| 光谱学与光谱分析 |
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| Studies on the Remote Measurement of the Emission of Formaldehyde by Mobile Differential Optical Absorption Spectroscopy |
| WU Feng-cheng, XIE Pin-hua*, LI Ang, SI Fu-qi, DOU Ke, LIU Yu, XU Jin, WANG Jie |
| Key Laboratory of Environmental Optics & Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China |
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Abstract Formaldehyde (HCHO) is the most abundant carbonyl compounds that play an important role in atmospheric chemistry and photochemical reactions. Formaldehyde is an important indicator of atmospheric reactivity and urban atmospheric aerosol precursors. In the present paper, the emission of formaldehyde from chemical area was measured using the mobile differential optical absorption spectroscopy (DOAS). This instrument uses the zenith scattered sunlight as the light source with successful sampling in the area loop. Vertical column density was retrieved by this system, combined with the meteorological wind field and car speed information, the emission of formaldehyde in the area was estimated. The authors carried out the measuring experiment in one chemical plant in Beijing using this technology. The result showed that the average value of the flux of formaldehyde in this area was 605 kg·h-1 during the measuring period.
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Received: 2010-11-08
Accepted: 2011-03-15
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Corresponding Authors:
XIE Pin-hua
E-mail: phxie@aiofm.ac.cn
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[1] Grosjean D. Environmental Science Technology，1982，16：254.
[2] Wisthaler A, Apel E C, Bossmeyer J, et al. Atmos. Chem. Phys., 2007, 7: 1347.
[3] Benning L, Wahner A. Journal of Atmospheric Chemistry, 1998, 31: 105.
[4] Jeong Soon LEE, Young J KIM, Bongjae KUK, et al. Environmental Monitoring and Assessment, 2005, 104: 281.
[5] An Junling, Zhang Wei, Qu Yu. Atmospheric Environment, 2009, 43: 3454.
[6] Heckel A, Richter A, Tarsu T, et al. Atmos. Chem. Phys. Discuss., 2004, 4: 1151.
[7] Inomata S, Tanimoto H, Kameyama S, et al. Atmos. Chem. Phys., 2008, 8: 273.
[8] Christophe Lerot, Isabelle De Smedt, Trissevgeni Stavrakou, et al. Atmosheric Science Conference, 2009, 7-11 Barcelona(Spain), 2009.
[9] Zheng Junyu, Zhang Lijun, Che Wenwei, et al. Atmospheric Environment, 2009, 43: 5112.
[10] Lei W, Foy B de, Zavala M, et al. Atmos. Chem. Phys., 2007, 7: 1347.
[11] Lei W, Zavala M, Foy B de, et al. Atmos. Chem. Phys., 2009, 9: 2607.
[12] Johansson M, Rivera C, Foy B de, et al. Atmos. Chem. Phys., 2009, 9: 5647.
[13] Rivera C, Sosa G, Wohrnschimmel H, et al. Atmos. Chem. Phys., 2009, 9: 6351.
[14] Fay C, Roozendael Van, WinDOAS2.1 Software User Mannual [OL].IASB/BIRA, 2001-2.
[15] Grainger J F, Ring J. Nature, 1962, 193: 762.
[16] Solomon S, Schmeltekopf A L, Sanders R W. J. Geophys. Res., 1987, 92: 8311.
[17] Johan Mellqvist, Jerker Samuelsson, Claudia Rivera. Final Report Harc Project H-53, 2003. |
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