| 光谱学与光谱分析 |
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| Study on the Conversion of Acrylic CC Double Bonds during Dark Reaction after UV Curing Using Infrared Spectroscopy |
| MA Guo-zhang1, 2，WU Jian-bing2，XU Bing-she1, 3 |
1. College of Materials Science and Engineering of Taiyuan University of Technology, Taiyuan 030024, China
2. Shanxi Institute of Applied Chemistry, Taiyuan 030027, China
3. Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China |
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Abstract Infrared spectroscopy was used to determine 1 648-1 589 cm-1 characteristic absorption peak area so as to study the conversation of acrylic CC double bonds after UV curing. The effects of phototinitiators, active diluents and UV curing resins on the conversion of CC double bonds were also investigated. The results showed that 40%-85% of CC double bonds were conversed during dark reaction after 45 s UV curing. Dark reaction will be changed gently after 1.75 h, but 95% conversion of CC double bonds needed more than 24 h. The rates of polymerization and conversation were affected by photoinitiators, the concentration of photoinitiator, oxygen inhibition, and CC functional groups of active diluents. The rate of polymerization was affected by the CC functional groups and types of UV curing resins, but conversation was not.
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Received: 2009-09-02
Accepted: 2009-12-03
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Corresponding Authors:
MA Guo-zhang
E-mail: maguozhang@hotmail.com
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[1] Hirose Masakazu, Zhou Jianhui, Kadowaki Fumiyuki. Colloids and Surfaces A: Physiochemical and Engineering Aspects, 1999, 153: 481.
[2] Corrales T, Catalina F, Peinado C, et al. Journal of Photochemistry and Photobiology A: Chemistry, 2003, 159: 103.
[3] CHEN Yong-lie, ZENG Zhao-hua, YANG Jian-wen(陈用烈，曾兆华，杨建文). Radiation Curing Material and Application(辐射固化材料及其应用). Beijing: Chemical Industry Press(北京：化学工业出版社)，2005. 38.
[4] Peinado Carmen, Allen N S, Salvador Enrique F, et al. Polymer Degradation and Stability, 2002, 77: 523.
[5] Jager W F, Nekers D C. Polymer Preprints, 1995, 36(2): 89.
[6] ZHANG Guo-bin, FAN Xiao-dong, LIU Yu-yang(张国彬，范晓东，刘郁杨). Acta Polymeria Sinica(高分子学报), 2007, 7: 644.
[7] Bentivoglio Ruiz C S, Machado L D B, Volponi J E, et al. Journal of Thermal Analysis and Calorimetry, 2004, 75(2): 507.
[8] XIONG Hua-fu, ZHENG Hong-juan, LU Shan-feng, et al(熊华富，郑红娟，陆山风, 等). Polymer Materials Science and Engineering(高分子材料科学与工程), 2005, 21(2): 267.
[9] Scherzer T, Tauber A, Mehnert R. Vibrational Spectroscopy, 2002, 29: 125.
[10] Stanbury J W, Dickens S H. Dental Material, 2001, 17: 71.
[11] Wu K C, Halloran J W. Journal of Materials Science, 2005, 40: 71.
[12] Scherzer Tom, Müller Sabine, Mechnert Reiner, et al. Nuclear Instruments and Methods in Physics Research B, 2005, 236: 123.
[13] Lü Bo, NIE Jun(吕 波，聂 俊). Photographic Science and Photochemistry(感光科学与光化学), 2005, 23(5): 321.
[14] CHEN Jing-min, HUA Feng-jun, QIU Jiang, et al(陈靖民, 华峰君，邱 江, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(1): 47.
[15] Trujillo M, Newman S M. Stansbury J W. Dental Materials, 2004, 20(20): 766.
[16] LIU Cheng-mei, CAO You, GAN Zhi-wei, et al(刘承美，曹 悠，甘志伟, 等). Chemical Propellants and Polymeric Materials(化学推进剂和高分子材料), 2003, 1(3): 3.
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