| 光谱学与光谱分析 |
|
|
|
|
|
| High Temperature Raman Spectra and Structure Study of Stolzite-Structured PbWO4 Crystals and Its Melt |
| ZHOU Feng-yu, YOU Jing-lin*, WANG Yuan-yuan, WANG Wei |
| School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China |
|
|
|
|
Abstract Raman spectra of stolzite-structured PbWO4 crystal were recorded from 298 to 1 473 K. All the appearing vibrational modes were interpreted and assigned. The most intense mode at 902.7 cm-1, which is identified as the internal mode ν1(Ag)of symmetrical stretching attributed to the vibration of [WO4]2- tetrahedron. Temperature dependent characteristics of the Raman spectra of the crystal were investigated. Band half-widths widened accompanied by the relative intensity decreased, and the lattice became more disorder with the increase in temperature. As being heated up to 1 398 K, PbWO4 crystals began to be melting and have completely transformed to liquid state at 1 473 K, while the internal vibrational modes of isolated [WO4]2- tetrahedron have appeared and the symmetry of vibrational modes transformed from S4 in crystal into Td of [WO4]2- in melt. It suggested that the isolated [WO4]2- structure unit exists in the melt.
|
|
Received: 2009-05-10
Accepted: 2009-08-20
|
|
|
|
Corresponding Authors:
YOU Jing-lin
E-mail: jlyou@staff.shu.edu.cn
|
|
[1] FENG Xi-qi, YUAN Hui(冯锡淇, 袁 晖). Journal of Inorganic Materials(无机材料学报), 1996, 11(5): 385.
[2] Kobayashi M, Ishii M, Usuki Y, et al. Nucl. Instrum. Methods A, 1993, 333: 429.
[3] Ishii M, Kbayashi M. Cryst Growth Charact., 1992, 23: 245.
[4] Baryshevsky V, Korzhik M, Moroz V, et al. Nucl. Instrum. Methods A, 1992, 322: 231.
[5] Korzhik M, V Proe. Intemet. Conf. Inorganic Scintinators and Their Applications, SCINT96 Deft University Press Delft(The Netherlands), 1996. 241.
[6] Cavalcante L S, Sczancoski J C, Albarici V C, et al. Materials Science and Engineering B, 2008, 150: 18.
[7] Yu K Voron ko, Sobol A A. Inorganic Materials, 2005, 41(4): 420. Translated by Neorganic Heskie Materialy, 2005, 41(4): 493.
[8] You J L. Coupled Device, Synopsis of International Conf. on Raman Spectroscopy, Australia, 2004. 84.
[9] YOU Jing-lin, HUANG Shi-ping, JIANG Guo-chang(尤静林, 黄世萍, 蒋国昌). Journal of Chinese Rare Earths(中国稀土学报), 1998, 16: 505.
[10] You J L, Jiang G C, Hou H Y, et al. Raman Spectrosc., 2005, 36: 237.
[11] LUO Li-ming, TAO De-jie, WANG Ying-jian(罗丽明, 陶德节, 王英俭). Journal of Synthetic Crystals(人工晶体学报), 2004, 33(5): 287.
[12] XU Ke-qin, XUE Ji-yue, DING Yang, et al(徐克勤, 薛纪越, 丁 阳, 等). Acta Geologica Sinica(地质学报), 1994, 68(3): 820.
[13] Kaminskii A A, McCray C L, Lee H R, et al. Opt. Commun., 2000, 183: 277.
[14] Huang Y, Seo H J, Feng Q, et al. Mater. Sci. Eng. B, 2005, 121: 103.
[15] Jayaraman A, Batlogg B, Vanuitert L G. Phys. Rev. B, 1985, 31: 5423.
[16] Hardcastle F D, Wachs I E. Raman Spectrosc., 1995, 26: 397.
[17] Findeisen J, Eichler H J, Kaminskii A A. IEEE J. Quant. Electron., 1999, 35: 173.
[18] ZHANG Ming-rong, YIN Zhi-wen, LI Pei-jun, et al(张明荣, 殷之文, 李培俊, 等). Acta Physica Sinica(物理学报), 1998, 5(48): 898.
[19] Geng J, Lu D J, Zhu J J, et al. Phys. Chem. B, 2006, 110: 13777.
[20] Fu Hongbo, Pan Chengsi, Zhang Liwu, et al. Materials Research Bulletin, 2007, 42: 696.
