光谱学与光谱分析 |
|
|
|
|
|
Analytical Figures of Merit of Hildebrand Grid and Ultrasonic Nebulizations in Inductively Coupled Plasma Atomic Emission |
TIAN Mei1, HAN Xiao-yuan1, ZHUO Shang-jun2, ZHANG Rui-rong1 |
1. Northwest Institute of Nuclear Technology, Xi’an 710024, China 2. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China |
|
|
Abstract Hildebrand grid nebulizer is a kind of improved Babington nebulizer, which can nebulize solutions with high total dissolved solids. And the ultrasonic nebulizer(USN) possesses advantage of high nebulization efficiency and fine droplets. In the present paper, the detection limits, matrix effects, ICP robustness and memory effects of Hildebrand grid and ultrasonic nebulizers for ICP-AES were studied. The results show that the detection limits using USN are improved by a factor of 6~23 in comparison to Hildebrand grid nebulizer for Cu,Pb,Zn,Cr,Cd and Ni. With the USN the matrix effects were heavier, and the degree of intensity enhancement and lowering depends on the element line, the composition and concentrations of matrices. Moreover, matrix effects induced by Ca and Mg are more significant than those caused by Na and Mg, and intensities of ionic lines are affected more easily than those of atomic lines. At the same time, with the USN ICP has less robustness. In addition, memory effect of the USN is also heavier than that of Hildebrand grid nebulizer.
|
Received: 2011-08-29
Accepted: 2011-11-20
|
|
Corresponding Authors:
TIAN Mei
E-mail: tmhxy@sohu.com
|
|
[1] XUN Yan-fu, ZHENG Jian, FENG Guo-dong, el al(郇延富, 郑 健, 冯国栋,等). Chinese Journal of Analytical Chemistry(分析化学), 2003, 31: 490. [2] Jolanta Borkowska-Burnecka, Anna Lesniewicz, Wieslaw Zyrnicki. Spectrochimica Acta Part B, 2006, 61: 579. [3] ZHOU Shi-ping, RONG Hui-feng, YIN Jia-yuan, et al(周世萍, 荣惠锋, 尹家元, 等). Chemical World(化学世界), 2001, 42: 601. [4] ZHANG Jun-qing, ZHANG Yue-zhong, LIU Zhong-xing(张俊卿, 张月忠, 刘中兴). Journal of Instrumental Analysis(分析测试学报), 2002, 21(4): 27. [5] Juan Mora, Salvador Maestre, Vicente Hernandis, et al. Trends in Analytical Chemistry, 2003, 22(3): 123. [6] Timothy S Conver, John A Koropchak. Spectrochimica Acta Part B, 1995, 50B: 341. [7] Mermet J M. Spectrochim. Acta Part B, 1989, 44: 1109. [8] José-Luis Todolí, Jean-Michel Mermet. Spectrochimica Acta Part B, 1999, 54: 895. |
[1] |
CHEN Xiao-li1, WANG Li-chun1, LI You-li1, GUO Wen-zhong1, 2*. Effects of Alternating Light Spectrum on the Mineral Element Level of Lettuce[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2813-2817. |
[2] |
LIAN Xiao-qin1, 2,LIU Yu1, 2,CHEN Yan-ming1, 2,HUANG Jing1, 2,GONG Yong-gang1, 2,HUO Liang-sheng1, 2. Research on Multi-Peak Spectral Line Separation Method Based on Adaptive Particle Swarm Optimization[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1452-1457. |
[3] |
ZHA Ling-yan1,2, ZHANG Yu-bin1,2, LI Zong-geng1,2, LIU Wen-ke1,2*. Effect of Continuous Red/Blue LED Light and Its Light Intensity on Growth and Mineral Elements Absorption of Lettuce[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2474-2480. |
[4] |
LIU Bing-bing, LIU Jia, ZHANG Chen-ling, HAN Mei, JIA Na, LIU Sheng-hua*. Preconcentration and Determination of Heavy Metals in Water Samples by Ion Exchange Resin Solid Phase Extraction with Inductively Coupled Plasma Atomic Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(12): 3917-3922. |
[5] |
TIAN Ying-gang, HU Qing-qing, XIE Ming-yong. Comparison of Mineral Element Contents in Silky Fowl and Non-Medicinal Chicken[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3563-3566. |
[6] |
LIU Jia, LIU Bing-bing, HAN Mei, JIA Na, ZHANG Chen-ling*. Methodology Research for Determination of Total Phosphorus in Water by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1880-1883. |
[7] |
CHEN Hua-zhou1, 2, XU Li-li3, CAI Ken4*, LIU Zhen-yao2, 5, CHEN An1, LIANG Yuan-yuan2. Performance Diagnosis of ICP-AES Combined with SVDV Technology for Quality Analysis of Drinking Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1558-1562. |
[8] |
ZHANG Wen-li1, 2, 3, LONG Ping1, 2, 3*, WU Jian1, 2, 3, CHEN Xiu-min1, 2, 3, XIONG Heng1, 2, 3, YANG Bin1, 2, 3. Determination of Sulfur in Solid and Solution of Phosphate Ore Pulp Flue Gas Desulfurization Agent with ICP-AES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1535-1539. |
[9] |
QI Li-jie, WANG Ying*, MENG Qing-zhu, ZHAO Zhen . Study on the Element Composition of Ancient Fossils and Meteorites [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(01): 247-249. |
[10] |
XIAN Yi-heng1, LI Yan-xiang1, TAN Yu-chen1, WANG Wei-lin2, YANG Qi-huang2, CUI Jian-feng3 . Application of LA-ICP-AES to Distinguish the Different Turquoise Mines [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3313-3319. |
[11] |
CAO Lei1, CHEN Wei-wei2, GAO Xiao-li1, LIAO Qi-lin1 . Research on the Matrix Interference on Major and Minor Elements in Soil Samples with ICP-AES [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(07): 2260-2265. |
[12] |
LIU Kun1, LIAO Hua1, ZHENG Pei-chao2, WANG Chen-ying1, LIU Hong-di2, Dobrynin Danil3 . The Characteristic Research of ·OH Induced by Water on an Argon Plasma Jet[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1791-1796. |
[13] |
CHEN Xi1, DU Peng1, GUAN Qing2, FENG Xu3, XU Dong-qun1*, LIN Shao-bin1* . Application of ICP-MS and ICP-AES for Studying on Source Apportionment of PM2.5 during Haze Weather in Urban Beijing[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(06): 1724-1729. |
[14] |
LIU Bing-bing, HAN Mei*, JIA Na, LIU Sheng-hua . Determination of SiO2 in Groundwater and Mineral Water by Inductively Coupled Plasma-Atomic Emission Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(05): 1388-1391. |
[15] |
QIN Wen-xia, GONG Qi*, LI Min, DENG Li-xin, MO Li-shu, LI Yan-lin . Determination of Arsenic in Food Package Aluminum by Ultrasound Assisted Solid Phase Extraction/ICP-AES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 1043-1047. |
|
|
|
|