光谱学与光谱分析 |
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Influence of Ancient Glass Samples Surface Conditions on Chemical Composition Analysis Using Portable XRF |
LIU Song1,LI Qing-hui1*,GAN Fu-xi1, 2 |
1. Center of Sci-tech. Archaeology, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China 2. Fudan University, Shanghai 200433, China |
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Abstract Portable X-ray fluorescence analysis (PXRF) is one kind of surface analysis techniques, and the sample surface condition is an important factor that influences the quantitative analysis results. The ancient glass samples studied in the present paper were excavated from Xinjiang, Guangxi, Jiangsu provinces, and they belong to Na2O-CaO-SiO2, K2O-SiO2, and PbO-BaO-SiO2 system, respectively. Quantitative analysis results of weathered surface and inside of the ancient glass samples were compared. The concentration change of main fluxes in different parts of the samples was pointed out. Meanwhile, the authors studied the effect of distance between the sample and the reference plane, and curve shape of the sample on the quantitative results. The results obtained were calibrated by three methods, and the validity of these three methods was proved. Finally, the normalizing method was proved to be a better method for quantitative analysis of antiques. This paper also has guiding significance for chemical composition analysis of ancient jade samples using PXRF.
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Received: 2010-08-24
Accepted: 2010-11-30
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Corresponding Authors:
LI Qing-hui
E-mail: qinghuil@sina.com
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[1] Nakai I, Yamada S, Terada Y, et al. X-Ray Spectrom., 2005, 34: 46. [2] Uhlir K, Griesser M, Buzanich G, et al. X-Ray Spectrom., 2008, 37: 450. [3] Pifferi A, Campi G, Giacovazzo C, et al. Croat. Chem. Acta, 2009, 82(2): 449. [4] Kato N,INakai, Shindo Y. Journal of Archaeological Science, 2009, 36: 1698. [5] Papageorgiou I, Liritzis I. Archaeometry, 2007, 49(4): 795. [6] Nathan Craig, Robert J Speakman, Rachel S, et al. Journal of Archaeological Science, 2007, 34: 2012. [7] Uhlir K, Griesser M, G. Buzanich G, et al. X-Ray Spectrom., 2008, 37: 450. [8] Ferrero J L, Roldán C, Juanes D, et al. X-Ray Spectrom., 2002, 31: 441. [9] LI Qing-hui, GU Dong-hong, GAN Fu-xi, et al(李青会,顾冬红,干福熹, 等). Nuclear Techniques(核技术), 2003, 26(12): 922. [10] LIU Song, LI Qing-hui, GAN Fu-xi, et al(刘 松,李青会,干福熹, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2010, 30(9):2576. [11] TAO Guang-yi(陶光仪). The Proceedings of 1989 International Symposium on Ancient Ceramics, 1989. 127. [12] HE Wen-quan, XIONG Ying-fei(何文权, 熊樱菲). Nuclear Techniques(核技术),2002, 25(7): 581. [13] Potts P J, Webb P C, Thopre O W. Journal of Analytical Atomic Spectrometry, 1997, 12: 769. [14] WU Zong-dao, ZHOU Fu-zheng, SHI Mei-guang(吴宗道,周福征,史美光). Journal of Chinese Electron Microscopy Society(电子显微学报), 1986, 5: 65. [15] SONG Yan, MA Qing-lin(宋 燕, 马清林). Glass & Enamel(玻璃与搪瓷), 2008, 36(2): 35.
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