| 光谱学与光谱分析 |
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| Transport Kinetics of Pb(Ⅱ) Through Bulk Liquid Membrane Using PC-88A as Carrier |
| YU Xiao-jiao1,YAO Bing-hua1,ZHOU Xiao-de2,ZHENG Huai-li3,ZHANG Jian-feng2 |
1. Department of Applied Chemistry，Xi’an University of Technology，Xi’an 710048，China
2. College of Water Resources and Hydraulic Power，Xi’an University of Technology，Xi’an 710048，China
3. College of Chemistry and Chemical Engineering，Chongqing University，Chongqing 400044，China |
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Abstract The effects of stirring speed, carrier concentration and reaction temperature on the transport of Pb(Ⅱ) ion through bulk liquid membrane were studied with chloroform as membrane solvent and 2-ethylhexyl phosphonic acid-mono-2-ethylhexylester as carrier. The Pb(Ⅱ) ions concentrations of feed phase and stripping phase were assayed by atomic absorption spectroscopy. The kinetic parameters, including apparent rate constants of Pb(Ⅱ) ion extraction and re-extraction reactions, the maximum concentration of Pb(Ⅱ) ion in the liquid membrane, the time of the maximum value of maximum concentration of Pb(Ⅱ) ion in the liquid membrane and the maximum entry and exit fluxes of Pb(Ⅱ) ion through the liquid membrane of the extraction and stripping reactions, were evaluated. The apparent activation energy value is 31.65 kJ·mol-1 for extraction and 23.11 kJ·mol-1 for stripping. The results indicate that good agreement between experimental data and theoretical predictions could be achieved and the kinetics of Pb(Ⅱ) transport could be evaluated by two consecutive irreversible pseudo-first order reactions. In this condition the chemical reaction is a procedure of controlled reaction rates.
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Received: 2009-01-22
Accepted: 2009-04-25
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Corresponding Authors:
YU Xiao-jiao
E-mail: yxjw@xaut.edu.cn
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[1] XU Ying, LUO Yu-lan, WEI Guang-yan(徐颖，罗玉兰，魏广艳). Environmental Science and Technology(环境科学与技术), 2006, 29(5)：75.
[2] WANG Fei, WANG Lian-jun, LI Jian-sheng, et al(王菲，王连军 ，李健生，等). Chinese Journal of Process Engineering(过程工程学报), 2008, 8(3)：467.
[3] ZHANG Yuan, LUO Wen-hong, LI Hui(张源，罗文鸿，李慧). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(7)：1349.
[4] Paphungkorn Teekayuttasakul, Annachhatre Ajit P. Journal of Environmental Science and Health, PartA: Toxic/Hazardous Substances and Environmental，2008, 43(12)：1424.
[5] SHAN Hai-xia, LI Zai-jun(单海霞，李在均). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(1)：214.
[6] LI Zhong-guo, LI Jin-hui, DUAN Hua-bo(李忠国，李金惠，段华波). Chinese Journal of Environmental Engineering(环境工程学报),2007, 1(11)：51.
[7] XIAO Shan-mei, CHEN Jian-rong, SHEN Yu-qin(肖珊美，陈建荣，沈玉勤). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(5)：955.
[8] ZHANG Dong, SU Hui-dong, GAO Hong, et al(张东，苏会东，高虹，等). Acta Chimica Sinica(化学学报), 2007, 65(22): 2549.
[9] YANG Xin, LIU Fu-qiang, JING Xiao-sheng, et al(杨鑫，刘福强，荆晓生，等). Ion Exchange and Adsorption(离子交换与吸附), 2008, 24(5): 385.
[10] Ali Reza Fakhari, Afshin Rajabi Khorrami, Mojtaba Shamsipur. Separation and Purification Technology, 2006, 50：77.
[11] Venkateswaran P, Gopalakrishnan Navaneetha A, Palanivelu K. Journal of Environmental Science, 2007, 19(12): 144.
[12] FEI De-jun, LUO Jian-hong, DANG Ya-gu, et al(费德君，罗建洪，党亚固，等). Chemical Engineering(化学工程), 2008, 36(3): 35.
[13] LIU Xin-fang, HE Ding-sheng, MA Ming, et al(刘新芳，何鼎胜，马铭，等). Chinese Journal of Inorganic Chemistry(无机化学学报), 2003, 19(12): 1295.
[14] Gerardo León, María Amelia Guzman. Desalination, 2008, 223：330.
[15] Zolgharnein Javad, Shahrjerdi Akram, Asanjarani Neda, et al. Separation Science and Technology, 2008, 43(11-12)：3119.
[16] LIU Hua-jie, WU Qing-sheng, DING Ya-ping, et al(柳华杰，吴庆生，丁亚平，等). Acta Chimica Sinica(化学学报), 2004, 62(10): 946.
[17] ZHANG Rui-hua, XU Zhi-wei, HONG Yong-jian, et al(张瑞华，徐志伟，洪勇健，等). Membrane Science and Technology(薄膜科学与技术)，2000，20(3): 44.
[18] Krull F F, Fritzmann C, Melin T. Journal of Membrane Science, 2008, 325: 509.
[19] JIANG Gui-hua, LIU Chun-ming, WANG Xiao-ju(蒋桂华，刘春明，王晓菊). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1999, 19(5)：732.
[20] CHEN Rui-zhan, WANG Xiao-ju, LIU Hai-yin(陈瑞战，王晓菊，刘海音). Metallurgical Analysis(冶金分析), 2001, 21(1): 46.
[21] Gürel Levent, Altas Levent, Büyükgüngr Hanife. Environmental Engineering Science, 2005,22 (4)：411.
[22] Salazar-Alvarez German，Bautista-Flores Ana Nelly,de San Miguel Eduardo Rodríguez, et al. Journal of Membrane Science, 2005, 250(1/2)：247.
[23] XIAO Xin-feng, ZHANG Xin-shen, GONG Zheng-jun, et al(肖新峰，张新申，龚正君，等). Chinese Journal of Analytical Chemistry(分析化学), 2006, 34(6)：855.
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