光谱学与光谱分析 |
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The Study of Advanced Fundamental Parameter Method in EDXRFA |
CHENG Feng, ZHANG Qing-xian*, GE Liang-quan, GU Yi, ZENG Guo-qiang,LUO Yao-yao, CHEN Shuang, WANG Lei, ZHAO Jian-kun |
Chengdu University of Technology, Chengdu 610059, China |
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Abstract The X-ray Fluorescence Analysis(XRFA) is an important and efficient method on the element anylsis and is used in geology, industry and environment protection. But XRFA has a backdraw that the determination limit and accuracy are effected by the matrix of the sample. Now the fundamental parameter is usually used to calculate the content of elements in XRFA, and it is an efficient method if the matrix and net area of characteristic X-ray peak are obtained. But this is invalide in in-stu XRFA. Also the method of net area and the “black material” of sample are the key point of the fundamental parameter method when the Energy Dispersive X-ray Fluorescence Analysis(EDXRFA) method is used in the low content sample. In this paper a advanced fundamental parameter method is discussed. The advanced fundamental parameter method includes the spectra analysis and the fundamental parameter method, which inserts the overlapping peaks separation method into the iteration process of the fundamental parameter method. The advanced method can resolve the net area and the quantitative analysis. The advanced method is used to analyse the standard sample. Compare to the content obtained from the coefficient method, the precision of Cu, Ni and Zn is better than coeffieciency method. The result shows that the advanced method could improve the precision of the EDXRFA, so the advanced method is better than the coefficient method.
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Received: 2014-12-29
Accepted: 2015-03-08
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Corresponding Authors:
ZHANG Qing-xian
E-mail: shinecore@163.com
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[1] GE Liang-quan, et al(葛良全, 等). In-Situ XRF Sampling Technique(原位X荧光取样技术). Chengdu: Sichuan Publishing House of Science and Technology(成都:四川科学技术出版社),1997. [2] JI Ang, ZHUO Shang-jun, LI Guo-hui(吉 昂, 卓尚军, 李国会). Energy Dispersive X-Ray Fluorescence Spectrometry(能量色散X射线荧光光谱). Beijing: Science Press(北京:科技出版社),2011. [3] CAO Li-guo(曹利国). Energy Dispersive X-Ray Fluorescence Method(能量色散X射线荧光方法). Chengdu: Publishing House of Chengdu University of Science and Technology(成都: 成都科技大学出版社), 1998. [4] Criss J W. NRLXRF, A Fortran Program for X-Ray Fluorescence Analysis. Naval Research Laboratory, 1977. [5] http://www.amptek.com/products/xrs-fp-quantitative-xrf-analysis-software/, 2014. 11. [6] Borkhodoev V Y. X-Ray Spectrom.,2002,31: 209. [7] Dariusz Wegrzynek, Andrzej Markowicz,Ernesto Chinea-Cano. X-Ray Spectrom., 2003, 32: 119. [8] Dariusz Wegrzynek, Andrzej Markowicz, Ernesto Chinea-Cano et al. Advances in X-Ray Analysis, 2003, 46: 388. [9] Ryan C G, Clayton E, Griffin W L,et al. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms,1988,(34):396. [10] LI Ti-bei, WU Mei(李惕培,吴 枚). Research in Astronomy and Astrophysics(天体物理学报),1993,(3):215. [11] Fudan University, Tsinghua University, Peking University(复旦大学,清华大学,北京大学). Nuclear Physics Experiment Method(原子核物理实验方法). Beijing: Atomic Energy Press(北京:原子能出版社),1992. [12] Beckhoff B, Kanngieber B, Langhoff N, et al. Handbook of Practical X-Ray Fluorescence Analysis. Spring, 2006. [13] Elam W T, Ravelb B D, Sieber J R. Radiation Physics and Chemistry, 2002; 63: 121. |
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