光谱学与光谱分析 |
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Study of the Physical Properties of SnS Thin Films Deposited by Ultrasonic Spray Pyrolysis Method |
TANG Ping, LI Bing, LEI Zhi*,FENG Liang-huan, CAI Ya-ping, ZHENG Jia-gui, ZHANG Jing-quan, LI Wei, WU Li-li, ZENG Guang-gen |
College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China |
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Abstract In the present paper, SnS thin films were deposited by ultrasonic spray pyrolysis method. The influence of the three different precursor concentrations on the properties of SnS thin films was compared. XRD shows that when precursor solution is thiourea (0.5 mol·L-1) + tin tetrachloride (0.5 mol·L-1)+deionized water, there are SnS and SnO2 mixed phases; when precursor solution is thiourea (0.6 mol·L-1)+tin tetrachloride (0.5 mol·L-1)+deionized water, SnS phase is the dominant diffraction peak, although a certain amount of SnO2 phase is contained; when precursor solution is thiourea (0.7 mol·L-1)+tin tetrachloride (0.5 mol·L-1)+deionized water, thin film after being annealed is single SnS thin film with orthorhombic structure. SEM shows that films are uniform and dense. Furthermore, the particles of films are bigger when thiourea concentration is higher. Transmittance spectrum shows that the influence of precursor concentration on transmittance of thin films is less. Dark I-V and C-V tests of the devices show that junction characteristics of the devices were similar when prepared by three different concentrations of precursor solution, and as the thiourea concentration is higher, the carrier concentration is relatively larger.
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Received: 2010-11-22
Accepted: 2011-03-15
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Corresponding Authors:
LEI Zhi
E-mail: leizhi328@yahoo.com.cn
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[1] Ramakrishna Reddya K T, Koteswara Reddya N, Miles R W. Solar Energy Materials and Solar Cells, 2006, 90: 3041. [2] An C H, Tang K B, Jin Y, et al. Journal of Crystal Growth, 2003, 252: 581. [3] ZHENG Chun-rui, LEI Tian-min, HU Yong-hong(郑春蕊, 雷天民, 胡永红). Micronanoelectronic Techology(微纳电子技术), 2005,2: 66. [4] Takeeuchi K, Ichimura M,Arai E, et al. Solar Energy Materials and Solar Cells, 2003, 75: 427. [5] Li Q, Ding Y, Wu H, et al. Materials Research Bulletin, 2002, 37: 925. [6] Yanuar F. Journal of Materials Science Letters, 2000, 19(23): 2135. [7] Tanusevski A. Semicond Sci. Technol., 2003, 18(6): 505. [8] Ristov M, Sinadiovski G, Mitreski M. Solar Energy Materials & Solar Cells, 2001, 69: 17. [9] Ichimura M, Takeuchi K, Ono Y, et al. Thin Solid Films, 2000, 361: 98. [10] Zulkarnain Zainal, Mohd Zobir Hussein, Arniza Ghazali. Solar Energy Materials and Solar Cells, 1996, 40: 347. [11] Subramanian B, Sanjeeviraja C, Jayachandran M. Materials Chemistry and Physics, 2001, 71: 40. [12] Tanusevski A. Solar Energy Materials and Solar Cells, 2003, 80(3):297. [13] Reddy K T R, Reddy P P, Miles R W, et al. Optical Materials, 2001, 17: 295. [14] Koteeswara Reddy N, Ramakrishna Reddy K T. Materials Research Bulletin, 2006, 41: 414. [15] Koteeswara Reddy N, Ramakrishna Reddy K T. Thin Solid Films, 1998, 325: 4. [16] Reddy K T R, Reddy P P, Datta P K, et al. Thin Solid Films, 2002, (403-404): 116. [17] Jayachandran M. Journal of Materials Science Letters, 2001, 20(4): 381. |
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