光谱学与光谱分析 |
|
|
|
|
|
Measurement of Near-UV Absorption Cross Sections of CS2 |
WANG Hai-tao1,HU Chang-jiang1,MU Yu-jing1*,Abdelwahid Mellouki2 |
1. Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085, China 2. Centre National de Recherche Scientifique, Institut de Combustion, Aérothermique, Réactivité et Environnement, Orléans France,45071 |
|
|
Abstract The UV-absorption cross sections of CS2 are reported. The absorption spectra were measured by using a diode array spectrometer over the wavelength range of 220-380 nm at room temperature (298±3)K. The maximum absorption cross section appeared around 315 nm with the value of σ(315 nm)=7.184×10-20 cm2·molecule-1. The measured data by this study were in good agreement with that reported in the literature, and used to estimate the photolysis of the CS2 in the atmosphere.
|
Received: 2008-03-16
Accepted: 2008-06-20
|
|
Corresponding Authors:
MU Yu-jing
E-mail: yjmu@rcees.ac.cn
|
|
[1] Charlson R J, Lovelock J E, Andreae M O, et al. Nature, 1987, 326: 655. [2] Crutzen P J. Geophys. Res. Lett., 1976, 3(2): 73. [3] Wayne R P. Chemistry of Atmospheres. Clarendon:Oxford Science Publications, Press, Oxford, 1985. [4] Kellogg W W, Cadle R D, Allen E R, et al. Science, 1972, 175(4022): 587. [5] Atkinson R, et al. Chem. Phys. Lett., 1978, 54(1): 14. [6] Cox R A, Sheppard D. Nature, 1980, 284: 330. [7] Wine P H, Shah R C, Ravishankara A R. J. Phys. Chem., 1980, 84(19): 2499. [8] Bonsang B, Nguyen B C, Gaudry A, et al. J. Geophy. Res., 1980, 85(C12): 7410. [9] Chen F Z, Wu C Y R. Geophys. Res. Lett., 1995, 22(16): 2131. [10] Carnovale F, White M G, Brion C. E. J. Electron Spectrosc. Relat. Phenom., 1981, 24(1): 63. [11] Cook G R, Ogawa M. J. Chem. Phys., 1969, 51(15): 2419. [12] Xu H, Joens J A. Geophys. Res. Lett., 1993, 20(11): 1035. [13] Mu Y, Abdelwahid M. J. Photochem. Photobio. A: Chem., 2000, 134(1): 31. [14] Hearn C H, Joens J A. J. Quant. Spectrosc. Radiat. Transfer., 1991, 45(2): 69. [15] Wine P H, Chameides W L, Ravishankara A R. Geophys. Res. Lett., 1981, 8(5): 543. [16] Wu C Y R, Judge D L. Geophys. Res. Lett., 1981, 8(7): 769. [17] Dove J E, Hippler H, Plach J, et al. J. Chem. Phys., 1984, 81(3): 1209. [18] Wood W P, Heicklen J. J. Phys. Chem., 1971, 75(7): 854. [19] Hardwick J L, Ono Y, Moseley J T. J. Phys. Chem., 1987, 91(17): 4506. [20] Finlayson-Pitts B J, Jr P J N. Atmospheric Chemistry, Canada:John Wiley & Sons Publications, Press, USA, 1986. [21] Atkinson R, Baulch D L, Cox R A, et al. J. Phys. Chem. Ref. Data, 1989, 18(3): 881. |
[1] |
PENG Wu-di1, NING Jia-lian2, CHEN Zhi-li1*, TANG Jin1, LIU Li-xi1, CHEN Lin1. Construction of CS2 Combustion Flame Spectral Radiation Model and Inversion of Characteristic Pollution Product Concentration[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 672-677. |
[2] |
ZHANG Kai-lin1, 2, ZHOU Min3, SHI Ying-ying2, LI Shu-qi2, MA Li-fu1, ZHANG Xian-yi3*, WANG Yan1, KONG Xiang-lei2, 4*. Development and Application of an Automated Program for Photodissociation Spectroscopy Study Based on a FT ICR Mass Spectrometer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2325-2331. |
[3] |
