| 光谱学与光谱分析 |
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| Controlled Syntheses and Photoluminescence Characterization of Monoclinic Cerium Orthophosphate with Nanostructure |
| BAO Jin-rong1, ZHU Xiao-wei2*, WEI Li-si2, PENG Jun-wen2, LI Wen-xian1 |
1. The College of Chemistry &Chemical Engineering, University of Inner Mongolia, Huhhot 010021, China
2. Medical College of Inner Mongolia, Huhhot 010110, China |
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Abstract The nanostructured CePO4 with monoclinic phase was controllably synthesized through a low temperature hydrothermal route by varying the reactant PO3-4/Ce3+ molar ratio. The structures, morphologies, sizes and luminescence properties of the products were studied by XRD, FE-SEM, DSC-TG and photoluminescence spectra. With the PO3-4/Ce3+ molar ratios increased, the synthesis temperature of as-synthesized monoclinic CePO4 was decreased, and the morphologies underwent the evolution from the rod-like nano-structures to the flower-like nanoclusters. When the PO3-4/Ce3+ molar ratio was lower, CePO4 nanorods were obtained, while the PO3-4/Ce3+ molar ratio was higher, the monoclinic CePO4 flower-like nanoclusters were crystallized. The photoluminescence spectrum showed that the CePO4 nanorods exhibit better photoluminescent property than the CePO4 flower-like nanoclusters. With the cycling use of phosphoric acid, the low-cost preparation of CePO4 could be achieved.
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Received: 2010-06-12
Accepted: 2010-09-10
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Corresponding Authors:
ZHU Xiao-wei
E-mail: zxwtxwd@sina.com
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[1] Hiruma K, Yazawa M, Katsuyama T, et al. J. Appl. Phys., 1995, 77(2): 447.
[2] Hu J, Odom T W, Lieber C M. Acc. Chem. Res., 1999, 32(5): 435.
[3] Justin J D, Johnston K P, Doty R C, et al. Science, 2000, 287: 1471.
[4] Huang M, Mao S, Feick H, et al. Science, 2001, 292: 1897.
[5] Xia Y, Yang P. Adv. Mater., 2003, 15(5): 351.
[6] Rambabu U, Munirathnam N R, Prakash T L, et al. Mater. Chem. Phys., 2002, 78(1): 160.
[7] Rajesh K, Mukundan P, Krishna Pillai P, et al. Chem. Mater., 2004, 16(14): 2700.
[8] Bregiroux D, Lucas S, Champion E. J. Eur. Ceram. Soc., 2006, 26(3): 279.
[9] Cao M H, Hu C W, Wu Q Y. Nanotechnology, 2005, 16(2): 282.
[10] Fang Y P, Xu A W, Song R Q, et al. J. Am. Chem. Soc., 2003, 125(51): 16025.
[11] Zhang J Y, Zhang Z T, Tang Z L. J. Mater. Process Technol., 2002, 121: 265.
[12] Riwotzki K, Meyssamy H, Kornowski A, et al. J, Phys, Chem., B, 2000, 104(13): 2824.
[13] Riwotzki K, Meyssamy H, Schnablegger H, et al. Angew. Chem. Int. Ed, 2001, 40(3): 573.
[14] Peng Z A, Peng X G. J. Am. Chem. Soc., 2001, 123(7): 1389.
[15] Zhang Y J, Guan H M. J. Cryst. Growth, 2003, 256(1-2): 156.
[16] Wickleder M S. Chem. Rev., 2002, 102(6): 2011.
[17] Bao J R, Yu R B, Zhang J Y, et al. Cryst. Eng. Comm., 2009, 11: 1630.
[18] Jüstel T, Nikol H, Ronda C. Angew. Chem. Int. Ed, 1998, 37(22): 3084. |
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