光谱学与光谱分析 |
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Spectral Analysis of Cu(Ⅰ), Zn(Ⅱ) Complexes of Schiff Base and Their Dismutation to O-2 Free Radical |
XIAN Jing-chun |
College of Chemistry and Life Science, Quanzhou Normal College, Quanzhou 362000, China |
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Abstract In the present paper a new 5-nitrosalicylaldehyde was prepared by the reaction of salicylaldehyde with mix acid, and this semicarbazide Schiff base ligand and its complex containing Cu(Ⅱ) and Ni(Ⅱ) were synthesized. Its compositions and structure were characterized by elemental analyses,thermal analyses,IR spectra and UV spectra,1H NMR and molar conductivity. The dismutation to O-2 free radical was also investigated. The result shows that the structure and thermodynamic properties were stable. The complexes showed a distinct -2 scavenging effect and some protective effects on hemoglobin of human erythrocyte in the system of -2 generating riboflavin with irradiation.
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Received: 2009-03-26
Accepted: 2009-06-28
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Corresponding Authors:
XIAN Jing-chun
E-mail: xjc019@yahoo.com.cn
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[1] LIN Qin,CHEN Dong-zhong,YU Xue-hai(林 沁,谌东中,余学海). Chin. J. Inorg. Chem.(无机化学学报),1998,14(3):287. [2] MA Chang-qin,WANG Xu-ning,ZHANG Wen-xing,et al(马长勤,王绪宁,张文兴,等). Acta Chim. Sin.(化学学报),1996,54:562. [3] HE Shui-xiang,CAO Wen-kai,YANG Rui,et al(何水祥,曹文凯,杨 锐,等). Chin. J. Inorg. Chem.(无机化学学报),2003,19(7):699. [4] BU Xin-yu,ZHANG Hua,LI Ya-ming,et al(卜鑫宇,张 华,李亚明,等). Fine Chemical Intermediates(精细化工中间体),2004,35(3):4. [5] WEI Qing,CHEN San-ping,PAN Rui-qi(魏 青,陈三平,潘瑞棋). Fine Chemical(精细化工),2000,17(3):178. [6] XIAN Jing-chun,HA Ri-bala, LI Rui-yan(贤景春, 哈日巴拉, 李瑞延). Chin. J. Inorg. Chem.(无机化学学报),2000,16(1):151. [7] SHI Wei-liang,CHEN De-yu(史卫良,陈德余). Acta Phys. -Chim. Sin.(物理化学学报),2001,17(2):181. [8] YAO Ke-min,WU Jing,CHEN De-yu,et al(姚克敏,吴 静,陈德余,等). Acta Chim. Sin.(化学学报),1998,56:900. [9] SHUN Shao-fa,HU Pei-zhi,ZHANG Lun,et al(孙绍发,胡培植,张 伦,等). Bull. Chemistry(化学通报),1998,10:36. [10] LI Jian-zhang,QIN Sheng-ying,LI Zhong-hui,et al(李建章,秦圣英,李仲辉,等). Acta Chim. Sin.(化学学报),1999,57:298. [11] ZHU Xin-de, LE Zhi-feng, WU Zi-shen(祝新德,乐芝风,吴自慎). Chin. J. inorg. Chem.(无机化学学报),1994,10(2):136. [12] WU Jing,YAO Ke-min,CHEN De-yu(吴 静,姚克敏,陈德余). Chem. J. of Chinese Universities(高等学校化学学报),1998,19(8):1211. [13] LIAGN Fang-zhen(梁芳珍). Chinese J. Appl. Chem.(应用化学),2003,20(7):693. [14] LIANG Fang-zhen,XU Ke-hua,YIN Lun-xiang,et al(梁芳珍,徐克花,殷伦祥,等). Bull. Chemistry(化学通报),1999,(8):37. [15] MAO Zong-wan,HANG Qing-wei, TANG Wen-xia(毛宗万,杭庆伟,唐雯霞). Chin. J. Inorg. Chem.(无机化学学报),1995,11(3):262. [16] SHI Shuang-qun,LIU Zhi-xian,LI Dian-xun(石双群,刘志贤,李殿勋). Chinese J. Appl. Chem.(应用化学),1998,15(2):52.
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