NING Jia-lian1, TANG Jin1, HU Tian-you1, LIU Qiang2, WANG Hao-wen1, CHEN Zhi-li1*. Study on Spectral Radiation Characteristics of Carbon Disulfide Flame Based on Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1377-1381. |
[4] |
LI Xiao-feng1, YAN Bei-bei2, ZHANG Da-yuan1, LI Hong1, LI Bo1*, CHEN Guan-yi2, LI Zhong-shan1. Instantaneous Imaging of Reaction Zone and CH3 Radicals in Flames Using Laser Photodissociation-Induced Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1799-1803. |
[5] |
FU Hai-ying1, CAO Xi-yan2, XING Zhao-guo2, WU Guo-zhong1 . Effect of Ionic Liquid [bmim][PF6] on the Transient Photolysis Behavior of Xanthone[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(07): 1744-1748. |
[6] |
CAO Xi-yan1,2, FU Hai-ying2*, ZHU Li1, 3*, WU Guo-zhong2. Laser Photolysis Study on Photo-Oxidation Reactions of Aromatic Amino Acids with Triplet 2-Methylanthraquinone[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(04): 916-920. |
[7] |
FU Hai-ying1,XING Zhao-guo1, 2,WU Guo-zhong1 . Laser Photolysis Studies on Pyrene in Ionic Liquids and Conventional Solvents [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(05): 1344-1347. |
[8] |
LIN Ying, GUO Xiao-yong, GU Xue-jun, XIA Wei-wei, ZHENG Hai-yang, ZHANG Wei-jun, FANG Li. Data Analysis of Laser Desorption/Ionization Mass Spectrum of Individual Particle Using Adaptive Resonance Theory Based Neural Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(03): 580-584. |
[9] |
LIAO Qiang-qiang1,2,WANG Zhong-yuan1,LI Yi-jiu1,XIANG Bo1,CHENG Ru-mei1,ZHANG Qin-jian3. Spectra Study of a Sodion Triethylenetetramine-bisDithiocarbamate and Its Complexes with Heavy Metal Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(03): 829-832. |
[10] |
GUO Xiao-yong,ZHAO Wen-wu,LIN Ying,GU Xue-jun,ZHENG Hai-yang,FANG Li,ZHANG Wei-jun. Single Particle Measurement of Suspended Soil Dust Using Laser Desorption/Ionization Time-of-Flight Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(08): 1919-1922. |
[11] |
GUO Xiao-yong,FANG Li,ZHAO Wen-wu,GU Xue-jun,ZHENG Hai-yang,ZHANG Wei-jun. Data Analysis of Laser Desorption/Ionization Mass Spectrum of Atmospheric Aerosol Particles Using Fuzzy Clustering Algorithms[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(08): 1713-1717. |
[12] |
ZHANG Zhao-xia1,2,ZHAO Hong-wei1,ZHU Hong-ping1,2,HAO Shu-mei1,2,WANG Wen-feng1*,LI Wen-xin1, Suppiah Navaratnam3. The Triplet Properties of β-Carotene in Acetonitrile Solution: A Laser Flash Photolysis Study[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(03): 481-484. |
[13] |
XU Jing-jing, WU Guo-zhong, LONG De-wu, YAO Si-de. Laser Photolysis Study on Photochemical Reactions in Mixed Solutions of [bmim][PF6] and Acetonitrile[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(10): 1936-1938. |
[14] |
HUANG Zheng-xu1, GUO Chang-juan1, CHEN Hua-yong1, ZHOU Zhen1,2*. The Development and Applications of Atmospheric Pressure Matrix-Assisted Laser Desorption/Ionization[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(10): 1910-1916. |
[15] |
WANG Cai-xia, CHEN Zhong-ming*, XU Jin-rong. Reaction Mechanisms of the UV-Photolysis of Methyl Hydroperoxide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(12): 2222-2225. |
|
|
|
|