| 光谱学与光谱分析 |
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| Synthesis, Characterization and Luminescence Properties of Coordination Compounds of Rare Earth with p-Tert-Butyl-Calix[8] Arene |
| YAN Lai1, ZHAO Yong-liang1*, ZHAO Feng-ying2, WANG Ling-xuan3, YE Jian-ping3 |
1. The College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China
2. Department of Fundamental, Inner Mongolia Agriculture University, Hohhot 010019, China
3. Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China |
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Abstract Fourteen solid coordination compounds of rare earth(Sm3+, Eu3+, Tb3+ and Dy3+ and Ln3+(La3+, Gd3+ and Y3+)-doped Tb3+ with p-tert-butyl-calix[8] arene (LH8) have been synthesized and characterized. Elemental analysis, rare erth complexometry, 1H NMR spectra and TG-DTA have been studied. The results suggest that the complexes have the composition of [RE2(LH2)(DMSO)5]DMSO，[RE2(LH2)(DMF)5]2DMF，[LnTb(LH2)(DMSO)5]DMSO and [LnTb(LH2) (DMF)5]2DMF respectively. Fluorescence spectrum suggests that the Tb3+ complexes have characteristic luminescence, and its fluorescence intensity is enhanced after doping with La3+, Gd3+ and Y3+. The influence of the doping ions and two neutral ligands(DMSO and DMF) has also been discussed. In addition, the fluorescence lifetime of some complexes has been investigated.
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Received: 2004-12-28
Accepted: 2005-06-06
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Corresponding Authors:
ZHAO Yong-liang
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| Cite this article: |
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YAN Lai,ZHAO Yong-liang,ZHAO Feng-ying, et al. Synthesis, Characterization and Luminescence Properties of Coordination Compounds of Rare Earth with p-Tert-Butyl-Calix[8] Arene [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 928-932.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I05/928 |
[1] LIU Yu, YOU Chang-cheng, et al(刘 育，尤长城, 等). Supramolecular Chemistry(超分子化学). Tianjin: Nankai University Press(天津: 南开大学出版社)，2001.
[2] WU Hui-xia, XU Li-xia, XIN Chi-yang, et al(吴惠霞, 徐丽霞, 忻弛洋, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(1): 69.
[3] WANG Xi-gui, WU Hong-ying, ZHAO Hui, et al(王喜贵, 吴红英, 赵 慧, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(3): 428.
[4] Gutsche C D，Balram Dhawan，Kuwang Hyun, et al. J. Am. Chem. Soc., 1981，103：3782.
[5] Krishnamurthy V N，Soundararajan S. J. Inorg. Nucl. Chem., 1967，29：517.
[6] Krishnamurthy S S，Soundararajan S. Canadian Journal of Chemistry，1969，47：995.
[7] YANG Yu-xiang，WANG Peng，JIANG Zhong-liang, et al(杨宇翔, 王 鹏, 蒋忠良, 等). Rare Earth(稀土), 1998, 19(6)：5.
[8] MEI Su-rong，HE Ji-ping, LI Jian-sen, et al(梅素容, 何季平, 李建森, 等). Journal of Wuhan University(Natural Science Edition)(武汉大学学报·理科版), 1998，44(2)：159.
[9] ZHAO Tian-zeng(赵天增)，<sup>1</sup>H-Nnclear Magnetic Resonance Spectra(核磁共振氢谱). Beijing: Peking University Press(北京: 北京大学出版社), 1983.
[10] HUANG Liang, YU De-quan(黄 量，于德泉). The Application of UV-Vis Spectrum in Organic Chemistry(紫外光谱在有机化学中的应用). Beijing: Science Press(北京: 科学出版社)，1988.
[11] HUANG Chun-hui(黄春辉). Coordination Chemistry of Rare Earth(稀土配位化学). Beijing: Science Press(北京: 科学出版社)，1977. 363.
[12] SU Qiang，WU Yu-hua，WANG Hong-yan(苏 锵，吴玉华，王鸿燕). Chinese Journal of Luminescence(发光学报)，1992，13(2)：189.
[13] PAN Li-hua，LIU Li-ping，DONG Xiang-ming, et al(潘利华, 刘莉萍, 董向明, 等). Chinese Journal of Analytical Chemistry(分析化学)，1988，16(9): 779.
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