| 光谱学与光谱分析 |
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| Photochromic Properties of Complexes of Curcumin Aniline Schiff Base with Rare Earth |
| SONG Yu-min, YANG Mei-ling,MA Jun-huai, ZHANG Yu-mei |
| College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China |
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Abstract Using Ce, La, Nd (Ⅲ) nitrate and a curcumin aniline schiff base and a curcumin bis (4-methyl aniline) schiff base as raw materials, six complexes were synthesized. Through the molar conductance, IR, TG-DTA and element analysis motheds, the structures of complexes were characterized. Moreover, the properties of UV-Visible spectra and photochromic properties of the complex，and the solvate-chromic performance in organic solvents were explored. The experiments showed that the complexes have good photochromic and solvate-chromic properties. The fluorescence intensity and UV-Visible spectra intensity were reduced under exposure，and the color of the complex solution became light. The complexes have different UV-Visible spectra in difference organic solvents. The relationship between photochromic properties and time was also studied.
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Received: 2013-05-10
Accepted: 2013-07-14
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Corresponding Authors:
SONG Yu-min
E-mail: songym@nwnu.edu.cn
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