| 光谱学与光谱分析 |
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| Study on UV-Vis Absorption Spectra of Tetra-Azo-Aromaticoxy Substituted Metallophthalocyanines |
| XUE Jin-ping, HONG Hu-ming, YE Ting-xiu, FAN Chang-an，SUN Gang-chun, CHEN Nai-sheng*, HUANG Jin-ling |
| Institute of Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China |
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Abstract UV-Vis absorption spectras of six series (18 kinds) of tetra- azo-aromaticoxy substituted metallophthalocyanines (R4PcM, R=4-pyridyloxy，8-quinolinoxy，2-methyl-8-quinolinoxy;substitution position：α position and β position;M=Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ)) were measured. The effects of central mentals，the kinds and the positions of substitution groups, and solvents on the metallophthalocyanines’ λmax in Q-band were discussed. Experimental data show：The λmax in Q-band of title complexes is about 680 nm. In contrast with substitution-free metallophthalocyanines(669-671 nm), the λmax in Q-band of the title complexes with the same central metal exhibits a different red-shift. The effect of substitution group’s kinds on λmax in Q-band of the title complexes is more obvious in α position than in β position, and with the same substitution group and central metal, λmax in Q-band of α position substituted complexes exhibits more obvious red-shift than β position substituted complexes. The effects of central metal and solvent on λmax in Q-band of the title complexes aren’t obvious.
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Received: 2005-09-08
Accepted: 2005-12-18
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Corresponding Authors:
CHEN Nai-sheng
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| Cite this article: |
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XUE Jin-ping,HONG Hu-ming,YE Ting-xiu, et al. Study on UV-Vis Absorption Spectra of Tetra-Azo-Aromaticoxy Substituted Metallophthalocyanines[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(11): 2050-2052.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I11/2050 |
[1] Lever A B P, Pickens S R, Minor P C, et al. J. Am. Chem. Soc., 1981, 103：6800.
[2] Danilo Dini, Michael Hanack. J. Porphyrins and Phthalocyanines, 2004, 8: 915.
[3] XUE Jin-ping, HONG Hu-ming, CAI Sen-lin, et al(薛金萍, 洪湖铭, 蔡森林, 等). Chinese J. Inorg. Chem.(无机化学学报), 2005, 21(6): 810.
[4] HONG Hu-ming, XUE Jin-ping, SUN Gang-chun, et al(洪湖铭, 薛金萍, 孙纲春, 等). J. of Fuzhou University·Natural Science Edition(福州大学学报·自然科学版), 2005, 33(3): 382.
[5] HUANG Jin-ling, PENG Yi-ru，CHEN Nai-sheng(黄金陵, 彭亦如, 陈耐生). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2001, 21(1)：1.
[6] HUANG Jian-dong，LIU Er-sheng，YANG Su-ling, et al(黄剑东, 刘尔生, 杨素苓, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2000, 20(1): 95.
[7] SHEN Shu-yin，LIU Kai，DING Xi-ming, et al(沈淑引, 刘 恺, 丁西明，等). Applied Chemistry(应用化学)，1997，14(5)：43. |
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