[21] Basiev T T, Sobol A A, Yu K Voronko, et al. Optical Materials, 2000, 15:205.
|
| [1] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
| [2] |
LIU Guo-peng1, YOU Jing-lin1*, WANG Jian1, GONG Xiao-ye1, ZHAO Yu-fan1, ZHANG Qing-li2, WAN Song-ming2. Application of Aerodynamic Levitator Laser Heating Technique: Microstructures of MgTi2O5 Crystal and Melt by in-situ Superhigh Temperature Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2507-2513. |
| [3] |
WANG Fang1, 3, ZHU Nan2, CHEN Jing-yi1, ZAN Jia-nan3, XIAO Zi-kang1, LIU Chang1, LIU Yun-fei3*. Infrared Spectroscopy Study on Temperature Characteristics of Several Common Antibiotics and Therapeutic COVID-19 Drugs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3719-3729. |
| [4] |
CHEN Jing-yi1, ZHU Nan2, ZAN Jia-nan3, XIAO Zi-kang1, ZHENG Jing1, LIU Chang1, SHEN Rui1, WANG Fang1, 3*, LIU Yun-fei3, JIANG Ling3. IR Characterizations of Ribavirin, Chloroquine Diphosphate and
Abidol Hydrochloride[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2047-2055. |
| [5] |
SONG Chao1, 2, DING Ling1, 2, FAN Wen-hui1*. Study on Terahertz and Infrared Characteristic Absorption Spectra of Solid-State Fructose[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(09): 2700-2705. |
| [6] |
LIU Jian-wei, SHEN Jing-ling*, ZHANG Bo . Identification of Six Isomers of Dimethylbenzoic Acid by Using Terahertz Time-Domain Spectroscopy Technique [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3041-3045. |
| [7] |
ZHANG Xu1, ZHANG Jie3, YAN Zhao-wen3, ZHOU Xing-yu2, ZHANG Fu-jia3 . Purification of PTCDA by Vacuum Sublimation and Spectral Test and Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 885-888. |
| [8] |
LIU Qin, YOU Jing-lin*, WANG Yuan-yuan, WANG Chen-yang, WANG Jing, LIU Xiao-wei . Study on Microstructure of Jadeite Melt and Its Glass [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(10): 2705-2710. |
| [9] |
LIU Sheng-gang, LI Jun, JING Qiu-min. High Temperature Raman Spectrum Study of LiTaO3[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(04): 985-988. |
| [10] |
JI Zi-fang1, YOU Jing-lin1, 2*, SIMON Patrick2, WANG Yuan-yuan1, HOU Min1, WANG Li-hong1, ZHANG Guo-chun3, WAN Song-ming4, FU Pei-zhen3, WU Yi-cheng3, YIN Shao-tang4 . Microstructure Study on Bismuth Triborate Crystal and Its Melt at High Temperature by Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 127-131. |
| [11] |
TAO Wan-jun1, LIU Xiao-dong1*, ZHENG Xu-guang2, MENG Dong-dong1，GUO Qi-xin3 . Mid-Infrared and Raman Spectral Analysis of Geometrically Frustrated Natural Atacamite [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(09): 2431-2436. |
| [12] |
JIANG Li-lin1,2, SONG Yun-fei1, YANG Zhen-ling1, HE Xing1, LIU Wei-long1, YU Guo-yang1, WANG Yang1, YANG Yan-qiang1*. Research on the Spectral Properties of the Rhodamine 101 Dye [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(05): 1348-1351. |
| [13] |
NIU Yu-jing, YOU Jing-lin*, WANG Yuan-yuan, WANG Zhi-chao, DAI Su-juan, XU Jian-lun, ZHENG Shao-bo . Temperature Dependent Raman Spectra and Micro-Structure Study of Cuspidine in Solid and Liquid Phases [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(12): 3228-3231. |
| [14] |
XU Pei-cang1，LI Ru-bi1，SHANG Tong-ming1，ZHOU Jian1，SUN Jian-hua1，YOU Jing-lin2 . A Study of Phonon Vibration Like Modes for Aggregation Structure in Silicate Melts by High Temperature Raman Spectrum [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(05): 1261-1265. |
| [15] |
TANG Zhong-feng1,2,3, LIN Hai-tao1, CHEN Xiao-wei1, ZHANG Zeng-fang1,3 . Detection of Amino Acids Based on Terahertz Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(09): 2351-2356. |
|
|
|
|
