光谱学与光谱分析 |
|
|
|
|
|
Spectral Analysis and Photoluminescence Properties of Eu-Tb Codoped Polymer |
LI Jie1,XU Bing-she2,LI Ying-chun1,XIE Jiang-bo1 |
1. College of Materials Science and Engineering,North University of China, Taiyuan 030051, China 2. Key Laboratory of Interface Science and Engineering in Advanced Materials of TYUT, Ministry of Education, College of Materials Science and Engineering of Taiyuan University of Technology, Taiyuan 030024, China |
|
|
Abstract In the present paper, Eu0.5Tb0.5(TTA)3Phen was synthesized and Eu0.5Tb0.5(TTA)3Phen/PMMA was prepared by in-situ polymerization. The structure of Eu0.5Tb0.5(TTA)3Phen/PMMA was characterized by FTIR spectra. Microscopic morphology and photoluminescence properties were investigated by SEM photographs and fluorescence spectra. The results indicated that polymer parts were attached with the rare-earth molecular parts in the composite luminescent materials.And Eu0.5Tb0.5(TTA)3Phen/PMMA could emit mostly characteristic fluorescence of europium ion and intense red fluorescence with a peak wavelength at 611.8 nm and a bandwidth of 10.4 nm(Purity: 0.990 5) under UV excitation at 365 nm. Its fluorescence intensity was found to be influenced with the content of MMA. It was demonstrated that Eu0.5Tb0.5(TTA)3Phen/PMMA was an excellent red photoluminescent rare-earth polymer material.
|
Received: 2008-01-13
Accepted: 2008-04-16
|
|
Corresponding Authors:
LI Jie
E-mail: ajiestar@tom.com
|
|
[1] WANG Lian-hui, ZHANG Wen-gong, WANG Wen(汪联辉,章文贡,王 文). Journal of Chinese Rare Earths(中国稀土学报), 1999, 20(3): 58. [2] Pan Yuan-feng, Zheng An-na, Xiao Hui-ning, et al. Functional Materials, 2005, 36(7): 1120. [3] GUO Xiang, LU Jian-mei, XU Qing-feng(郭 祥,路建美,徐庆锋). Polymer Materials Science and Engineering(高分子材料科学与工程), 2006, 22(1): 69. [4] XU Ying, DENG Zhen-bo, XU Deng-hui,et al(徐 颖,邓振波,徐登辉,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(5): 812. [5] PENG Lei-lei, LUO Yong-yue, DAN Yi, et al(彭蕾蕾,罗勇悦,淡 宜,等). Polymer Materials Science and Engineering(高分子材料科学与工程), 2006, 22(3): 152. [6] WANG Lian-hui, ZHANG Wen-gong(汪联辉,章文贡). Polymer Bulletin(高分子通报), 1995, (2): 104. [7] WANG Lian-hui, ZHANG Wen-gong(汪联辉,章文贡). Chemical Journal of Chinese Universities(高等学校化学学报), 1996, 17(5): 808. [8] WANG Lian-hui, ZHANG Wen-gong(汪联辉,章文贡). Acta Polymeric Sinica(高分子学报),1996, 17(5): 808. [9] LU Jian-mei, CHEN Nai-yong, DING Mei-xiang(路建美,陈乃勇,丁梅香). Chemical Engineering Journal of Chinese Universities(高校化学工程学报), 2001, 15(3): 259. [10] LU Jian-mei, DAI Wei-quan, JI Shun-jun, et al(路建美,戴蔚荃,纪顺俊, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22 (6): 990. [11] Larhed M, Haliberg A. J. Org. Chem., 1996, 61(26): 9582. [12] HUANG Chun-hui, LI Fu-you, HUANG Yan-yi (黄春辉,李富友,黄岩谊). Ultrathin Films for Optics and Electronics(光电功能超薄膜). Beijing: Peking University Press(北京: 北京大学出版社),2001. 76,165. [13] WANG Wen, LIN Mei-juan, LING Qi-dan, et al(王 文,林美娟,凌启淡,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(6): 1123. [14] FANG Rong-chuan(方容川). Solid Optical Spectroscopy(固体光谱学). Hefei: Science and Technology University of China Publishing House(合肥: 中国科学技术大学出版社),2001. 58. [15] YANG Bo, Lü Chang-li, SHEN Jia-cong(杨 柏,吕长利,沈家骢). Optical Materials of High-property Polymer(高性能聚合物光学材料). Beijing: Chemical Industry Press(北京: 化学工业出版社),2005. 3.
