanced Raman spectroscopy (SERS) technique to detect the organophosphorus pesticide residue of phorate and fenthion on apple to investigate a fast, nondestructive detection method for the pesticide of phorate and tiguron on apples. The results show that the characteristic frequencies of the two organophosphorus pesticides are easier to identify using surface-enhanced Raman spectroscopy. We select Raman signal at 728 cm-1 for phorate and that at 1 512 cm-1 for fenthion as target peak for quantitative analysis, and use an internal standard to establish phorate and fenthion linear regression model. This method can be used as a quantitative analysis reference of phorate and fenthion.
Key words:Pesticide residues;Surface enhanced Raman spectroscopy;Qualitative and quantitative analysis
李晓舟1,于 壮1,杨天月1,丁建华2 . SERS技术用于苹果表面有机磷农药残留的检测 [J]. 光谱学与光谱分析, 2013, 33(10): 2711-2714.
LI Xiao-zhou1, YU Zhuang1, YANG Tian-yue1, DING Jian-hua2 . Detection of Organophosphorus Pesticide Residue on the Surface of Apples Using SERS . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(10): 2711-2714.
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