|
[1] |
QIN Li-mei, Andy Hsitien Shen*. Photoluminescence Spectral Characteristics of Jet From Fushun, Liaoning Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3180-3185. |
[2] |
ZHU Hong-wei1, CHENG You-fa1, CHEN Shu-xiang2*, FAN Chun-li1, LI Ting1, LIU Hai-bin1, ZHAO Xiao-xue1SHAN Guang-qi1, LI Jian-jun1. Spectroscopic Characteristics of a Natural Diamond Suspected of Synthetic Diamond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1690-1696. |
[3] |
YAN Xue-jun1, ZHOU Yang2, HU Dan-jing1, YU Dan-yan1, YU Si-yi1, YAN Jun1*. Application of UV-VIS Diffuse Reflectance Spectrum, Raman and
Photoluminescence Spectrum Technology in Nondestructive
Testing of Yellow Pearl[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1703-1710. |
[4] |
LI Zhao, WANG Ya-nan, XU Yi-pu, CAO Jing, WANG Yong-feng, WU Kun-yao, DENG Lu. Synthesis and Photoluminescence of Blue-Emitting Phosphor
YVO4∶Tm3+ for White Light Emitting Diodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 623-628. |
[5] |
LIAO Yi-min1, YAN Yin-zhou1, WANG Qiang2*, YANG Li-xue3, PAN Yong-man1, XING Cheng1, JIANG Yi-jian1, 2. Laser-Induced Growth Device and Optical Properties of ZnO
Microcrystals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3000-3005. |
[6] |
WANG Tao1, 2, LIU Jian-xun2, GE Xiao-tian2, WANG Rong-xin2, SUN Qian2, NING Ji-qiang2*, ZHENG Chang-cheng3*. Fine Photoluminescence Spectroscopic Characterization of Interfacial Effects on Emission Properties of InGaN/GaN Multiple Quantum Wells in a Blue-Light Laser Diode Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1179-1185. |
[7] |
LI Zhao, WU Kun-yao, WANG Ya-nan, CAO Jing, WANG Yong-feng, LU Yuan-yuan. Synthesis and Luminescence Properties of Yellow-Emitting Phosphor Y2.93Al5O12∶0.07Ce3+ Under Blue Light Excitation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 381-385. |
[8] |
CHEN Cai-yun-fei, LI Li-ping*. The Application of Photoluminescence Spectra on Identification of Different Types of Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 20-25. |
[9] |
ZHAO Tong1, WANG Ya-mei1,2, LIU Ling1, LI Yan1,3*. Gemological and Spectral Characteristics of Mexican Red Blue Amber[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2618-2625. |
[10] |
CHEN Yan-ping1, LUO De-li2*, HUANG Bin1, CHENG Hao1, TANG Xian-chen1, LI Qiang1, LEI Hong-bo1, CHEN Dan-ping3. Photoluminescence and Radioluminescence of Tb3+ Ion-Doped Lithium Aluminosilicate Glasses[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1863-1868. |
[11] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
[12] |
ZHAO Yuan, LÜ Zhao-yue*, DENG Jian, ZENG Guo-qing. The Emissive Mechanism of C545T Thin Layer at the Exciplex and Non-Exciplex Interfaces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3711-3715. |
[13] |
LIN Shun-hui,ZHANG Li-hui, LIU Yong-quan, WANG Xiao-kun, LIN Chun-lei, YU Yun-peng*. Thermal Annealing Effect on Photoluminescence of Y2O3∶Eu3+ Thin Films Prepared by Magnetron Sputtering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3336-3340. |
[14] |
YAN Jun1,2, SUN Qing2, YAN Xue-jun1, FANG Shi-bin1, SHENG Jia-wei2, ZHANG Jian2*. The Categories of the UV-Vis Reflectance Spectra of Seawater Cultured Black Pearl and Its Unique PL Spectral Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2781-2785. |
[15] |
ZHENG Bao-feng1, YANG Xiao-yun2,3, MIN Chun-gang2,3, CUI Xiao-ying2,3, DONG Kun2,3*. Study on Raman Spectra and Fluorescence Spectra of Dy3Al2(AlO4)3 in Aluminosilicate Substrates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 809-812. |
|
|
|
|